Methoxydiphenylphosphine

Methoxydiphenylphosphane · METHOXYDIPHENYLPHOSPHINE · METHYL DIPHENYLPHOSPHINITE · NSC 171167 · AURORA KA-1329 · DIPHENYLMETHOXYPHOSPHINE · Diphenylphosphinooxymethane · Methoxydiphenylphosphine>(diphenylmethyl)oxyphosphine

https://huagongshe.com/ko/chemical/77636

식별자 및 물리적 특성

CAS No.	4020-99-9
분자식	C13H13OP
평균 분자량	216.21 g/mol
단동위원소 질량	216.07040167 g/mol
SMILES	COP(c1ccccc1)c1ccccc1
InChIKey	OAADXJFIBNEPLY-UHFFFAOYSA-N
PubChem CID	77636
EC No.	223-683-9
DTXSID	DTXSID80193202

화학 및 물리적 성질

XLogP	3.1
극성 표면적	9.2
수소 결합 공여자 수	0
수소 결합 수용자 수	1
회전 가능 결합 수	3
무거운 원자 수	15
형식 전하	0
복잡도	153
물질 분류	Other Classes -> Phosphite Compounds
Physical Description	Liquid[Alfa Aesar MSDS]
끓는 점	149 °C6 mm Hg(lit.)
밀도	1.078 g/mL at 25 °C(lit.)
굴절률	n20/D 1.604(lit.)
인화점	>230 °F
저장 조건	2-8°C
물리적 상태	액체
비중	1.078
색상	투명하고 무색에서 아주 약간 노란색을 띤다.
BRN	1640480
InChI	InChI=1S/C13H13OP/c1-14-15(12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
InChIKey	OAADXJFIBNEPLY-UHFFFAOYSA-N
SMILES	P(C1=CC=CC=C1)(C1=CC=CC=C1)OC
NIST	Methyl diphenylphosphinite(4020-99-9)

화학적 성질

Colorless to light yellow liqui

안전 및 규제

GHS 분류	WarningH315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 45 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 요약	A skin and strong eye irritant[Alfa Aesar MSDS] See Triphenylphosphine. See Dimethyl phenylphosphonite.
Hazard Classes and Categories	Skin Irrit. 2 (100%)
수질 위해 등급(WGK)	3
운송 번호(UN)	UN 2810 6.1/PG 3
관세 코드	29310099
위험 문구(R)	36/37/38-20/21/22
위험 표시	Xi,Xn
안전 문구(S)	26-37/39-36
포장분류	III
위험 등급	6.1Eye Irrit. 2Skin Irrit. 2STOT SE 3
저장 분류	6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects

용도

Ased as:Catalyst for hydroformylative desymmetrization of bisalkenyl carbinols and bishomoallylic carbinolsLigand in rhodium-catalyzed hydroformylation of bishomoallylic alcoholsCalatyst in preparation of γ-lactones via branched-regioselective hydroformylation reactionsLigand for nickel-catalyzed hydrocyanation reactionsCatalyst in annulation reactions