Vinyl chloroformate (HCID 78808)

이름 및 식별자

우선 이름: Vinyl chloroformate
IUPAC: ethenyl carbonochloridate
영어명: Vinyl chloroformate
분자식: C3H3ClO2
분자량: 106.51

이름 및 동의어

Vinyl chloroformate5130-24-5ethenyl carbonochloridate9DJ5DDM7G9Carbonochloridic acid, ethenyl esterEINECS 225-874-2chloroformic acid vinyl esterDTXSID30199299RefChem:901916DTXCID10121790225-874-2vinyl carbonochloridate

이름 더 보기

Vinyl chlorocarbonateVinylchloroformate99%Vinyl chloroformate 98%Vinyloxycarbonyl chlorideVINYL CHLOROFORMATE, STAB.Ethenyl carbonochloridoateChloroformic acid ethenyl esterVinyl Chloroformate DISCONTINUED

vinylchloroformateethenyl chloroformateUNII-9DJ5DDM7G9Vinyl chloroformate, 94%Vinyl chloroformate, 99%SCHEMBL197073STR07467MFCD00000641

데이터베이스 식별자

CAS: 5130-24-5
PubChem CID: 78808
DTXSID: DTXSID30199299
UNII: 9DJ5DDM7G9
EC Number: 225-874-2
Nikkaji: J203.322D

물성

구조 계산 물성

XLogP: 1.7
극성 표면적: 26.3 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 2
회전 가능 결합 수: 2
무거운 원자 수: 6
형식 전하: 0
복잡도: 69.2

실험 및 물리화학적 성질

Chemical ClassesToxic Gases & Vapors -> Acid Halides

Vapor Pressure45.5 [mmHg]

Physical DescriptionColorless liquid; [Alfa Aesar MSDS]

물리화학적 성질

끓는 점: 68 · 68-69 °C735 mm Hg(lit.)
밀도: 1.166 g/mL · 1.166 g/mL at 20 °C(lit.)
증기압: 0.88 psi · 0.88 psi ( 20 °C)
굴절률: 20 · n20/D 1.41(lit.)
인화점: 24 °F · 24 °F
저장 조건: 2 · 2-8°C
물리적 상태: 액체
색상: 무색의
BRN: 1741679 · 1741679

화학적 성질

clear colourless liquid

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P270, P271, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P330, P361+P364, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationChemical: Carbonochloridic acid, ethenyl ester

Other Safety InformationEvaluation - Chemicals that are unlikely to require further regulation to manage risks to human health

Hazards SummaryReacts with water; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract; Toxic by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] See Allyl chloroformate.

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

안전 및 보호

Exposure Control and Personal Protection · 1건

TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

안전 데이터

wgk: 3
ridadr: UN 3390 6.1/PG 1
HS 번호: 29159000
risk_code: 23/24/25-34-11
hazard_code: F,T
safety_code: 16-26-36-45-36/37
포장분류: II
위험 등급: 6.1(a)
F 고인화성물질: 10-21-19

화학 및 산업

응용 분야

용도Vinyl Chloroformate was used to prepare analogues of the Nicotinic Acetylcholine Receptor Agonist (±)-UB-165. It was also used to synthesize possible antitumor agents such as paclitaxel-2''-carbonates and N-carbamyl triazenes.