Methyl morpholine oxide (HCID 82029)

개요

N-methylmorpholine N-oxide is a morpholine N-oxide resulting from the oxidation of the amino group of N-methylmorpholine.

이름 및 식별자

우선 이름: Methyl morpholine oxide
IUPAC: 4-methyl-4-oxidomorpholin-4-ium
현지명: 4-메틸모르폴린 4-산화물
영어명: 4-Methylmorpholine N-oxide
분자식: C5H11NO2
분자량: 117.15

이름 및 동의어

7529-22-84-Methylmorpholine 4-oxideN-Methylmorpholine oxideN-Methylmorpholine N-oxideMorpholine, 4-methyl-, 4-oxideMethyl morpholine oxide4-Methylmorpholine-4-oxide4-Methylmorpholine Oxide4-methylmorpholine-N-oxideN-Methylmorpholine 4-oxideNSC 73198NSC 82153

이름 더 보기

4-메틸모르폴린4-산화물4-메틸모르폴린4-산화물(4-METHYLMORPHOLINE4-OXIDE)메틸모폴린옥사이드4-메틸모폴린 N-옥사이드4-메틸모르폴린N-옥사이드NMO4-methyl-morpholin4-oxideMMNO4-methyl-4-oxidomorpholin-4-ium4-methylmorpholine n-oxide solution4-MethylMorpholin-4-iuM-4-olate

DTXSID3029287EINECS 231-391-8NSC-73198NSC-821534-methylmorpholine 4-oxide, monohydrateDTXCID509287CHEBI:52093EC 231-391-8

데이터베이스 식별자

CAS: 7529-22-8
PubChem CID: 82029
DTXSID: DTXSID3029287
ChEMBL: CHEMBL3184330
ChEBI: CHEBI:52093
UNII: ARC64PKJ0F
EC Number: 231-391-8
Nikkaji: J256.599D

물성

구조 계산 물성

XLogP: -0.7
극성 표면적: 27.3 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 2
회전 가능 결합 수: 0
무거운 원자 수: 8
형식 전하: 0
복잡도: 78.5

실험 및 물리화학적 성질

Chemical ClassesNitrogen Compounds -> Amine Oxides

CosmeticsCleansing; Foam boosting; Surfactant

Physical Description · 2건

Liquid

White hygroscopic solid; [Merck Index] Light yellow crystalline solid; [Sigma-Aldrich MSDS]

물리화학적 성질

녹는점: 180 · 180-184 °C(lit.)
끓는 점: 118 · 118-119°C
밀도: 1 · 1,14 g/cm3
증기압: 1.41 hPa · 1.41hPa at 20℃
굴절률: 20 · n20/D 1.43
인화점: 118 · 118-119°C
저장 조건: 2 · 2-8°C
용해도: DMSO(용해성), 메탄올(약간)에 용해됨
물리적 상태: 액체
산도 계수 (pKa): 4.93 · 4.93±0.20(Predicted)
색상: 무색~황색으로 투명함
수소이온지수(pH): 9 · 9.00 ( in neat)
수용성: 물, 메탄올, 에탄올, 아세톤, 에테르 및 디메틸설폭사이드에 용해됩니다.
BRN: 507437 · 507437
안정성: 흡습성
화장품 원료 기능: 계면활성제 - 거품 증진제계면활성제 - 세정세척제
InChI: 1S/C5H11NO2/c1-6(7)2-4-8-5-3-6/h2-5H2,1H3
InChIKey: LFTLOKWAGJYHHR-UHFFFAOYSA-N
SMILES: C[N+]1([O-])CCOCC1
LogP: -1.2 at · -1.2 at 25℃
NIST: N-Methylmorpholine-N-oxide(7529-22-8)
EPA: 4 · Morpholine, 4-methyl-, 4-oxide (7529-22-8)

화학적 성질

Clear colorless to yellow solution

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 0.5% (1 of 202) of reports.

Danger

H228 (66.8%): Flammable solid [Danger Flammable solids]

P203, P210, P220, P240, P241, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P318, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 202 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 4건

Chemical: Morpholine, 4-methyl-, 4-oxide

Morpholine, 4-methyl-, 4-oxide is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Morpholine, 4-methyl-, 4-oxide are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 12-12-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/15946

Morpholine, 4-methyl-, 4-oxide: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1건

An irritant; [Merck Index] An oxidizer that may intensify fire; [ECHA REACH Registrations] A skin and strong eye irritant; May cause allergic reactions in sensitive individuals, based on QSAR modeling; [Sigma-Aldrich MSDS] Search for (7529-22-8[EC/RN Number]) AND (allergic OR sensitizer OR sensitization OR dermatitis): no results; [PubMed]

Hazard Classes and CategoriesFlam. Sol. 1 (66.8%)

안전 데이터

wgk: 1
tsca: TSCA listed
HS 번호: 29349990
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36/37
기존화학 물질: 97-3-137
Hazard Classifications: Flam. Sol. 1Repr. 2
스토리지 클래스: 4.1B - Flammable solid hazardous materials

화학 및 산업

용도 및 제조

Uses · 2건

Used as a reagent in synthetic organic chemistry and commercially for swelling and dissolution of cellulose; [Merck Index] Used as an intermediate, to make flexible and rigid polyurethane foams, as a solvent in synthetic fiber production, and in industrial and professional coatings, adhesives, and sealants; [ECHA REACH Registrations]

Textiles (Fiber & Fabric Manufacturing) [Category: Industry]

U.S. Production2023: 500,000 - <1,000,000 lb

Industry UsesOther

Use ClassificationCosmetics -> Cleansing; Foam boosting; Surfactant

General Manufacturing Information · 2건

Organic Fiber Manufacturing

Morpholine, 4-methyl-, 4-oxide: ACTIVE

응용 분야 · 2건

용도4-Methylmorpholine N-Oxide is a metabolite of Morpholine (M723725). N-Methylmorpholine N-Oxide is commonly used to dissolve cellulose as well as in the dissolution of of scleroproteins.

일반 설명4-MethylmorpholineN-oxide is an organic compound used as a co-oxidant along with OsO4 and ruthenates in organic synthesis. In recent studies, it has been used as a catalyst in silylcyanation of aldehydes and ketones. Lyocell, a regenerated cellulose fiber, can be prepared using 4-methylmorpholineN-oxide in an eco-friendly manner.

상·하류 제품 정보

상류 원료

하류 제품

4-메틸-2-옥소-2H-크롬-7-카르발데히드 N-Boc-4-oxo-L-Proline methyl ester 4-메틸모르폴린N-옥사이드일수화물 4-Bromo-2-nitroaniline N,N'-디모르폴리메탄 Boc-4-oxo-L-proline tert-butyl ester 프레그네디온

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

济南氟泽新材料有限公司00-15169181 15169181281 · [email protected]

연결된 노트

불러오는 중…

4-메틸모르폴린 4-산화물

기본 정보

개요