요오드 모노브롬화물

Iodine bromide (IBr)

HCID 82238CAS 7789-33-5

기본 정보

표준 SMILES
BrI
InChIKey
CBEQRNSPHCCXSH-UHFFFAOYSA-N
분자식
BrI
평균 분자량
206.81 g/mol
단동위원소 질량
205.8228101

개요

used for analysis of phenols; RN given refers to cpd with MF Br-I

이름 및 식별자

우선 이름
Iodine bromide (IBr)
현지명
요오드 모노브롬화물
영어명
Iodine monobromide
분자식
BrI
분자량
206.81

이름 및 동의어

Iodine monobromide7789-33-5Iodine bromide (IBr)Iodobrominebromine monoiodideG0K622RD9NDTXSID2064862RefChem:148491DTXCID4048066232-159-9Iodine bromideMFCD00011353
이름 더 보기
요오드모노브롬화물요오드모노브롬화물(IODINEMONOBROMIDE)IBrIODOBROMIDEHANUS SOLUTIONBromo iodideBROMINE IODIDEIODOMONOBROMIDE
BromoiodineIodine monobromide; IodobromineiodobromaneiodbromideUNII-G0K622RD9NJodmonobromidbromonium iodideiodonium bromide

데이터베이스 식별자

CAS
7789-33-5
PubChem CID
82238
DTXSID
DTXSID2064862
UNII
G0K622RD9N
EC Number
232-159-9
Nikkaji
J96.353D

물성

구조 계산 물성

XLogP
1.8
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
2

실험 및 물리화학적 성질

Chemical ClassesOther Classes -> Halogenated Aliphatics, Saturated
Density4.3 g/cu cm
Color/Form · 4건

Crystals, purplish-black mass

Black orthorhombic crystals

Dark red solid

Brownish-black crystals or very hard solid

Solubility · 4건

Soluble in water

Soluble in water with decomposition

Soluble in carbon disulfide, glacial acetic acid

Soluble in alcohol, ether

Boiling Point116 °C (decomposes)
DecompositionWhen heated to decomposition it emits toxic fumes of /hydrogen bromides and iodides/.

물리화학적 성질

녹는점
42 · 42-50 °C (lit.)
끓는 점
116 °C · 116 °C
밀도
4.416 g/mL · 4.416 g/mL at 25 °C (lit.)
인화점
116 °C · 116°C
저장 조건
2 · 2-8°C
용해도
수용성 염기(약간 용해됨), 메탄올(약간 용해됨), 물(약간 용해됨)
화학적 성질 · 1건

A dark grey to brownish-black crystalline mass that can be dissolved in ethanol, ether, chloroform, carbon disulphide, and other solvents. When it is heated, it becomes partially dissociated. It can prepared by the action of iodine with bromine in a stream of nitrogen. It is used in organic synthesis.

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 2% (1 of 50) of reports.

Danger

H314 (98%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P319, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 50 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

유해성 정보

Regulatory Information · 2건

Chemical: Iodine bromide (IBr)

Iodine monobromide: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1건

Vapors corrosive to mucous membranes and eyes; [Merck Index] Corrosive to skin and eyes; [eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Bromine. See Iodine.

Toxic Combustion ProductsSpecial hazards arising from the substance or mixture: Hydrogen bromide gas, Hydrogen iodide.
Hazard Classes and CategoriesSkin Corr. 1B (98%)
Hazardous Reactivities and IncompatibilitiesIncompatible materials: Forms shock-sensitive mixtures with certain other materials., Alcohols, Phosphorus, Sodium/sodium oxides, Potassium.

안전 및 보호

Fire Fighting Procedures · 2건

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary.

Storage ConditionsKeep container tightly closed in a dry and well-ventilated place. Recommended storage temperature 2 - 8 °C Air, light, and moisture sensitive. Store under inert gas.
Cleanup Methods · 1건

ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions: Do not let product enter drains. Methods and materials for containment and cleaning up: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

Disposal Methods · 2건

SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in air, soil or water; effects on animal, aquatic and plant life; and conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.

Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber; Contaminated packaging: Dispose of as unused product.

Preventive Measures · 5건

ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions: Do not let product enter drains.

Precautions for safe handling: Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.

Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

SRP: Local exhaust ventilation should be applied wherever there is an incidence of point source emissions or dispersion of regulated contaminants in the work area. Ventilation control of the contaminant as close to its point of generation is both the most economical and safest method to minimize personnel exposure to airborne contaminants. Ensure that the local ventilation moves the contaminant away from the worker.

Personal Protective Equipment (PPE) · 4건

Eye/face protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection: Handle with gloves.

Body Protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

독성 정보

Adverse EffectsDermatotoxin - Skin burns.
Toxicity SummaryIDENTIFICATION AND USE: Iodobromine is a dark red solid. It is used in organic synthesis and as experimental medication. HUMAN STUDIES: There are no data available. ANIMAL STUDIES: There are no data available.
Artificial Pollution SourcesIodobromine's production and use in chemical synthesis(1) may result in its release to the environment through various waste streams(SRC).
Antidote and Emergency Treatment · 5건

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Bromine, methyl bromide, and related compounds/

/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . Cover skin burns with dry sterile dressings after decontamination ... . /Bromine, methyl bromide, and related compounds/

/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag valve mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Consider administering a beta agonist such as albuterol for severe bronchospasm ... . Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Treat seizures with diazepam (Valium) or lorazepam (Ativan) ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Bromine, methyl bromide, and related compounds/

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Iodine and related compounds/

For more Antidote and Emergency Treatment (Complete) data for Iodobromine (6 total), please visit the HSDB record page.

안전 데이터

wgk
3
tsca
TSCA listed
ridadr
UN 3264 8/PG 2
HS 번호
3822 00 00
risk_code
34-35-10-40-20/21/22-67-37
hazard_code
C

화학 및 산업

용도 및 제조

Uses · 3건

Used in organic synthesis; [Hawley] Used for analysis of phenols; [ChemIDplus]

MEDICATION

Organic synthesis.

Methods of ManufacturingPrepared from the elements, excess Br is removed by heating to 50 °C in a current of CO2.
General Manufacturing InformationIodine bromide (IBr): ACTIVE
응용 분야 · 1건

용도Iodine monobromide is used as an electrophile employed in a new synthetic approach to polyketide structural units. It is also used in iodometry and serves as a source of I+. It is a powerful iodinating agent used in organic synthesis as well as involved in the synthesis of radioiodinated fatty acids for heart imaging.

제조 방법

Prepared from the elements, excess Br is removed by heating to 50 °C in a current of CO2.

상·하류 제품 정보

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
阿诺西(上海)生物技术有限公司400-1107768 15058188853 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]

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