1,2-Bis(dibromomethyl)benzene (HCID 83234)

이름 및 식별자

우선 이름: 1,2-Bis(dibromomethyl)benzene
IUPAC: 1,2-bis(dibromomethyl)benzene
영어명: alpha,alpha,alpha',alpha'-Tetrabromo-o-xylene
분자식: C8H6Br4
분자량: 421.75

이름 및 동의어

1,2-Bis(dibromomethyl)benzene13209-15-9alpha,alpha,alpha',alpha'-Tetrabromo-o-xyleneBenzene, 1,2-bis(dibromomethyl)-EINECS 236-176-2UNII-3WG2H68VX4NSC 386073WG2H68VX4NSC-38607o-Xylene, alpha,alpha,alpha',alpha'-tetrabromo-DTXSID7022255o-Xylene, .alpha.,.alpha.,.alpha.',.alpha.'-tetrabromo-

이름 더 보기

′-Tetrabromo-o<1,2-Bis(dibromomethyl)O-XYLYLENE TETRABROMIDEAAAATETRABROMOORTHOXYLENEa,a,a,a-Tertabromo-O-Xylene1,2-bis(dibromomethyl)-benzeà,à,à',à'-tetrabromo-o-xyleneA,A,A',A'-TETRABROMO-O-XYLENE

.alpha.,.alpha.,.beta.,.beta.-Tetrabromo-o-xylene.alpha.,.alpha.,.alpha.',.alpha.'-Tetrabromo-o-xylene.alpha.,.alpha.,.alpha.1,.alpha.1-Tetrabromo-o-xylenealpha,alpha,beta,beta-Tetrabromo-o-xyleneRefChem:71730a,a,a'a'Tetrabromooxylene1,2Bis(dibromomethyl)benzeneDTXCID102255

데이터베이스 식별자

CAS: 13209-15-9
PubChem CID: 83234
DTXSID: DTXSID7022255
UNII: 3WG2H68VX4
EC Number: 236-176-2
Nikkaji: J31.710A

물성

구조 계산 물성

XLogP: 4.8
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 2
무거운 원자 수: 12
형식 전하: 0
복잡도: 119

실험 및 물리화학적 성질

Physical DescriptionLight brown crystalline solid; [Sigma-Aldrich MSDS]

물리화학적 성질

녹는점: 114 · 114-116 °C(lit.)
끓는 점: 303.01 °C · 303.01°C (rough estimate)
밀도: 2.2654 · 2.2654 (rough estimate)
굴절률: 1.704 · 1.7040 (estimate)
저장 조건: 30 °C · Store below +30°C.
물리적 상태: 액체 또는 저융점 고체
색상: 무색~황색으로 투명함
수용성: 불용성
BRN: 2211698 · 2211698
InChI: InChI=1S/C8H6Br4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4,7-8H
InChIKey: LNAOKZKISWEZNY-UHFFFAOYSA-N
SMILES: C1(C(Br)Br)=CC=CC=C1C(Br)Br
EPA: 1 · 1,2-Bis(dibromomethyl)benzene (13209-15-9)

화학적 성질

OFF-WHITE TO GREY CRYSTALLINE POWDER

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (89.1%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H335 (93.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H400 (84.8%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]

P260, P261, P264, P264+P265, P271, P273, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information1,2-Bis(dibromomethyl)-benzene: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryCauses burns and lachrymation; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS]

Hazard Classes and CategoriesSkin Corr. 1B (100%)；Eye Dam. 1 (89.1%)；STOT SE 3 (93.5%)；Aquatic Acute 1 (84.8%)

독성 정보

Adverse EffectsDermatotoxin - Skin burns.；Lacrimator (Lachrymator) - A substance that irritates the eyes and induces the flow of tears.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

규제 정보

Regulatory Information1,2-Bis(dibromomethyl)-benzene: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 3261 8/PG 2
HS 번호: 29039990
risk_code: 34-36/37-20/21/22
hazard_code: C
safety_code: 26-36/37/39-45
포장분류: II
위험 등급: 8
F 고인화성물질: 19-21
Hazard Classifications: Aquatic Acute 1Eye Dam. 1Skin Corr. 1BSTOT SE 3
스토리지 클래스: 8A - Combustible corrosive hazardous materials

화학 및 산업

용도 및 제조

General Manufacturing InformationBenzene, 1,2-bis(dibromomethyl)-: ACTIVE

응용 분야 · 1건

용도α,α,α',α'-Tetrabromo-o-xylene reacts with 5endo,6endo-bis-chlormethyl-norborn-2-en to obtain trans/cis-2,3-bis(chloromethyl)-1,4-methano-1,2,3,4-tetrahydroanthracene. Further, it is involved in the preparation of 1-(3-butenyl)-2-(deuteriomethyl)benzene by reacting with allylmagnesium bromide. In addition this, it is used to prepare exo-benzocyclobuteno-1,2,3,4-tetrahydro-1,4-methanoanthracene by reacting with exo-1,4,4a,8b-tetrahydro-1,4-methanobiphenylene.