Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
벤조페논히드라존
벤조페논하이드라존 · 벤조페논히드라존 · 벤조페논 하이드라존 · 다이(페닐)메틸리덴하이드라진 · 다이페닐 케톤 하이드라존 · 다이페닐메탄온 하이드라존 · 메탄온, 다이페닐-, 하이드라존 · 벤조페논 히드라존
식별자 및 물리적 특성
| CAS No. | 5350-57-2 |
|---|---|
| 분자식 | C13H12N2 |
| 평균 분자량 | 196.25 g/mol |
| 단동위원소 질량 | 196.10004839 g/mol |
| SMILES | NN=C(c1ccccc1)c1ccccc1 |
| InChIKey | QYCSNMDOZNUZIT-UHFFFAOYSA-N |
| PubChem CID | 79304 |
| ChEMBL | CHEMBL1881268 |
| EC No. | 226-321-8 |
| DTXSID | DTXSID6063806 |
| 현지명 | 벤조페논히드라존 |
화학 및 물리적 성질
| XLogP | 2.8 |
|---|---|
| 극성 표면적 | 38.4 |
| 수소 결합 공여자 수 | 1 |
| 수소 결합 수용자 수 | 2 |
| 회전 가능 결합 수 | 2 |
| 무거운 원자 수 | 15 |
| 형식 전하 | 0 |
| 복잡도 | 191 |
| 용해도 | 8.1 [ug/mL] (The mean of the results at pH 7.4)에테르, 벤젠, 클로로포름 및 기타 유기 용매에 용해됩니다. |
| 증기압 | 0.000151 [mmHg] |
| Physical Description | White to yellow powder[Acros Organics MSDS] |
| 녹는점 | 95-98 °C (lit.) |
| 끓는 점 | 225-230 °C/55 mmHg (lit.) |
| 밀도 | 1.1 |
| 굴절률 | 1.5014 (estimate) |
| 인화점 | 146°C |
| 저장 조건 | 2-8°C |
| pKa(산도 계수) | 1.44±0.70(Predicted) |
| 물리적 상태 | 수정 바늘 또는 수정 가루 |
| 색상 | 흰색에서 노란색으로 |
| BRN | 1910177 |
| InChI | 1S/C13H12N2/c14-15-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,14H2 |
| InChIKey | QYCSNMDOZNUZIT-UHFFFAOYSA-N |
| SMILES | N\N=C(/c1ccccc1)c2ccccc2 |
| NIST | Methanone, diphenyl-, hydrazone(5350-57-2) |
| EPA | Methanone, diphenyl-, hydrazone (5350-57-2) |
화학적 성질
white to light yellow crystal powde
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 10% (1 of 10) of reports.DangerH301 (80%): Toxic if swallowed [Danger Acute toxicity, oral]H302 (10%): Harmful if swallowed [Warning Acute toxicity, oral]H317 (80%): May cause an allergic skin reaction [Warning Sensitization, Skin]H401 (10%): Toxic to aquatic life [Hazardous to the aquatic environment, acute hazard]H411 (80%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]P261, P264, P270, P272, P273, P280, P301+P316, P301+P317, P302+P352, P321, P330, P333+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 10 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Reported as not meeting GHS hazard criteria per 1 of 10 reports by companies.There are 4 notifications provided by 9 of 10 reports by companies with hazard statement code(s).Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| 규제 정보 | Chemical: Methanone, diphenyl-, hydrazoneStatus: Active Update: 06-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/21208Benzophenone hydrazone: Does not have an individual approval but may be used under an appropriate group standard |
| 유해성 요약 | Intraperitoneal LD50 (mouse) = 134 mg/kg[RTECS] May cause irritation[Acros Organics MSDS] |
| Hazard Classes and Categories | Acute Tox. 3 (80%)Acute Tox. 4 (10%)Skin Sens. 1 (80%)Aquatic Acute 2 (10%)Aquatic Chronic 2 (80%) |
| 수질 위해 등급(WGK) | 3 |
| TSCA 등재 상태 | TSCA listed |
용도
용도
An important compound in organic photochemistry and perfumery as well as in organic synthesis. Used in the antibiotics synthesis of 6-APA and 7-ACA of the carboxyl protecting groups and other organic compounds. Used as organic pigment and medical intermediate. It is used as a photoinitiator of UV-curing applications in inks, adhesive, coatings and optical fiber.