기본 정보
- CAS
12063-98-8- 표준 SMILES
[P]#[Ga]- InChIKey
HZXMRANICFIONG-UHFFFAOYSA-N- 분자식
- GaP
- 평균 분자량
- 100.697 g/mol
- 단동위원소 질량
- 99.89934
개요
Gallium phosphide is a phosphide of gallium. It is a semiconductor and optical material that is used for manufacture of low and standard brightness red, orange, and green light-emitting diodes. Metal phosphides are hydrolysed to phosphine upon contact with water or stomach acid. Phosphine is a colorless, flammable, explosive, and toxic gas. (L980, L985)
이름 및 식별자
- 우선 이름
- Gallium phosphide
- IUPAC
- gallanylidynephosphane
- 현지명
- 인화갈륨
- 영어명
- GALLIUM PHOSPHIDE
- 분자식
- GaP
- 분자량
- 100.7
이름 및 동의어
Gallium phosphide12063-98-8gallanylidynephosphaneGallium monophosphideGallium phosphide (GaP)3J421F73DVDTXSID60894184Gallium PhosphoricumRefChem:58069DTXCID301324226235-057-2CCRIS 4019
이름 더 보기
갈륨포스피드인화갈륨갈륨포스피드GALLIUM PHOSPHIDE, 99.99%Galenium PhosphidegalliummonophosphidePhosphinidynegalliumgallium(III) phosphide
EINECS 235-057-2UNII-3J421F73DVSCHEMBL43606GALLIUM PHOSPHIDE [MI]Gallium phosphide, 99.99% metals basisGallium phosphide, 99.99% trace metals basisQ421416Gallium phosphide, (single crystal substrate), <111>, diam. x thickness 2 in. x 0.5 mm
데이터베이스 식별자
- CAS
12063-98-8- PubChem CID
- 82901
- DTXSID
DTXSID60894184- UNII
- 3J421F73DV
- EC Number
- 235-057-2
- Nikkaji
- J95.943J
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 2
- 형식 전하
- 0
- 복잡도
- 10
실험 및 물리화학적 성질
Chemical Classes
Metals -> Phosphides
Flammable agents - 3rd degree
SpringerMaterials Propertiesvalence band parameter
Physical DescriptionAmber translucent solid; Greenish-yellow opaque solid if unreacted gallium present; [Merck Index] Pale orange solid; [Alfa Aesar MSDS]
물리화학적 성질
- 녹는점
- 1480 °C · 1480 °C
- 밀도
- 4.13 g/mL · 4.13 g/mL at 25 °C
- 굴절률
- 2.9 · 2.9
- 인화점
- 230 °F · 230 °F
- 물리적 상태
- 고체
- Specific Gravity
- 4.1 · 4.1
- 색상
- 창백한 오렌지
- 수용성
- 물에 불용성.
- Merck
- 14 · 14,4353
- InChI
- InChI=1S/Ga.P
- InChIKey
- HZXMRANICFIONG-UHFFFAOYSA-N
- SMILES
- P#[Ga]
- Knoop Microhardness
- 9450 · 9450, N/mm2
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Warning
H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
P261, P264+P265, P271, P280, P304+P340, P305+P351+P338, P319, P337+P317, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 99 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
Chemical: Gallium phosphide (GaP)
The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
Hazards Summary
Causes flaccid paralysis without anesthesia (usually neuromuscular blockage), somnolence, and effects on food intake in oral lethal-dose studies of mice; [RTECS] A strong eye irritant; [Alfa Aesar MSDS] See Gallium. See Aluminum phosphide. See PHOSPHIDES.
Hazard Classes and Categories
Eye Irrit. 2 (100%)
Flammable agents - 3rd degree, Reactive agents - 2nd degree
독성 정보
TreatmentAs there is no antidote for phosphine poisoning, treatment is mainly symptomatic. Artificial respiration, gastric lavage, and/or administration of activated charcoal may be necessary. (L982)
Health Effects
Inhalation of phosphine may cause severe pulmonary irritation leading to acute pulmonary oedema, cardiovascular dysfunction, CNS excitation, coma and death. Gastrointestinal disorders, renal damage and leukopenia may also occur. Chronic exposure to phosphine can result in anemia, bronchitis, gastrointestinal effects, and visual, speech and motor problems. (L980, L982)
화학 및 산업
약리 정보
Metabolism/Metabolites
Phosphine and metal phosphides may be absorbed following ingestion or inhalation, then distribute to the nervous system, liver, and kidney. In the body, metal phosphides are hydrolysed to phosphine, and phosphine is oxidized to hypophosphite and phosphite. Metabolites are excreted in the urine, while unchanged phosphine is exhaled. (L982)
용도 및 제조
Uses
Used in semiconductor electronics; [Merck Index]
Semiconductor Manufacturing [Category: Industry]
Gallium phosphide is a semiconductor and optical material that is used for manufacture of low and standard brightness red, orange, and green light-emitting diodes. (L985)
General Manufacturing InformationGallium phosphide (GaP): ACTIVE
응용 분야
용도Gallium phosphide (GaP) is used in semiconductor devices, and in the manufacture of light-emitting diodes (LEDs) doped with other elements or in combination with gallium arsenide phosphide. With appropriate dopants, p-type and n-type semiconductors can be produced. It is used in optical systems.
제조 방법
The compound is prepared by vapor phase reaction of gallium suboxide, Ga2O and phosphorus. It is produced in polycrystalline form or as single crystals or whiskers in high purity grade for use in semiconducting devices.
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