Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester (HCID 85963)

개요

This liquid peroxide is particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently. They are generally stored or transported in a solvent slurry.

이름 및 식별자

우선 이름: Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester
IUPAC: 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate
현지명: 비스-(2-에틸헥실)퍼옥시디카보네이트
영어명: Di-(2-ethylhexyl)peroxydicarbonate
분자식: C18H34O6
분자량: 346.46

이름 및 동의어

16111-62-9Peroxydicarbonic acid, bis(2-ethylhexyl) esterDi(2-ethylhexyl) peroxydicarbonateBis(2-ethylhexyl) peroxydicarbonateEINECS 240-282-4BRN 5964960di-(2-Ethylhexyl)peroxydicarbonateDTXSID5027778Peroxydicarbonic acid, di(2-ethylhexyl) esterEC 240-282-4Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) esterDI-(2-ETHYLHEXYL) PEROXYDICARBONATE, (TECHNICALLY PURE)

이름 더 보기

비스-(2-에틸헥실)퍼옥시디카보네이트다이-(2-에틸헥실) 퍼옥시다이카보네이트, 상업용 순도디-(2-에틸헥실)퍼옥시디카보네이트Lupersol 223Trigonox EHP-C75Trigonox EHP-W60Trigonox EHPS-C75Initiating agent EHPDEHP peroxydicarbonate2-Ethylhexyl percarbonateBis(2-ethylhexyl) perdicarbonate

DI-(2-ETHYLHEXYL) PEROXYDICARBONATE, [TECHNICALLY PURE]RefChem:860365ESPERCARB 840MTRIGONOX EHP-W 40DTXCID407778di-2-ethylhexyl peroxydicarbonate240-282-42-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate

데이터베이스 식별자

CAS: 16111-62-9
PubChem CID: 85963
DTXSID: DTXSID5027778
EC Number: 240-282-4
Nikkaji: J9.287H

물성

구조 계산 물성

XLogP: 7.3
극성 표면적: 71.1 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 6
회전 가능 결합 수: 17
무거운 원자 수: 24
형식 전하: 0
복잡도: 299

실험 및 물리화학적 성질

Physical Description · 2건

This liquid peroxide is particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently. They are generally stored or transported in a solvent slurry.

Liquid; CBI

물리화학적 성질

끓는 점: 401.18 °C · 401.18°C (rough estimate)
밀도: 1.0722 · 1.0722 (rough estimate)
증기압: 0.001 Pa · 0.001Pa at 25℃
굴절률: 1.445 · 1.4450 (estimate)
수용성: 880 mg/L · 880mg/L at 25℃
안정성: 가열하면 불안정함. 가열하면 폭발할 위험이 있습니다. 충격에 민감할 수 있습니다. 가연성. 유기 물질과 격렬하게 반응할 수 있음.
LogP: 2.73 · 2.73
EPA: Peroxydicarbonic acid, bis(2-ethylhexyl) ester (16111-62-9)

화학적 성질 · 1건

It is colorless liquid with unpleasant odor. Thermally unstable with required continuous refrigeration below -10°C (-14°F). Refer to the Code for the Storage of Organic Peroxide Formulations. Storage incompatibility includes strong acids, oxidizing agents, alkaline materials, reducing agents, and amines. Also, it should be stored away from excessive heat, sources of ignition, and reactive materials (12b).

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H242 (100%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]

P210, P234, P235, P240, P261, P264, P264+P265, P270, P272, P280, P301+P317, P302+P352, P305+P351+P338, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P370+P378, P403, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 559 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 4건

Chemical: Peroxydicarbonic acid, bis(2-ethylhexyl) ester

Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 31-05-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/14207

Peroxydicarbonic acid, bis(2-ethylhexyl) ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

DOT LabelOrganic Peroxide

Fire HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Health HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Reactive GroupPeroxides, Organic

Reactivity AlertsExplosive

안전 및 보호

Fire FightingExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

First AidExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Nonfire Spill ResponseExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Isolation and EvacuationExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Personal Protective Equipment (PPE)Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

안전 데이터

tsca: TSCA listed
ridadr: 3117
포장분류: II
위험 등급: 5.2
기존화학 물질: KE-28163

화학 및 산업

용도 및 제조

U.S. Production2023: 4,000,000 - <5,500,000 lb

Consumer UsesNot Known or Reasonably Ascertainable

Industry UsesPolymerization promoter

General Manufacturing Information · 2건

Plastics Material and Resin Manufacturing

Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester: ACTIVE

응용 분야

일반 설명Di-(2-ethylhexyl)peroxydicarbonate is particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently. They are generally stored or transported in a solvent slurry.