Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
N,N,N',N'-테트라메틸-1,6-헥사메틸렌디아민
N,N,N',N'-테트라메틸-1,6-헥사메틸렌디아민 · TMHD · TMHDA · N1,N1,N6,N6-TetraMethylhexane-1,6-diaMine · N,N,N,N-Tetramethyl-1,6-hexanediamine · 6-hexanediamine · u1000 · TMHMDA
식별자 및 물리적 특성
| CAS No. | 111-18-2 |
|---|---|
| 분자식 | C10H24N2 |
| 평균 분자량 | 172.31 g/mol |
| 단동위원소 질량 | 172.19394877 g/mol |
| SMILES | CN(C)CCCCCCN(C)C |
| InChIKey | TXXWBTOATXBWDR-UHFFFAOYSA-N |
| PubChem CID | 8097 |
| ChEMBL | CHEMBL118765 |
| EC No. | 203-842-9 |
| DTXSID | DTXSID5033701 |
| 현지명 | N,N,N',N'-테트라메틸-1,6-헥사메틸렌디아민 |
화학 및 물리적 성질
| XLogP | 1.7 |
|---|---|
| 극성 표면적 | 6.5 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 2 |
| 회전 가능 결합 수 | 7 |
| 무거운 원자 수 | 12 |
| 형식 전하 | 0 |
| 복잡도 | 77.8 |
| Physical Description | Liquid |
| 녹는점 | -46 °C |
| 끓는 점 | 209-210 °C(lit.) |
| 밀도 | 0.806 g/mL at 25 °C(lit.) |
| 증기압 | 12.4Pa at 20℃ |
| 굴절률 | n20/D 1.4359(lit.) |
| 인화점 | 165 °F |
| 저장 조건 | Sealed in dry,Room Temperature |
| 용해도 | 물과 섞임 |
| 물리적 상태 | 액체 |
| pKa(산도 계수) | 10.07±0.28(Predicted) |
| 색상 | 무색~황색으로 투명함 |
| 용해도 | 혼용 가능 |
| LogP(분배 계수) | 1.99 at 23℃ |
| NIST | (CH3)2N(CH2)6N(CH3)2(111-18-2) |
| EPA | N,N,N',N'-Tetramethyl-1,6-hexanediamine (111-18-2) |
화학적 성질
clear colorless to yellow liquid
안전 및 규제
| GHS 분류 | DangerH301+H311+H331 (23.9%): Toxic if swallowed, in contact with skin or if inhaled [Danger Acute toxicity, oralacute toxicity, dermalacute toxicity, inhalation]P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 264 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.WarningH227: Combustible liquid [Warning Flammable liquids] |
|---|---|
| 규제 정보 | Chemical: 1,6-Hexanediamine, N,N,N',N'-tetramethyl-1,6-Hexanediamine, N1,N1,N6,N6-tetramethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1,6-Hexanediamine, N1,N1,N6,N6-tetramethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 13-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/119201,6-Hexanediamine, N,N,N',N'-tetramethyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| Hazard Classes and Categories | Acute Tox. 3 (88.3%)Flammable liquids - Category 4 |
| 수질 위해 등급(WGK) | 1 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | MO1370000 |
| 운송 번호(UN) | UN 3390 6.1/PG 1 |
| 관세 코드 | 29212900 |
| 위험 문구(R) | 22-24-34-23/24 |
| 위험 표시 | T |
| 안전 문구(S) | 26-36/37/39-45 |
| 포장분류 | III |
| 위험 등급 | 8 |
| 기존화학 물질 | KE-33603 |
용도
용도
N,N,N'',N''-Tetramethyl-1,6-hexanediamine is used in the synthesis of fluorene containing poly(arylene ether sulfone) as anion exchange membranes for alkaline fuel cells.
제조 및 합성 방법
제조 방법
N,N,N',N'-Tetramethyl-1,6-hexanediamine can be made from adipodinitrile and dimethylamine or from 1,6- hexanediamine and formaldehyde.