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HCID 7836생성일: 2026년 10월 27일

아크릴산 글리시딜

글리시딜아크릴산 · 아크릴산글리시딜 · 2,3-에폭시프로필 아크릴레이트 · 2-프로펜산, 2-옥시란일메틸 에스터 · 글리시딜 아크릴레이트 · 글리시딜 아크릴산 · 글리시딜 프로페네이트 · 글리시딜아크릴레이트

https://huagongshe.com/ko/chemical/7836

아크릴산 글리시딜 분자 구조식

식별자 및 물리적 특성

CAS No.106-90-1
분자식C6H8O3
평균 분자량128.13 g/mol
단동위원소 질량128.04734412 g/mol
SMILESC=CC(=O)OCC1CO1
InChIKeyRPQRDASANLAFCM-UHFFFAOYSA-N
PubChem CID7836
EC No.203-440-3
DTXSIDDTXSID5025360
현지명아크릴산 글리시딜

화학 및 물리적 성질

XLogP0.4
극성 표면적38.8
수소 결합 공여자 수0
수소 결합 수용자 수3
회전 가능 결합 수4
무거운 원자 수9
형식 전하0
복잡도130
물질 분류Flammable agents - 2nd degree
PolymersPlastics & Rubber -> (Meth)acrylates
밀도1.1 (NTP, 1992) - Denser than waterwill sink1.1074 @ 20 °C/20 °C1.1074 @ 20°C1.1163 g/cm3
Color/FormLiquid
용해도10 to 50 mg/mL at 68.9 °F (NTP, 1992)Insoluble in water클로로포름(소량으로 용해), 메탄올(약간 용해됨)
인화점141 °F (NTP, 1992)141 °F (61 °C) (open cup)61°C(lit.)
끓는 점135 °F at 2 mmHg (NTP, 1992)57 °C @ 2 mm HgPolymerization occurs at boiling point60°C 16mm
DecompositionWhen heated to decomp it emits acrid smoke and fumes.
녹는점Freezing point: -41.5 °C-42 °C
증기 밀도4.4 (NTP, 1992) - Heavier than airwill sink (Relative to Air)4.4 (air= 1)
증기압2.97 [mmHg]
Physical DescriptionGlycidyl acrylate is a light amber liquid. (NTP, 1992)Light amber liquid[CAMEO] Colorless liquid[CHEMINFO] Clear deep red liquid[MSDSonline]
굴절률1.4508 (589.3 nm 20℃)
저장 조건-20°C Freezer
물리적 상태투명한 액체
색상Colorless to Light orange to Yellow
안정성안정성 가연성. 강한 산화제와 호환되지 않습니다. 중합되기 쉬울 수 있습니다.
InChIInChI=1S/C6H8O3/c1-2-6(7)9-4-5-3-8-5/h2,5H,1,3-4H2
InChIKeyRPQRDASANLAFCM-UHFFFAOYSA-N
SMILESC(OCC1CO1)(=O)C=C
EPAGlycidyl acrylate (106-90-1)

화학적 성질

amber liquid

안전 및 규제

GHS 분류DangerH301: Toxic if swallowed [Danger Acute toxicity, oral]P260, P261, P262, P264, P270, P271, P272, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P333+P317, P361+P364, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]
규제 정보Chemical: 2-Propenoic acid, oxiranylmethyl esterTP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
기타 안전 정보Evaluation - Glycidyl acrylate and glycidyl methacrylate
운송 라벨(DOT)Flammable Liquid Poison
화재 위험This chemical is combustible. (NTP, 1992)
화재 가능성Flammable liquid when exposed to heat or flame.
건강 유해성Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:
유해성 요약A skin and eye irritant[Hawley] External application to rabbit eyes scored 10 on a scale of 1-10 (10 being most severe) for degree of injury after 24 hours[HSDB] May polymerize[CAMEO] Corrosive to skin and eyes, based on animal studies[CHEMINFO] Can cause burnsMay cause skin sensitization[eChemPortal: ESIS] A corrosive substance that can cause injury to the skin, eyes, and respiratory tractCan be absorbed through skinInhalation may cause chemical pneumonitis and pulmonary edema[MSDSonline] See ACRYLIC RESINS (MONOMERS).
반응성 그룹Epoxides
Reactivity AlertsHighly Flammable
Reactivity ProfileGLYCIDYL ACRYLATE may be sensitive to polymerizing conditions and/or catalysts. This compound will react with oxidizers. (NTP, 1992)

용도

개요

Glycidyl acrylate (GA) is a monomer that polymerizes in the presence of a free-radical initiator to form polyacrylic acid. This compound is used as a cross-linking agent for coatings, adhesives, and sealing compounds. GA is an excellent starting material for the preparation of cationic polymers with high reactivity and good stability. It has been used as a control agent in the synthesis of polycarboxylic acids and fatty acids. The hydroxyl group on this molecule allows it to be used as a water-repellent coating or sealant.

용도

Glycidyl Acrylate 85% can be used as an adhesive composition.

일반 설명

Light amber liquid.

Air and Water ReactionsWater soluble.
NFPA Hazard Classification0 - Materials that, under emergency conditions, would offer no hazard beyond that of ordinary combustible materials.2 - Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release vapor in sufficient quantities to produce hazardous atmospheres with air.0 - Materials that in themselves are normally stable, even under fire conditions.
소화Fires involving this chemical should be extinguished with a foam, dry chemical or carbon dioxide extinguisher. (NTP, 1992)
응급 처치EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
보관 조건The effectiveness of phenolic inhibitors is dependent on the presence of oxygen and the monomers must be stored under air rather than an inert atmosphere. Temp must be kept low to minimize formation of peroxides and other products. ... The acrylic esters may be stored in mild or stainless steel, or aluminum. /Acrylic acid & derivatives/
비화재 누출 대응SMALL SPILLS AND LEAKAGE: If you spill this chemical, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
처리 방법SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
Preventive MeasuresAwareness of the dangers and of good engineering design are essential to safety. Employees should be instructed about the necessity of cleansing the skin if it is contaminated by materials which are irritants or skin-absorbed. With careful design, however, and complete enclosure of those processes where toxic chemicals or intermediates occur, dangerous exposures can be avoided. /Acrylic acid & derivatives/SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
Isolation and EvacuationExcerpt from ERG Guide 131 [Flammable Liquids - Toxic]:
Protective Action Criteria (PAC)0.081 [ppm]0.89 [ppm]5.4 [ppm]
Personal Protective Equipment (PPE)RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)SUITABLE PROTECTIVE CLOTHING & SELF CONTAINED RESP PROTECTIVE APPARATUS SHOULD BE AVAILABLE FOR USE OF THOSE WHO MAY HAVE TO RESCUE PERSONS OVERCOME BY FUMES. /ACRYLIC ACID & DERIVATIVES/Protection required for safe handling of acrylic acid and esters commonly includes use of impervious gloves, shoe soles, and clothingsplash-proof goggles ... . /Acrylic acid & derivatives/
유해 작용Dermatotoxin - Skin burns.
Human Toxicity ExcerptsTHE ACUTE TOXICITY OF THE ACRYLATES DECREASES WITH INCREASING MOLECULAR WEIGHT. ... HUMAN SIGNS & SYMPTOMS FOLLOWING INGESTION OF ACRYLIC MONOMERS INCL COLLAPSE, SEVERE RESPIRATORY DIFFICULTIES, & CNS STIMULATION. ACUTE INHALATION OF HIGHER CONCN MAY CAUSE MARKED IRRITATION, SALIVATION, CONJUNCTIVAL IRRITATION, & PRONOUNCED PULMONARY IRRITATION OR EDEMA. PROLONGED SKIN OR EYE CONTACT MAY RESULT IN SEVERE TISSUE DAMAGE. THE PATHOLOGY FROM SINGLE EXPOSURE IS NONSPECIFIC, CONTRARY TO REPEATED EXPOSURE EFFECTS, WHICH INCL PULMONARY CONGESTION OR HEMORRHAGE & CLOUDY SWELLING OF LIVER & KIDNEY. /ACRYLATES/
Non-Human Toxicity ExcerptsGLYCIDYL ACRYLATE ADMIN @ 0.5 MG/100 G IP, SHOWED NO INHIBITORY EFFECT ON TRANSPLANTED WALKER TUMORS IN RATS 24 HR AFTER DOSE, BONE MARROW SHOWED 2% ANAPHASES IN EXCESS OF CONTROLS WITH STICKY CHROMOSOME BRIDGES.Acrylic acid 2,3-epoxypropyl ester has been tested externally on the eyes of rabbits & ... rated 10 on scale of 1 to 10 according to the degree of injury observed after 24 hr. The most severely injurious substances have been rated 10.Contact sensitivity was produced in guinea pigs with mono-, di-, and tri- acrylate compounds. /Mono-, di-, and tri- acrylate compounds/
Antidote and Emergency TreatmentBasic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . /Esters and related compounds/Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start an IV with D5W TKO /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Consider drug therapy for pulmonary edema ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Esters and related compounds/
Toxicity DataLCLo (rat) = 125 ppm/4h
Non-Human Toxicity ValuesLD50 Rat oral 210 mg/kgLD50 Rabbit skin 400 mg/kg
TSCA 등재 상태TSCA listed
RTECS 번호AS9275000
운송 번호(UN)2810
관세 코드2916.12.5050
위험 문구(R)23/24/25-34-43
위험 표시T
안전 문구(S)26-36/37/39-45
포장분류III
위험 등급6.1(b)
기존화학 물질KE-18033
유해 물질 데이터106-90-1(Hazardous Substances Data)
함량 및 규제정보물질구분: 유독물질혼합물(제품)함량정보: 글리시딜 아크릴산 및 이를 25% 이상 함유한 혼합물
유해화학물질 필터링97-1-6