Potassium hydride (HCID 82127)

개요

Potassium hydride is an alkali metal hydride.

이름 및 식별자

우선 이름: Potassium hydride
IUPAC: potassium hydride
현지명: 수소화칼륨
영어명: Potassium hydride
분자식: HK
분자량: 40.11

이름 및 동의어

PotassiumhydridePotassium hydride7693-26-7potassium;hydridePotassium hydride (KH)KaliumhydridSCHEMBL266SCHEMBL3334[KH]CHEBI:32589DTXSID10894770CS0062

이름 더 보기

수소화칼륨포타슘 하이드라이드KHHK-9PotassiuM hydridpotassiumhydride(kh)Potassium monohydrideHydrogen potassium saltPotassiumhydride,30-35%inoilPotassiuM hydride in paraffin

MFCD00011357AKOS015833247Q6036

데이터베이스 식별자

CAS: 7693-26-7
PubChem CID: 82127
ChEBI: CHEBI:32589

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 1
형식 전하: 0
복잡도: 0

물리화학적 성질

녹는점: 10 · decomposes [CRC10]
끓는 점: 316 °C · 316 °C
밀도: 1.54 · 1.54
인화점: 113 °C · 113 °C
저장 조건: Flammables + water-Freezer (-20°C)e area
용해도: 벤젠, 디에틸 에테르 및 이황화 탄소에 용해되지 않습니다.
물리적 상태: 분산(미네랄 오일(~35%))
색상: 그레이쉬 베이지
수용성: 2 O · H2O [CRC10]에 의해 분해됨
InChI: 1S/K.H
InChIKey: NTTOTNSKUYCDAV-UHFFFAOYSA-N
SMILES: [K]
EPA: Potassium hydride (KH) (7693-26-7)

화학적 성질 · 1건

Potassium hydride is available in laboratory quantities only as a 20 – 35 % dispersion in oil. Potassium hydride is a considerably stronger base than lithium hydride or sodium hydride. It is able to remove protons from tertiary alcohols and ketones, a reaction that either does not occur or is very slow when sodium hydride is used. Potassium hydride also reacts with weak Lewis acids, converting sterically hindered boron trialkyls to the corresponding sterically hindered complex borohydrides:

안전 및 규제

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 1409 4.3/PG 1
HS 번호: 28500090
risk_code: 11-14/15-34
hazard_code: F,C
safety_code: 16-26-27-36/37/39-45-43
포장분류: I
위험 등급: 4.3
기존화학 물질: KE-29123
자연 발화 온도: Ignites spontaneously at room temperature in moist air
Hazard Classifications: Eye Dam. 1Skin Corr. 1BWater-react 1
스토리지 클래스: 4.3 - Hazardous materials which set free flammable gases upon contact with water

화학 및 산업

응용 분야

용도Potassium Hydride is used in preparation of Hydroxy-Xanthone derivatives via Isoprenylation followed by Claisen rearrangement starting from Fluoroxanthone derivatives.

일반 설명This product has been enhanced for energy efficiency.

상·하류 제품 정보

상류 원료

수소 칼륨

하류 제품

Indole-5-carboxaldehyde 1-METHYL-1H-INDOLE-5-BORONIC ACID 2,2-DIMETHYL PROPANE DIOL-1,3-CYCLIC ESTER 5-아세틸린돌 Indole-4-boronic acid 2-Oxo-(2H)-furo(2,3-h)-1-benzopyran 5-Indolylboronic acid

공급사41 곳

上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]

上海晶抗生物工程有限公司021-54721350 13524668266 · [email protected]

阿法埃莎（中国）化学有限公司400-6106006 · [email protected]

安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]

上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]

추가 설명 · 1건

정의potassium hydride: A white orgreyish white crystalline solid, KH;r.d. 1.43–1.47. It is prepared by passinghydrogen over heated potassiumand marketed as a light grey powderdispersed in oil. The solid decomposeson heating and in contact withmoisture and is an excellent reducingagent. Potassium hydride is a firehazard because it produces hydrogenon reaction with water.