1-트리메틸실릴-2-피롤리디논

1-(Trimethylsilyl)pyrrolidin-2-one

HCID 84461CAS 14468-90-7

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: C[Si](C)(C)N1CCCC1=O
InChIKey: LUBVCBITQHEVCJ-UHFFFAOYSA-N
분자식: C7H15NOSi
평균 분자량: 157.29 g/mol
단동위원소 질량: 157.09229063

이름 및 식별자

우선 이름: 1-(Trimethylsilyl)pyrrolidin-2-one
IUPAC: 1-trimethylsilylpyrrolidin-2-one
현지명: 1-트리메틸실릴-2-피롤리디논
영어명: 1-TRIMETHYLSILYL-2-PYRROLIDINONE
분자식: C7H15NOSi
분자량: 157.29

이름 및 동의어

14468-90-71-(Trimethylsilyl)pyrrolidin-2-one1-(Trimethylsilyl)-2-pyrrolidinoneEINECS 238-461-7DTXSID50162783RefChem:428854DTXCID2085274238-461-7N-trimethylsilyl-2-pyrrolidone1-trimethylsilylpyrrolidin-2-one1-TRIMETHYLSILYL-2-PYRROLIDINONEN-Trimethylsilyl-2-pyrrolidinone

이름 더 보기

1-트리메틸실릴-2-피롤리디논n-trimethylsilylbutyrolactam1-Trimethylsilyl-2-pyrrolizinone1-(Trimethylsilanyl)pyrrolidin-2-one1-(Trimethylsilyl)-2-pyrrolidinone 96%

2-Pyrrolidinone, 1-(trimethylsilyl)-MFCD000515721-trimethylsilanyl-pyrrolidin-2-one1-trimethylsilylpyrrolidones20275N-trimethylsilylpyrrolid-2-one2-Pyrrolidinone, TMS derivative1-(Trimethylsilyl)-2-pyrrolidinone #

데이터베이스 식별자

CAS: 14468-90-7
PubChem CID: 84461
DTXSID: DTXSID50162783
UNII: V72A3P73CS
EC Number: 238-461-7
Nikkaji: J217.027B

물성

구조 계산 물성

극성 표면적: 20.3 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 1
무거운 원자 수: 10
형식 전하: 0
복잡도: 150

실험 및 물리화학적 성질

SpringerMaterials Properties29Si nuclear magnetic resonance spectrum

물리화학적 성질

끓는 점: 90 °C/20 · 90 °C/20 mmHg (lit.)
밀도: 0.983 g/mL · 0.983 g/mL at 25 °C (lit.)
굴절률: 1.459 · 1.4590
인화점: 53 °C · 53°C
저장 조건: 2 · Storage temp. 2-8°C
용해도: 클로로포름(약간 용해됨), 메탄올(약간 용해됨)
산도 계수 (pKa): -0.11 · -0.11±0.20(Predicted)
물리적 상태: 기름
Specific Gravity: 0.821 · 0.821
색상: 투명 무색
수용성: 물로 가수분해됩니다.
BRN: 114950 · 114950
안정성: 냉동실에 건조 보관
InChI: 1S/C7H15NOSi/c1-10(2,3)8-6-4-5-7(8)9/h4-6H2,1-3H3
InChIKey: LUBVCBITQHEVCJ-UHFFFAOYSA-N
SMILES: C[Si](C)(C)N1CCCC1=O

화학적 성질

Colourless Liquid

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 44 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesFlam. Liq. 3 (100%)

안전 데이터

wgk: 3
ridadr: 1993
HS 번호: 2933790090
risk_code: 10-36/38-36/37/38
hazard_code: Xi
safety_code: 26-36-16
포장분류: II
위험 등급: 3
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

응용 분야 · 2건

용도1-Trimethylsilyl-2-pyrrolidinone, is used as a fine chemical intermediate.

일반 설명1-(Trimethylsilyl)-2-pyrrolidinone has been prepared by refluxing a mixture of 2-pyrrolidinone, triethylamine and trimethylchlorosilane in benzene. It undergoes sulfenylation with phenyl disulfide to form the corresponding bissulfide as the major product.

상·하류 제품 정보

상류 원료

1,3,2-Dioxaphosphorinane, 2-chloro-Benzene, [(1Z)-1-[(trimethylsilyl)oxy]-1-propen-1-yl]-Benzene, [(1Z)-2-[(trimethylsilyl)oxy]-1-propen-1-yl]-5-메톡시-3,4-디하이드로-2H-피롤 1-(Trimethylsiloxy)cyclopentene 1-Cyclohexenyloxytrimethylsilane Phenylacetone 프로피오페논 1,3-Diphenylacetone 사이클로펜타논 사이클로헥사논 트리메틸클로로실란

하류 제품

3,3-디메틸-2-피롤리디논 N- 에틸 -2- 피 롤리 돈 2-OXO-1-피롤리딘아세트산메틸에스테르 3-메틸-2-피롤리디논 2-피롤리디논

공급사50 곳

上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]

Sichuan Biosynce Pharmatech Co., Ltd.[email protected]

上海腾准生物科技有限公司19821570922 · [email protected]

上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]

陕西缔都化学有限公司029-029-81123119 17391733320 · [email protected]

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