Cyclohexyl bromide (HCID 7960)

이름 및 식별자

우선 이름: Cyclohexyl bromide
IUPAC: bromocyclohexane
현지명: 브로모사이클로헥산
영어명: Bromocyclohexane
분자식: C6H11Br
분자량: 163.06

이름 및 동의어

BROMOCYCLOHEXANE108-85-0Cyclohexyl bromideCyclohexane, bromo-1-BromocyclohexaneYA0UMS4RNYEINECS 203-622-2NSC 11207AI3-28585NSC-11207CYCLOHEXYL BROMIDE [MI]DTXSID1044148

이름 더 보기

브로모사이클로헥산브로모시클로헥산브로모사이클로헥세인CyclohexylbromidBromocylohexanebromo-cyclohexanBroMocyclohexanceCyclohexane,bromo-Cyelohexyl bromideBromocyclohexane>

1BromocyclohexaneCyclohexane, bromoRefChem:580805DTXCID9024148203-622-2InChI=1/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5Hbromo-cyclohexaneMFCD00003819

데이터베이스 식별자

CAS: 108-85-0
PubChem CID: 7960
DTXSID: DTXSID1044148
UNII: YA0UMS4RNY
EC Number: 203-622-2
Nikkaji: J5.082B

물성

구조 계산 물성

XLogP: 3.2
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 0
무거운 원자 수: 7
형식 전하: 0
복잡도: 46

실험 및 물리화학적 성질

Vapor Pressure3.62 [mmHg]

Physical DescriptionLiquid with a penetrating odor; [Merck Index] Colorless liquid with an unpleasant odor; [Acros Organics MSDS]

Kovats Retention Index · 3건

969；969；1023；970.2；969；969；975

984；1009；1009；1023

1303；1303；1288

물리화학적 성질

녹는점: -57 °C · -57°C
끓는 점: 166 · 166-167 °C (lit.)
밀도: 1.324 g/mL · 1.324 g/mL at 25 °C (lit.)
증기 밀도: 5.62 · 5.62 (vs air)
굴절률: 20 · n20/D 1.495(lit.)
인화점: 145 °F · 145 °F
저장 조건: Sealed in dry,Room Temperature
용해도: 에탄올, 에테르, 아세톤, 벤젠 및 사염화탄소와 혼합 가능합니다.
물리적 상태: 액체
Specific Gravity: 1.33 · approximate 1.33 (20℃)
색상: 무색투명~연황색
냄새: 불쾌한 냄새
수용성: 불용성
Merck: 14 · 14,2730
BRN: 1098373 · 1098373
Henry's Law Constant: 7 · 7.0×10-3 mol/(m3Pa) at 25℃, Hilal et al. (2008)
Dielectric constant: 7.9 · 7.9(25℃)
안정성: 안정적인. 타기 쉬운. 강한 산화제, 강한 염기와 호환되지 않습니다.
InChI: 1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2
InChIKey: AQNQQHJNRPDOQV-UHFFFAOYSA-N
SMILES: BrC1CCCCC1
NIST: Cyclohexane, bromo-(108-85-0)
EPA: Cyclohexane, bromo- (108-85-0)

화학적 성질

colourless liquid

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 22.2% (2 of 9) of reports.

Warning

H227 (11.1%): Combustible liquid [Warning Flammable liquids]；H315 (66.7%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (66.7%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (66.7%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H411 (22.2%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P210, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P391, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 9 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 2 of 9 reports by companies.；There are 4 notifications provided by 7 of 9 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 3건

Chemical: Cyclohexane, bromo-

Status: Active Update: 06-06-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/17906

Cyclohexane, bromo-: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryMay cause irritation; [Acros Organics MSDS] See Chlorocyclohexane. See 1-Bromohexane.

Hazard Classes and CategoriesFlam. Liq. 4 (11.1%)；Skin Irrit. 2 (66.7%)；Eye Irrit. 2A (66.7%)；STOT SE 3 (66.7%)；Aquatic Chronic 2 (22.2%)

규제 정보

Regulatory Information · 3건

Chemical: Cyclohexane, bromo-

Status: Active Update: 06-06-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/17906

Cyclohexane, bromo-: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk: 3
tsca: TSCA listed
rtecs: GU7171700
HS 번호: 29035990
risk_code: 36/37/38-20-18-52
hazard_code: Xn
safety_code: 23-24/25-37/39-26
기존화학 물질: KE-09221
F 고인화성물질: 8
Hazard Classifications: Aquatic Chronic 2
스토리지 클래스: 10 - Combustible liquids

화학 및 산업

용도 및 제조

UsesUsed as an intermediate; [REPROTOX]

General Manufacturing InformationCyclohexane, bromo-: ACTIVE

응용 분야 · 2건

용도Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.

일반 설명Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.

제조 방법

Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.

상·하류 제품 정보

상류 원료

브롬화수소 사이클로헥산올

하류 제품

1,1'-비스(디-t-부틸포스피노)페로센팔라듐디클로라이드,1-Cyclohexylpiperazine Bis(tricyclohexylphosphine)palladium(II) Dichloride 1,1'-Bis(di-tert-butylphosphino)ferrocene 2- (디시 클로 헥실 포스 피노) -2 '- (N, N- 디메틸 아미노)) -1,1'- 비 페닐 2- (디 사이클로 헥실 포스 피노)) -1,1'- 비 페닐 트리사이클로헥실포스핀 요오드시클로헥산 시클로헥실아민 1,1-디브로모시클로헥산 2-사이클로헥실피리딘 디시클로헥실포스핀옥사이드

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

合肥翰刚医药科技有限公司+8618062405514 · [email protected]

VladaChem GmbH+49-7246-3082843 +86-18411632868 · [email protected]

연결된 노트

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