| GHS 분류 | This chemical does not meet GHS hazard criteria for 3.1% (75 of 2412) of reports.DangerH315 (13.3%): Causes skin irritation [Warning Skin corrosion/irritation]H318 (19.9%): Causes serious eye damage [Danger Serious eye damage/eye irritation]H319 (12.7%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]H400 (72.8%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]H410 (64.5%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]P264, P264+P265, P273, P280, P302+P352, P305+P351+P338, P305+P354+P338, P317, P321, P332+P317, P337+P317, P362+P364, P391, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 2412 reports by companies from 24 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Reported as not meeting GHS hazard criteria per 75 of 2412 reports by companies.There are 23 notifications provided by 2337 of 2412 reports by companies with hazard statement code(s).Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
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| 규제 정보 | Chemical: 1-TridecanolChemical: Alcohols, C12-141-Tridecanol is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Tridecanol are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 01-08-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/17453Status: Active Update: 30-05-2016 https://echa.europa.eu/registration-dossier/-/registered-dossier/17503Status: Active Update: 09-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/175321-Tridecanol: Does not have an individual approval but may be used under an appropriate group standard |
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| 기타 안전 정보 | IMAP assessments - Alcohols, C12-14: Human health tier I assessmentIMAP assessments - 1-Tridecanol: Human health tier I assessment |
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| 화재 위험 | Combustible. (USCG, 1999) |
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| 화재 가능성 | MODERATE TO SLIGHT, WHEN EXPOSED TO HEAT OR FLAMECombustible liquid when exposed to heat or flame. |
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| 건강 유해성 | Not harmful. (USCG, 1999) |
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| 유해성 요약 | A skin and eye irritant[ICSC] A mild skin irritant, based on animal studies[MSDSonline] See 1-Decanol.A severe eye irritant[CHRIS] Causes CNS depression in animal experiments[RTECS] An irritant |
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| FDA 요건 | Tridecyl alcohol is an indirect food additive for use only as a component of adhesives. |
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| 반응성 그룹 | Alcohols and Polyols |
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| Reactivity Profile | TRIDECANOL is an alcohol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. |
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| Chemical Dangers | Reacts with strong reducing agents. This generates heat and flammable/explosive gas (hydrogen - see ICSC 0001). Attacks aluminium. |
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| Air and Water Reactions | Insoluble in water. |
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| NFPA Hazard Classification | 0 - Materials that, under emergency conditions, would offer no hazard beyond that of ordinary combustible materials.1 - Materials that must be preheated before ignition can occur. Materials require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur.0 - Materials that in themselves are normally stable, even under fire conditions. |
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| 소화 | Extinguish with dry chemical or alcohol foam. Water may be ineffective on fire. Cool exposed containers with water. (USCG, 1999)Use water spray, powder, alcohol-resistant foam, carbon dioxide. |
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| 응급 조치 | Fresh air, rest.Rinse and then wash skin with water and soap.First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.Rinse mouth. |
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| 응급 처치 | EYES: promptly flush with clean water for at least 15 minutes and see a physician.SKIN: wash exposed area with soap and water. (USCG, 1999) |
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| 안전 보관 | Separated from strong reducing agents. Store only in original container. Do NOT store or transport in containers made from aluminium. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing. |
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| 소화 절차 | MIST, SPRAY, DRY CHEMICAL, FOAMTo fight fire use mist, spray, dry chemical, foam.Alc foam, dry chem, water fog. ...Water may cause frothing. /Mixed isomers/ |
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| 정리 방법 | AEROBIC: 1-Tridecanol, present at 100 mg/L, reached 100% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L and the Japanese MITI test(1). The zero order and first order biodegradation rates of 1-tridecanol in activated sludge were 1.04X10-2 ppm/hr and 5.2X10-3 1/hr, respectively(2). Using this first order degradation rate, the half-life of 1-tridecanol can be calculated as 5.6 days(SRC).If in liquid state: collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. If in solid state: sweep spilled substance in sealable container, carefully collect remainder then remove to safe place. |
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| 비화재 누출 대응 | Stop discharge if possible. Isolate and remove discharged material. Notify local health and pollution control agencies. (USCG, 1999) |
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| 처리 방법 | SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air qualitypotential migration in soil or watereffects on animal, aquatic, and plant lifeand conformance with environmental and public health regulations. |
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| 누출 처리 | Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. If liquid: collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. If solid: sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. |
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| Preventive Measures | SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place. |
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| Eye Prevention | Wear safety spectacles. |
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| Fire Prevention | NO open flames. |
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| 체내 부담 | 1-Tridecanol has been qualitatively detected in one sample of human adipose tissue from a 45 and over age group in the North Central Region of the United States(1). |
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| 생태독성 수치 | EC50 Tetrahymena pyriformis (Ciliatedecreased population growth) 1.05 mg/L/48 hrstatic /formulated product/ |
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| 환경 거동 | TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 35,000(SRC), determined from a log Kow of 5.82(2) and a regression-derived equation(3), indicates that 1-tridecanol is expected to be immobile in soil(SRC). Volatilization of 1-tridecanol from moist soil surfaces is expected to be an important fate process(SRC) given an estimated Henry's Law constant of 1.3X10-4 atm-cu m/mole(SRC), using a fragment constant estimation method(4). However, adsorption to soil is expected to attenuate volatilization(SRC). 1-Tridecanol is not expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 4.36X10-4 mm Hg(5). A biodegradation half life of 5.6 days(SRC) can be calculated, using a first order degradation rate of 5.2X10-3 1/hr(6), suggesting that biodegradation may be an important environmental fate process in soil(SRC).AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 35,000(SRC), determined from a log Kow of 5.82(2) and a regression-derived equation(3), indicates that 1-tridecanol is expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is expected(3) based upon an estimated Henry's Law constant of 1.3X10-4 atm-cu m/mole(SRC), developed using a fragment constant estimation method(4). Using this Henry's Law constant and an estimation method(3), volatilization half-lives for a model river and model lake are 14 hours and 8.5 days, respectively(SRC). However, volatilization from water surfaces is expected to be attenuated by adsorption to suspended solids and sediment in the water column. The estimated volatilization half-life from a model pond is 16 years if adsorption is considered(5). According to a classification scheme(6), an estimated BCF of 600(SRC), from its log Kow(2) and a regression-derived equation(7), suggests the potential for bioconcentration in aquatic organisms is high(SRC). A biodegradation half-life of 5.6 days(SRC) can be calculated, using a first order degradation rate of 5.2X10-3 1/hr(8), suggesting that biodegradation may be an important environmental fate process in water(SRC).ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), 1-tridecanol, which has a vapor pressure of 4.36X10-4 mm Hg at 25 °C(2), is expected to exist solely as a vapor in the ambient atmosphere. Vapor-phase 1-tridecanol is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC)the half-life for this reaction in air is estimated to be 20 hours(SRC), calculated from its rate constant of 1.96X10-11 cu cm/molecule-sec at 25 °C(SRC) that was derived using a structure estimation method(3). |
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| 식품 조사 수치 | 1-Tridecanol has qualitatively been detected as a volatile component of beef(1). |
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| 유해 작용 | Neurotoxin - Acute solvent syndrome |
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| 생태독성 발췌 | /AQUATIC SPECIES/ The general anesthetic potency of several members of the homologous series of saturated aliphatic alcohols, including 1-tridecanol, was determined in tadpoles, using the loss of righting reflex as the criterion of anesthesia. 1-Tridecanol was found to be a partial anesthetic. |
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| Plant Concentrations | 1-Tridecanol emission rates from green leaf composite samples and dead leaves were 5.5 ug/g and 51 ug/g, respectively(1). |
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| Signs and Symptoms | Redness.Redness. Pain. |
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| Effluent Concentrations | 1-Tridecanol emission rate from paved road dust was 1.7 ug/g(1). |
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| ICSC Environmental Data | The substance is toxic to aquatic organisms. |
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| Soil Adsorption/Mobility | The Koc of 1-tridecanol is estimated as 35,000(SRC), using a log Kow of 5.82(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that 1-tridecanol is expected to be immobile in soil. |
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| Natural Pollution Sources | 1-Tridecanol emission rates from green leaf composite samples and dead leaves were 5.5 ug/g and 51 ug/g, respectively(1). |
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| 독성 | skn-rbt 410 mg open MLD UCDS** 10/14/64 |
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