금 트리브롬화물

Gold tribromide

HCID 82525CAS 10294-28-7

기본 정보

표준 SMILES
[Br][Au]([Br])[Br]
InChIKey
OVWPJGBVJCTEBJ-UHFFFAOYSA-K
분자식
AuBr3
평균 분자량
436.68 g/mol
단동위원소 질량
433.72158

이름 및 식별자

우선 이름
Gold tribromide
IUPAC
tribromogold
현지명
금 트리브롬화물
영어명
GOLD(III) BROMIDE
분자식
AuBr3
분자량
436.68

이름 및 동의어

10294-28-7Gold tribromideAuBr3Auric bromideUNII-4PJV3VH75Ygold(3+) bromidegold (III) bromideEINECS 233-654-24PJV3VH75YCHEBI:30079(AuBr3)[AuBr3]
이름 더 보기
금트리브롬화물트라이브로민화금(트리브롬화금)트라이브로민화금(트리브롬화금)(GOLDTRIBROMIDE)금(III)브로마이드GOLD BROMIDEd(III) bromidegoldbromide(aubr3)digold hexabroMideGOLD(III) BROMIDE, 99.9%Gold(III) bromide Hydrate
RefChem:57324233-654-2Aurum Bromatumgold(III) bromideGold bromide (AuBr3)tribromogoldGold(III) tribromidegold(3+) tribromide

데이터베이스 식별자

CAS
10294-28-7
PubChem CID
82525
DTXSID
DTXSID9065025
ChEBI
CHEBI:30079
EC Number
233-654-2

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
4

물리화학적 성질

녹는점
160 °C · 160°C (dec.)
저장 조건
2 · under inert gas (nitrogen or Argon) at 2–8 °C
용해도
2 O: · H2O: 약간 용해됨(lit.)
물리적 상태
가루
색상
주황색에서 갈색으로
수용성
물에 약간 용해됩니다.

화학적 성질

Yellowish-gray mass. Decomposes at approximately 165C. Insoluble in water.

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 43 reports by companies from 2 notifications to the ECHA C&L Inventory.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Hazard Classes and CategoriesSkin Corr. 1B (100%)

독성 정보

Treatment · 1건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1건

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

안전 데이터

wgk
3
tsca
TSCA listed
ridadr
UN 3260 8/PG 3
risk_code
34
hazard_code
C
safety_code
26-36/37/39-45

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

용도 및 제조

UsesGold(III) bromide is used as a catalyst in a variety of reactions. (L648)
General Manufacturing InformationGold bromide (AuBr3): ACTIVE
응용 분야 · 1건

용도Gold(III) bromide is used as a catalyst in a variety of reactions. It catalyzes the reaction between an enynal unit and carbonyl compounds to form a six-membered cyclic compound. Another catalytic use of gold tribromide is in the nucleophilic substitution reaction of propargylic alcohols, with the gold complex acting as an alcohol-activating agent to facilitate the substitution. It can be used as a testing reagent for the presence of ketamine.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
毕佳索(上海毕得医药科技股份有限公司)400-6005915 · [email protected]
陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
郑州鸿晟医药科技有限公司0371-55695890 15637198702 · [email protected]

추가 설명

정의Brownish-black powder. Mp 160C with decomposition. Soluble in water and alcohol.

관련 반응

8건

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