CAS 7688-51-9 N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine (HCID 82125)

이름 및 식별자

우선 이름: N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine
IUPAC: N,N-bis(trimethylsilyl)prop-2-en-1-amine
영어명: N-Allyl-n N-bis(trimethylsilyl)amine
분자식: C9H23NSi2
분자량: 201.46

이름 및 동의어

7688-51-9N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamineEINECS 231-699-2DTXSID50227684Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-RefChem:828934DTXCID00150175231-699-2N,N-Bis(trimethylsilyl)allylamineN-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINEN,N-bis(trimethylsilyl)prop-2-en-1-amineN-Allyl-N,N-bis(trimethylsilyl)amine

이름 더 보기

Ditrimethylsilyl allylamineN,N'-bis(trimethylsilyl)allylamineProp-2-en-1-ylbis(trimethylsilyl)amineN-Allyl-N,N-bis(trimethylsilyl)amine 97%2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&

3-Bis(trimethylsilyl)amino-1-propene(prop-2-en-1-yl)bis(trimethylsilyl)amineMFCD00545193N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamineC9H23NSi2Allylbis(trimethylsilyl)amine578932_ALDRICH, EINECS 231-699-2, MolPort-003-937-319, N,N-Bis(trimethylsilyl)allylamine, CID82125, N-Allyl-N,N-bis(trimethylsilyl)amine, N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine, Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-, 7688-51-9AHL726ZXM9

데이터베이스 식별자

CAS: 7688-51-9
PubChem CID: 82125
DTXSID: DTXSID50227684
UNII: AHL726ZXM9
EC Number: 231-699-2
Nikkaji: J125.864H

물성

구조 계산 물성

극성 표면적: 3.2 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 4
무거운 원자 수: 12
형식 전하: 0
복잡도: 139

물리화학적 성질

끓는 점: 72 °C/15 · 72 °C/15 mmHg (lit.)
밀도: 0.816 g/mL · 0.816 g/mL at 25 °C (lit.)
굴절률: 20 · n20/D 1.440(lit.)
인화점: 109 °F · 109 °F
물리적 상태: 액체
Specific Gravity: 0.817 · 0.817
InChI: 1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
InChIKey: CVNCFZIIZGNVFD-UHFFFAOYSA-N
SMILES: C[Si](C)(C)N(CC=C)[Si](C)(C)C

안전 및 규제

GHS 분류

GHS Classification · 5건

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]；H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 2건

Chemical: Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Hazard Classes and CategoriesFlam. Liq. 3 (100%)；Skin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (100%)

규제 정보

Regulatory Information · 2건

Chemical: Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 3
risk_code: 10-36/37/38
hazard_code: Xi
safety_code: 16-26-36/37
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

용도 및 제조

General Manufacturing InformationSilanamine, 1,1,1-trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)-: ACTIVE

응용 분야 · 1건

용도N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare: Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions. Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride. Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.