1,3-Bis(diphenylphosphino)propane (HCID 81219)

이름 및 식별자

우선 이름: 1,3-Bis(diphenylphosphino)propane
IUPAC: 3-diphenylphosphanylpropyl(diphenyl)phosphane
현지명: 1,3- 비스 (디 페닐 포스 피노) 프로판
영어명: 1,3-Bis(diphenylphosphino)propane
분자식: C27H26P2
분자량: 412.45

이름 및 동의어

1,3-Bis(diphenylphosphino)propane6737-42-4Phosphine, 1,3-propanediylbis[diphenyl-DPPP cpdPhosphine, 1,3-propanediylbis(diphenyl-44R56E2C68NSC-193753DTXSID0064464RefChem:72524DTXCID30448871,3-B(DPP)PPhosphine, 1,1'-(1,3-propanediyl)bis(1,1-diphenyl)-

이름 더 보기

1,3-비스(디페닐포스피노)프로판1,3-BIS(DIPHENYLPHOSPHINE)PROPANE1,3-Bis(diphenylphosphanyl)propane1,3-bis(diphenyphosphino)propaneBis(1,3-diphenylphosphino)propane98% DPPP1,3-Bis(diphenyLphosphino)propanePH2PCH2 CH2CH2PPH21,3-BIS(DIPHENYPHOSPHINO)

229-791-2DPPP3-diphenylphosphanylpropyl(diphenyl)phosphaneMFCD00003050Trimethylenebis(diphenylphosphine)[3-(diphenylphosphanyl)propyl]diphenylphosphanePropane-1,3-diylbis(diphenylphosphine)1,3-Propanediylbis(diphenylphosphine)

데이터베이스 식별자

CAS: 6737-42-4
PubChem CID: 81219
DTXSID: DTXSID0064464
ChEMBL: CHEMBL73394
UNII: 44R56E2C68
EC Number: 229-791-2
Nikkaji: J208.099K

물성

구조 계산 물성

XLogP: 6.2
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 8
무거운 원자 수: 29
형식 전하: 0
복잡도: 350

물리화학적 성질

녹는점: 63 · 63-65 °C (lit.)
끓는 점: 529.7 · 529.7±33.0 °C(Predicted)
인화점: 235 °C · 235°C
저장 조건: Inert atmosphere,Room Temperature
물리적 상태: 과립 또는 분말
색상: 흰색에서 밝은 노란색-베이지색
수용성: 불용성
BRN: 2821785 · 2821785
InChI: InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKey: LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES: P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
NIST: 1 · 1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA: 1 · Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)

화학적 성질

white to light yellow crystal powde

안전 및 규제

GHS 분류

GHS Classification · 5건

Warning

H302 (64.7%): Harmful if swallowed [Warning Acute toxicity, oral]；H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (64.7%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (99.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H400 (64.7%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]；H410 (65.4%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 153 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory InformationPMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Hazard Classes and CategoriesAcute Tox. 4 (64.7%)；Skin Irrit. 2 (100%)；Skin Sens. 1 (64.7%)；Eye Irrit. 2 (100%)；STOT SE 3 (99.3%)；Aquatic Acute 1 (64.7%)；Aquatic Chronic 1 (65.4%)

규제 정보

Regulatory InformationPMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

안전 데이터

wgk: 3
tsca: TSCA listed
HS 번호: 29310095
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-37/39-36
F 고인화성물질: 10-23
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

용도 및 제조

General Manufacturing InformationPhosphine, 1,1'-(1,3-propanediyl)bis[1,1-diphenyl-: ACTIVE

응용 분야 · 3건

개요청정:최소 98%；외관：백색 고체.

개요1,3-Bis(diphenylphosphino)propane is a ligand for metal-catalyzed substitution reactions of aryl and vinyl triflates, halides, and carbonates; carbonylation reactions; Grignard coupling; diene alkylation; macrocycle synthesis.

용도1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

INTATRADE GmbH+49 3493/605464 · [email protected]

연결된 노트

불러오는 중…

1,3- 비스 (디 페닐 포스 피노) 프로판

기본 정보