기본 정보
- 표준 SMILES
[Br][Au]([Br])[Br]- InChIKey
OVWPJGBVJCTEBJ-UHFFFAOYSA-K- 분자식
- AuBr3
- 평균 분자량
- 436.68 g/mol
- 단동위원소 질량
- 433.72158
이름 및 식별자
- 우선 이름
- Gold tribromide
- IUPAC
- tribromogold
- 현지명
- 금 트리브롬화물
- 영어명
- GOLD(III) BROMIDE
- 분자식
- AuBr3
- 분자량
- 436.68
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
10294-28-7- PubChem CID
- 82525
- DTXSID
DTXSID9065025- ChEBI
CHEBI:30079- EC Number
- 233-654-2
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 4
- 형식 전하
- 0
- 복잡도
- 8
물리화학적 성질
- 녹는점
- 160 °C · 160°C (dec.)
- 저장 조건
- 2 · under inert gas (nitrogen or Argon) at 2–8 °C
- 용해도
- 2 O: · H2O: 약간 용해됨(lit.)
- 물리적 상태
- 가루
- 색상
- 주황색에서 갈색으로
- 수용성
- 물에 약간 용해됩니다.
- InChI
- 1S/Au.3BrH/h;3*1H/q+3;;;/p-3
- InChIKey
- OVWPJGBVJCTEBJ-UHFFFAOYSA-K
- SMILES
- Br[Au](Br)Br
- EPA
- Gold bromide (AuBr3) (10294-28-7)
화학적 성질
Yellowish-gray mass. Decomposes at approximately 165C. Insoluble in water.
안전 및 규제
GHS 분류
GHS Classification
Danger
H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 43 reports by companies from 2 notifications to the ECHA C&L Inventory.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
유해성 정보
독성 정보
Treatment
EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.
Health Effects
Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)
Toxicity Summary
Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)
Signs and Symptoms
Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)
안전 데이터
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 3260 8/PG 3
- risk_code
- 34
- hazard_code
- C
- safety_code
- 26-36/37/39-45
- 포장분류
- III
- 위험 등급
- 8
- 기존화학 물질
- KE-18094
- F 고인화성물질
- 8-10-23
- Hazard Classifications
- Skin Corr. 1B
- 스토리지 클래스
- 8A - Combustible corrosive hazardous materials
화학 및 산업
약리 정보
Metabolism/Metabolites
Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)
용도 및 제조
응용 분야
용도Gold(III) bromide is used as a catalyst in a variety of reactions. It catalyzes the reaction between an enynal unit and carbonyl compounds to form a six-membered cyclic compound. Another catalytic use of gold tribromide is in the nucleophilic substitution reaction of propargylic alcohols, with the gold complex acting as an alcohol-activating agent to facilitate the substitution. It can be used as a testing reagent for the presence of ketamine.
공급사50 곳
추가 설명
정의Brownish-black powder. Mp 160C with decomposition. Soluble in water and alcohol.
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