Vinyl isobutyl ether (HCID 7992)

개요

Vinyl isobutyl ether appears as a clear colorless liquid. May polymerize if contaminated or subjected to heat. If polymerization take place inside a container, the container may violently rupture. Vapors are heavier than air.

이름 및 식별자

우선 이름: Vinyl isobutyl ether
IUPAC: 1-ethenoxy-2-methylpropane
현지명: 이소부틸 비닐 에테르
영어명: Isobutyl vinyl ether
분자식: C6H12O
분자량: 100.16

이름 및 동의어

ISOBUTYL VINYL ETHER109-53-5Vinyl isobutyl etherPropane, 1-(ethenyloxy)-2-methyl-IsobutoxyetheneEther, isobutyl vinyl1-(ethenyloxy)-2-methylpropaneIsobutanol vinyl etherLutanol LR 85002-Methyl-1-vinyloxypropaneVinoflex MO 400*NSC 8265

이름 더 보기

비닐아이소뷰틸에테르아이소뷰틸비닐에테르이소부틸비닐에테르아이소뷰틸비닐에테르비닐 아이소뷰틸 에테르IVEvinoflexmo400*isobutoxy-ethene1-IsobutoxyetheneIsobutyl vinyl ethAllylisobutylether

Vinoflex MO 400iso-butyl vinyl etherDTXSID8029608EINECS 203-678-88HQ2X2D0TMUN1304BRN 1560159Vinyl isobutyl ether, inhibited

데이터베이스 식별자

CAS: 109-53-5
PubChem CID: 7992
DTXSID: DTXSID8029608
ChEMBL: CHEMBL3183612
UNII: 8HQ2X2D0TM
EC Number: 203-678-8
Nikkaji: J48.642F

물성

구조 계산 물성

XLogP: 2.2
극성 표면적: 9.2 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 3
무거운 원자 수: 7
형식 전하: 0
복잡도: 48.1

실험 및 물리화학적 성질

Chemical Classes · 2건

Other Classes -> Ethers, Other

Flammable agents - 3rd degree

SpringerMaterials PropertiesBoiling point

Flash Point15 °F (NFPA, 2010)

Vapor Pressure59.5 [mmHg]

Physical Description · 3건

Vinyl isobutyl ether appears as a clear colorless liquid. May polymerize if contaminated or subjected to heat. If polymerization take place inside a container, the container may violently rupture. Vapors are heavier than air.

Liquid

Clear colorless liquid; [CAMEO]

물리화학적 성질

녹는점: -112 °C · -112 °C
끓는 점: 83 °C · 83 °C
밀도: 0.769 · 0.769
증기 밀도: 3.45 · 3.45 (vs air)
증기압: 68 mm · 68 mm Hg ( 20 °C)
굴절률: 20 · n20/D 1.395(lit.)
인화점: 8 °F · 8 °F
저장 조건: Flammables area
물리적 상태: 투명한 액체
색상: 무색 내지 거의 무색
수용성: 0.7 g/L · 0.7g/L(25℃)
BRN: 1560159 · 1560159
Henry's Law Constant: 3.9 · 3.9×10-3 mol/(m3Pa) at 25℃, Raventos-Duran et al. (2010)
Dielectric constant: 3.34 · 3.3399999999999999
InChI: 1S/C6H12O/c1-4-7-5-6(2)3/h4,6H,1,5H2,2-3H3
InChIKey: OZCMOJQQLBXBKI-UHFFFAOYSA-N
SMILES: CC(C)COC=C
LogP: 3.07 at · 3.07 at 25℃
NIST: Vinylisobutyl ether(109-53-5)
EPA: 1 · Propane, 1-(ethenyloxy)-2-methyl- (109-53-5)

화학적 성질

Colorless liquid. Very slightly soluble in water; soluble in alcohol and ether; easily polymerized.

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 3.8% (8 of 213) of reports.

Danger

H225 (96.2%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P264, P264+P265, P273, P280, P302+P352, P303+P361+P353, P305+P351+P338, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P235, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 213 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

유해성 정보

Regulatory Information · 5건

Chemical: Propane, 1-(ethenyloxy)-2-methyl-

Propane, 1-(ethenyloxy)-2-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Propane, 1-(ethenyloxy)-2-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 31-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/2053

Propane, 1-(ethenyloxy)-2-methyl-: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid

Fire Hazards · 2건

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible); polymerization hazard]:

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Health Hazards · 2건

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible); polymerization hazard]:

· Inhalation or contact with material may irritate or burn skin and eyes.

Hazards Summary · 1건

May polymerize; Forms explosive peroxides on exposure to air; [CAMEO] A skin, eye, nose, and throat irritant; [NJ-HSFS] May form explosive peroxides; An irritant; [Sigma-Aldrich MSDS] Vinyl isobutyl ether, stabilized (UN1304) has warning of explosive polymerization; [ERG 2016]

DOT ID and Guide1304 127P

안전 및 보호

Fire FightingExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible); polymerization hazard]:

Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible); polymerization hazard]:

General First Aid:

Exposure Control and Personal Protection · 2건

· Wear positive pressure self-contained breathing apparatus (SCBA).

20.0 [ppm]

Nonfire Spill ResponseExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible); polymerization hazard]:

Isolation and Evacuation · 2건

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible); polymerization hazard]:

Immediate precautionary measure

독성 정보

Toxicity DataLCLo (rat) = 16,000 ppm/4hr

안전 데이터

wgk: 1
tsca: TSCA listed
rtecs: KO1300000
ridadr: UN 1304 (VINYL ISOBUTYL ETHER, STABILIZED)
독성: rabbit,LD50,skin,20mL/kg (20mL/kg),American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962.
HS 번호: 29091990
risk_code: 11-38-52/53
hazard_code: F,Xi
safety_code: 16-23-24/25-33-37-61
포장분류: II
위험 등급: 3
기존화학 물질: KE-21461
F 고인화성물질: 9
Hazard Classifications: Aquatic Chronic 3Flam. Liq. 2Skin Irrit. 2
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

용도 및 제조

Uses · 2건

Used in adhesives, coatings, and lacquers, as a resin modifier, plasticizer, and to make other chemicals; [NJ-HSFS]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

U.S. Production2023: <50,000 lb

Industry UsesIntermediate

General Manufacturing Information · 2건

All Other Basic Organic Chemical Manufacturing

Propane, 1-(ethenyloxy)-2-methyl-: ACTIVE

응용 분야

용도Isobutyl vinyl ether is use in preparation method and formula of bulk polymerized Chloroether resin.

일반 설명A clear colorless liquid. Flash point 15°F. May polymerize if contaminated or subjected to heat. If polymerization take place inside a container, the container may violently rupture. Vapors are heavier than air.