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철(II) 브로마이드

Ferrous bromide

HCID 82240
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
7789-46-0
표준 SMILES
[Br-].[Br-].[Fe+2]
InChIKey
GYCHYNMREWYSKH-UHFFFAOYSA-L
분자식
Br2Fe
평균 분자량
215.65 g/mol
단동위원소 질량
213.77161

개요

Iron(II) bromide is a chemical compound of iron and bromine. It is useful synthetic intermediate. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625, L653)

이름 및 식별자

우선 이름
Ferrous bromide
IUPAC
iron(2+) dibromide
현지명
철(II) 브로마이드
영어명
IRON (II) BROMIDE
분자식
Br2Fe
분자량
215.65

이름 및 동의어

Iron(II) bromide7789-46-0UNII-EA3X054RBZEA3X054RBZEINECS 232-168-8RefChem:57875232-168-8Ferrous bromideIron dibromideIRON (II) BROMIDEiron(2+);dibromideMFCD00016081
이름 더 보기
철(II)브로마이드철(II)브롬화물FeBr2IRON BROMIDEIron(II)bromide,ultradry,99.995%(metalsbasis)Dibromoironironbromide(febr2)Iron Bromide PowderIron bromide (FeBr2)
Br2FeDibromoiron; Ferrous Bromide,;Iron Dibromide;FERRUM BROMATUMFERROUS BROMIDE, ANHYDROUS, 99.999%SCHEMBL96654FERROUS BROMIDE [MI]FERRUM BROMATUM [HPUS]AKOS015832994

데이터베이스 식별자

CAS
7789-46-0
PubChem CID
82240
UNII
EA3X054RBZ
EC Number
232-168-8
Nikkaji
J43.817K

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
0
무거운 원자 수
3
형식 전하
0
복잡도
0

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesdielectric constant
Physical DescriptionLight yellow to dark brown hygroscopic solid; Soluble in water; [Merck Index] Yellow odorless granules; Hygroscopic and soluble in water; [Alfa Aesar MSDS]

물리화학적 성질

녹는점
684 °C · 684 °C(lit.)
끓는 점
934 °C · 934 °C(lit.)
밀도
4.63 g/mL · 4.63 g/mL at 25 °C(lit.)
저장 조건
2 · Storage temp. 2-8°C
용해도
에탄올: 매우 용해됨(lit.)
물리적 상태
염주
색상
노란색
Specific Gravity
4.636 · 4.636
수용성
물, THF, 메탄올, 에탄올에 용해됩니다.
Merck
14 · 14,4042
안정성
흡습성
주요 응용
전기 도금재료 합성 전구체
InChI
InChI=1S/2BrH.Fe/h2*1H;/q;;+2/p-2

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 4건

Danger

H302 (11.1%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazards SummaryCauses burns; Harmful by ingestion; [Alfa Aesar MSDS] See Iron salts, soluble.
Hazard Classes and CategoriesSkin Corr. 1B (15.6%)

안전 및 보호

Threshold Limit Values (TLV)1.0 [mg/m3], as Fe

독성 정보

Treatment · 1건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1건

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

용도 및 제조

Uses · 2건

Used as a polymerization catalyst; [Merck Index]

Iron(II) bromide is useful synthetic intermediate. (L653)

응용 분야

일반 설명This product has been enhanced for catalytic efficiency.

제조 방법

Iron(II) bromide can be prepared by the direct reaction of bromine or hydrogen bromide with iron at red heat.

상·하류 제품 정보

하류 제품

브롬화칼슘

공급사86 곳

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관련 반응

0건
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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
InChIKey
GYCHYNMREWYSKH-UHFFFAOYSA-L
SMILES
[Fe+2].[Br-].[Br-]
EPA
Iron bromide (FeBr2) (7789-46-0)

화학적 성질

Yellow to dark brown lumps

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1건

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

안전 데이터

wgk
3
tsca
TSCA listed
ridadr
UN3260
HS 번호
28275900
risk_code
20-36/37/38
hazard_code
Xn
safety_code
26-36
포장분류
III
위험 등급
8
기존화학 물질
KE-21084
스토리지 클래스
11 - Combustible Solids
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