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Gallium bromide (GaBr3)

HCID 83477
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
13450-88-9
표준 SMILES
[Br][Ga]([Br])[Br]
InChIKey
SRVXDMYFQIODQI-UHFFFAOYSA-K
분자식
Br3Ga
평균 분자량
309.44 g/mol
단동위원소 질량
305.68059

개요

Gallium(III) bromide is a chemical compound of gallium and bromine. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625)

이름 및 식별자

우선 이름
Gallium bromide (GaBr3)
IUPAC
tribromogallane
영어명
GALLIUM(III) BROMIDE
분자식
Br3Ga
분자량
309.43

이름 및 동의어

Gallium(III) bromide13450-88-9Gallium bromide (GaBr3)tribromogallaneGaBr3Gallium bromideTribromogalliumGallium (III) Bromide, anhydrousEINECS 236-609-5NSC 94001Gallium bromide, GaBr3SCHEMBL150912
이름 더 보기
ribromogallaneGALLIUM TRIBROMIDEGallium(lll) bromidegalliumbromide(gabr3)Gallium(III) Tribromide
DTXSID2065466Gallium(III) bromide, ultra dryNSC94001Gallium(III) bromide, 99.999%NSC-94001Q2175117Gallium(III) bromide, anhydrous, powder, 99.999% trace metals basisGallium(III) bromide, ultra dry, 99.99% (metals basis), crystalline, ampouled

데이터베이스 식별자

CAS
13450-88-9
PubChem CID
83477
DTXSID
DTXSID2065466
EC Number
236-609-5

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
4
형식 전하
0
복잡도
8

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical DescriptionWhite, odorless crystalline solid; [MSDSonline]

물리화학적 성질

녹는점
121.5 °C · 121.5 °C(lit.)
끓는 점
279 °C · 279 °C(lit.)
밀도
3.69 g/mL · 3.69 g/mL at 25 °C(lit.)
인화점
278.8 °C · 278.8°C
저장 조건
2 · under inert gas (nitrogen or Argon) at 2-8°C
용해도
2 O: · H2O: 약간 용해됨(lit.)
물리적 상태
가루
색상
하얀색
Specific Gravity
3.69 · 3.69
수용성
물에 용해됩니다.
안정성
안정적이지만 물과 격렬하게 반응합니다. 물, 습기, 강한 산화제와의 접촉을 피하십시오. 공기 중에서 변색될 수 있습니다.
주요 응용
전기 도금재료 합성 전구체
InChI
1S/3BrH.Ga/h3*1H;/q;;;+3/p-3
InChIKey
SRVXDMYFQIODQI-UHFFFAOYSA-K
SMILES
Br[Ga](Br)Br

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 4건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 43 reports by companies from 2 notifications to the ECHA C&L Inventory.

유해성 정보

Regulatory InformationChemical: Gallium bromide (GaBr3)
Other Safety InformationEvaluation - Chemicals not considered for in depth evaluation - Not commercially active in Australia
Hazards SummaryReacts violently with water; A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Bromine.
Hazard Classes and CategoriesSkin Corr. 1B (100%)

독성 정보

Treatment · 1건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1건

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

용도 및 제조

General Manufacturing InformationGallium bromide (GaBr3): INACTIVE

응용 분야

용도Gallium(III) bromide is used as organic intermediates. It is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes.

상·하류 제품 정보

하류 제품

Gallium(III) trifluoromethanesulfonate

공급사47 곳

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관련 반응

0건
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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
EPA
Gallium bromide (GaBr3) (13450-88-9)

화학적 성질

white crystalline powder

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1건

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

안전 데이터

wgk
3
tsca
TSCA listed
ridadr
UN 3260 8/PG 2
HS 번호
2827590000
risk_code
14-34
hazard_code
C
safety_code
8-26-36/37/39-45
포장분류
II
위험 등급
8
기존화학 물질
KE-17442
Hazard Classifications
Skin Corr. 1B
스토리지 클래스
8A - Combustible corrosive hazardous materials
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