Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
이소부틸 비닐 에테르
비닐아이소뷰틸에테르 · 아이소뷰틸비닐에테르 · 이소부틸비닐에테르 · 비닐 아이소뷰틸 에테르 · VINYL ISOBUTYL ETHER · IVE · vinoflexmo400* · isobutoxyethene
식별자 및 물리적 특성
| CAS No. | 109-53-5 |
|---|---|
| 분자식 | C6H12O |
| 평균 분자량 | 100.16 g/mol |
| 단동위원소 질량 | 100.088815 g/mol |
| SMILES | C=COCC(C)C |
| InChIKey | OZCMOJQQLBXBKI-UHFFFAOYSA-N |
| PubChem CID | 7992 |
| ChEMBL | CHEMBL3183612 |
| EC No. | 203-678-8 |
| DTXSID | DTXSID8029608 |
| 현지명 | 이소부틸 비닐 에테르 |
화학 및 물리적 성질
| XLogP | 2.2 |
|---|---|
| 극성 표면적 | 9.2 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 1 |
| 회전 가능 결합 수 | 3 |
| 무거운 원자 수 | 7 |
| 형식 전하 | 0 |
| 복잡도 | 48.1 |
| 물질 분류 | Other Classes -> Ethers, OtherFlammable agents - 3rd degree |
| SpringerMaterials Properties | Boiling point |
| 인화점 | 15 °F (NFPA, 2010)8 °F |
| 증기압 | 59.5 [mmHg]68 mm Hg ( 20 °C) |
| Physical Description | Vinyl isobutyl ether appears as a clear colorless liquid. May polymerize if contaminated or subjected to heat. If polymerization take place inside a container, the container may violently rupture. Vapors are heavier than air.Clear colorless liquid[CAMEO] |
| 녹는점 | -112 °C |
| 끓는 점 | 83 °C |
| 밀도 | 0.769 |
| 증기 밀도 | 3.45 (vs air) |
| 굴절률 | n20/D 1.395(lit.) |
| 저장 조건 | Flammables area |
| 물리적 상태 | 투명한 액체 |
| 색상 | 무색 내지 거의 무색 |
| 용해도 | 0.7g/L(25℃) |
| BRN | 1560159 |
| 헨리 상수 | 3.9×10-3 mol/(m3Pa) at 25℃, Raventos-Duran et al. (2010) |
| 유전율 | 3.3399999999999999 |
| InChI | 1S/C6H12O/c1-4-7-5-6(2)3/h4,6H,1,5H2,2-3H3 |
| InChIKey | OZCMOJQQLBXBKI-UHFFFAOYSA-N |
| SMILES | CC(C)COC=C |
| LogP(분배 계수) | 3.07 at 25℃ |
| NIST | Vinylisobutyl ether(109-53-5) |
| EPA | Propane, 1-(ethenyloxy)-2-methyl- (109-53-5) |
화학적 성질
Colorless liquid. Very slightly soluble in water; soluble in alcohol and ether; easily polymerized.
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 3.8% (8 of 213) of reports.DangerH225 (96.2%): Highly Flammable liquid and vapor [Danger Flammable liquids]P210, P233, P240, P241, P242, P243, P264, P264+P265, P273, P280, P302+P352, P303+P361+P353, P305+P351+P338, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P235, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 213 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Chemical: Propane, 1-(ethenyloxy)-2-methyl-Propane, 1-(ethenyloxy)-2-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Propane, 1-(ethenyloxy)-2-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 31-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/2053Propane, 1-(ethenyloxy)-2-methyl-: Does not have an individual approval but may be used under an appropriate group standardThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 운송 라벨(DOT) | Flammable Liquid |
| 화재 위험 | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]:· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. |
| 건강 유해성 | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]:· Inhalation or contact with material may irritate or burn skin and eyes. |
| 유해성 요약 | May polymerizeForms explosive peroxides on exposure to air[CAMEO] A skin, eye, nose, and throat irritant[NJ-HSFS] May form explosive peroxidesAn irritant[Sigma-Aldrich MSDS] Vinyl isobutyl ether, stabilized (UN1304) has warning of explosive polymerization[ERG 2016] |
| 운송 번호 및 가이드(DOT) | 1304 127P |
| 반응성 그룹 | Ethers |
| Reactivity Alerts | Highly Flammable |
| Reactivity Profile | VINYL ISOBUTYL ETHER is a colorless, moderately toxic liquid, highly flammable. A very dangerous fire hazard when exposed to heat, flame or strong oxidizing agents. Highly explosive in the form of vapor when exposed to open flame or sparks. |
| DOT Hazard Classification | Vinyl isobutyl ether, stabilizedUN1304Class 3 Flammable and combustible liquid (49 eCFR § 173.120)PG II: the degree of danger presented by the material is medium |
| Air and Water Reactions | Highly flammable. Less dense than water and very slightly soluble in water. Tends to form explosive peroxides when exposed to air. When ethers containing peroxides are heated (distilled) they can detonate [Lewis, 3rd ed., 1993, p. 728]. |
| Peroxide Forming Chemical | Isobutyl vinyl etherB: Compounds that form peroxides on concentration (distillation/evaporation)Kelly |
| 소화 | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]: |
| 누출 비상 조치 | · CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. |
| 응급 처치 | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]:General First Aid: |
| 노출 관리 및 개인 보호 | · Wear positive pressure self-contained breathing apparatus (SCBA).20.0 [ppm] |
| 비화재 누출 대응 | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]: |
| Isolation and Evacuation | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]:Immediate precautionary measure |
| Personal Protective Equipment (PPE) | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]: |
| Emergency Response Planning Guidelines | CAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient. |
| Toxicity Data | LCLo (rat) = 16,000 ppm/4hr |
| 수질 위해 등급(WGK) | 1 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | KO1300000 |
| 운송 번호(UN) | UN 1304 (VINYL ISOBUTYL ETHER, STABILIZED) |
| 독성 | rabbit,LD50,skin,20mL/kg (20mL/kg),American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. |
| 관세 코드 | 29091990 |
| 위험 문구(R) | 11-38-52/53 |
| 위험 표시 | F,Xi |
| 안전 문구(S) | 16-23-24/25-33-37-61 |
| 포장분류 | II |
| 위험 등급 | 3Aquatic Chronic 3Flam. Liq. 2Skin Irrit. 2 |
| 기존화학 물질 | KE-21461 |
| F 고인화성물질 | 9 |
| 저장 분류 | 3 - Flammable liquids |
용도
용도
Isobutyl vinyl ether is use in preparation method and formula of bulk polymerized Chloroether resin.
일반 설명
A clear colorless liquid. Flash point 15°F. May polymerize if contaminated or subjected to heat. If polymerization take place inside a container, the container may violently rupture. Vapors are heavier than air.