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브롬화리튬

Lithium Bromide

HCID 82050
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
7550-35-8
표준 SMILES
[Br-].[Li+]
InChIKey
AMXOYNBUYSYVKV-UHFFFAOYSA-M
분자식
BrLi
평균 분자량
86.9 g/mol
단동위원소 질량
85.93434165

개요

Lithium bromide is a lithium salt in which the counterion is bromide. The anhydrous salt forms cubic crystals similar to common salt. It is a bromide salt and a lithium salt.

이름 및 식별자

우선 이름
Lithium Bromide
IUPAC
lithium bromide
현지명
브롬화리튬
영어명
Lithium bromide
분자식
BrLi
분자량
86.85

이름 및 동의어

Lithium bromide7550-35-8Lithium monobromideLithium bromide (LiBr)bromolithiumLITHIUM BROMATUM864G646I84CHEBI:63042DTXSID20892222RefChem:55513DTXCID801079305231-439-8
이름 더 보기
브로민화리튬브롬화리튬브로민화리튬LITHIUM HALIDEAnhydrous lithiuM broMideithium bromideLithiumbromide,dihydrateLITHIUM BROMIDE ANYDROUSLithium bromide, extra pure, 99.999%Lithium bromide anhydrous, free-flowing, Redi-Dri, ReagentPlus, >=99%
LITHIUMBROMIDELiBrlithium;bromideBrLiLithium bromide anhydrousLITHIUM BROMIDE, ANHYDROUSMFCD00011077LIthium bromide solution

데이터베이스 식별자

CAS
7550-35-8
PubChem CID
82050
DTXSID
DTXSID20892222
ChEBI
CHEBI:63042
UNII
864G646I84
EC Number
231-439-8
Nikkaji
J43.853G

물성

구조 계산 물성보충 중

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
2
형식 전하
0
복잡도
2

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesdielectric constant
Density3.464 @25 °C
Melting Point550 °C
Physical Description · 2건

Dry Powder; Wet Solid; Dry Powder

Highly deliquescent white solid; [Merck Index] White powder, crystals, or beads; Hygroscopic; [Alfa Aesar MSDS]

물리화학적 성질

녹는점
550 °C · 550 °C (lit.)
끓는 점
1265 °C · 1265 °C
밀도
1.57 g/mL · 1.57 g/mL at 25 °C
증기압
1 hPa · 1 hPa ( 748 °C)
인화점
1265 °C · 1265°C
저장 조건
Inert atmosphere,Room Temperature
용해도
메탄올(약간 용해됨, 가열), 물(약간 용해됨)
산도 계수 (pKa)
2.64 · 2.64[at 20 ℃]
물리적 상태
가루
Specific Gravity

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Warning

H302 (98.2%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P272, P280, P301+P317, P302+P352, P305+P351+P338, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 279 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

유해성 정보

Regulatory Information · 4건

Chemical: Lithium bromide (LiBr)

Lithium bromide (LiBr) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Lithium bromide (LiBr) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/13642

Lithium bromide: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Lithium bromide (LiBr): Human health tier I assessment
Hazards Summary · 1건

Causes flaccid paralysis with appropriate anesthesia, tetany, and arrhythmias in oral lethal-dose studies of mice; [RTECS] High doses may cause CNS depression and disturbed blood electrolyte balance; Chronic exposure may cause skin eruptions and adverse CNS effects; [Merck Index] A skin and strong eye irritant; Harmful by ingestion; [Alfa Aesar MSDS] See Lithium and Bromine.

Hazard Classes and Categories · 4건

Acute Tox. 4 (98.2%)

Acute toxicity (Oral) - Category 4

Skin sensitization - Category 1B

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

FDA Pharmacological Classification · 2건

LITHIUM BROMATUM

Mood Stabilizer [EPC]

용도 및 제조

UsesUsed as a humectant and sedative/hypnotic; [Merck Index]
U.S. Production2023: 100,000 - <250,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesIntermediate
General Manufacturing Information · 2건

Petroleum Refineries

Lithium bromide (LiBr): ACTIVE

응용 분야 · 2건

용도As humectant, in air-conditioning systems. An aqueous solution of lithium bromide containing about 50 % lithium bromide is used as an absorbent in large-scale absorption air conditioning equipment. Lithium bromide is also used in limited amounts by the pharmaceutical industry for dehydrobromination of organic compounds to form olefins.

일반 설명LiBr/Chlorotrimethylsilane reagent participates in the conversion of alcohols to bromides.

제조 방법 · 1건

Lithium bromide may be prepared by the reaction of lithium hydroxide monohydrate or lithium carbonate with hydrobromic acid. The resultant solution of lithium bromide may be evaporated and cooled to crystallize a hydrate of lithium bromide, the composition of which depends on the final temperature. The lithium bromide hydrate may be filtered from the mixture and carefully dried by the application of heat in a vacuum desiccator to avoid melting the hydrate.

관련 반응

948건
반응 기록 만들기
HRID 2542 반응식
HRID 2542반응물로uspto-grants-1998_03
HRID 2576 반응식
HRID 2576반응물로uspto-grants-1998_03
HRID 6283 반응식
HRID 6283반응물로uspto-grants-1993_09
HRID 9736 반응식
HRID 9736반응물로uspto-grants-2006_08
HRID 11999 반응식
HRID 11999촉매로uspto-grants-2010_06
HRID 18710 반응식
HRID 18710반응물로uspto-grants-2010_06
HRID 23784 반응식
HRID 23784반응물로uspto-grants-2005_02
HRID 31556 반응식
HRID 31556반응물로uspto-grants-2008_09
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화합물 노트

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이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
더보기
새 노트새 반응견적 요청하기
3.464 · 3.464
색상
하얀색
수소이온지수(pH)
7 · 7 (20°C, 10g/L)
냄새
냄새 없는
수용성
61 g/100mL · 61g/100mL(25℃)
Merck
14 · 14,5526
안정성
안정적인. 무수 형태는 흡습성이 매우 높습니다.
InChI
1S/BrH.Li/h1H;/q;+1/p-1
InChIKey
AMXOYNBUYSYVKV-UHFFFAOYSA-M
SMILES
[Li+].[Br-]
LogP
-0.37 at · -0.37 at 25℃
NIST
Lithium bromide(7550-35-8)
EPA
Lithium bromide (7550-35-8)
화학적 성질 · 1건

White cubic crystals; hygroscopic; refractive index 1.784; density 3.464 g/cm3; melts at 550°C; vaporizes at 1,265°C; highly soluble in water (145g/100g at 4°C), much greater solubility in hot water (254g/100g at 90°C); soluble in methanol, ethanol and ether; slightly soluble in pyridine; vapor pressure of aqueous solutions at 52 and 68% concentrations at 25°C are 5 and 0.7 torr, respectively.

Acute toxicity (Oral) - Category 4

안전 및 보호

Exposure Control and Personal Protection0.2 [mg/m3], inhalable fraction, as Li[German Research Foundation (DFG)]
Protective Action Criteria (PAC) · 3건

1.5 [mg/m3]

17 [mg/m3]

100 [mg/m3]

독성 정보

Treatment · 1건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Adverse EffectsNeurotoxin - Other CNS neurotoxin
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1건

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).
Toxicity DataLD50: 1800 mg/kg (Oral, Rat) (L661) LD50: 1680 mg/kg (Subcutaneous, Mouse) (L660)

안전 데이터

wgk
2
tsca
TSCA listed
rtecs
OJ5755000
HS 번호
2827590000
risk_code
32-40-43-36/37 -36/37/38 -36/38
hazard_code
Xi
safety_code
22-26-60-24/25-36/37-36/37/39
기존화학 물질
KE-22549
F 고인화성물질
3
Hazard Classifications
Acute Tox. 4 OralEye Irrit. 2Skin Irrit. 2Skin Sens. 1
스토리지 클래스
13 - Non Combustible Solids

상·하류 제품 정보

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Iron filings하이드록시 리튬탄산, 리튬 염브롬화수소브롬

하류 제품

2-(3-Bromo-propyl)-1H-benzoimidazole1-Methoxy-3-trimethylsiloxy-1,3-butadiene브롬화 나트륨트리스(트리메틸실릴)실란리튬 보로수소화물트리 -tert- 부틸 포스 핀Bromotris(triphenylphosphine)rhodium(I)

추가 설명

정의ChEBI: A lithium salt in which the counterion is bromide. The anhydrous salt forms cubic crystals similar to common salt.