CAS 17697-12-0 Phenylseleninyl benzeneseleninate (HCID 87253)

이름 및 식별자

우선 이름: Phenylseleninyl benzeneseleninate
IUPAC: phenylseleninyl benzeneseleninate
영어명: Benzeneseleninic anhydride
분자식: C12H10O3Se2
분자량: 360.13

이름 및 동의어

17697-12-0phenylseleninyl benzeneseleninateBenzeneselenic anhydride69M675B633DTXSID10170228RefChem:563678DTXCID3092719241-701-3Benzeneseleninic anhydrideBenzeneseleninic acid anhydridePhenylseleninic AnhydrideBenzeneseleninic acid, phenylseleninyl ester

이름 더 보기

PHENYLSELENIC ANHYDRIDEBenzene Selenenic AnhydrideBisbenzeneseleninic anhydrideBis(benzeneseleninic)anhydrideBenzeneseleninic anhydride,98%Di(benzeneseleninic acid)anhydride

MFCD00001991Bis(phenylseleninic) anhydridePhenylseleninic Anhydride;C12H10O3Se2Benzeneseleninic acid, anhydrideEINECS 241-701-3BENZENESELENINICANHYDRIDESCHEMBL1165959

데이터베이스 식별자

CAS: 17697-12-0
PubChem CID: 87253
DTXSID: DTXSID10170228
UNII: 69M675B633
EC Number: 241-701-3
Nikkaji: J287.128I

물성

구조 계산 물성

극성 표면적: 43.4 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 3
회전 가능 결합 수: 4
무거운 원자 수: 17
형식 전하: 0
복잡도: 253

물리화학적 성질

녹는점: 165 · 165-170 °C (lit.)
끓는 점: 184.2 · 184.2±23.0 °C(Predicted)
저장 조건: RT, stored under nitrogen
물리적 상태: 고체
BRN: 2332406 · 2332406
InChI: InChI=1S/C12H10O3Se2/c13-16(11-7-3-1-4-8-11)15-17(14)12-9-5-2-6-10-12/h1-10H
InChIKey: FHPZOWOEILXXBD-UHFFFAOYSA-N
SMILES: C1([Se](O[Se](C2=CC=CC=C2)=O)=O)=CC=CC=C1

화학적 성질

WHITE TO LIGHT BEIGE POWDER

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]；H331 (100%): Toxic if inhaled [Danger Acute toxicity, inhalation]；H373 (100%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]；H400 (100%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]；H410 (100%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P260, P261, P264, P270, P271, P273, P301+P316, P304+P340, P316, P319, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory InformationBenzeneseleninic acid, anhydride: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesAcute Tox. 3 (100%)；Acute Tox. 3 (100%)；STOT RE 2 (100%)；Aquatic Acute 1 (100%)；Aquatic Chronic 1 (100%)

규제 정보

Regulatory InformationBenzeneseleninic acid, anhydride: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk: 3
ridadr: UN 3283 6.1/PG 2
HS 번호: 29310099
risk_code: 23/25-33-50/53
hazard_code: T,N
safety_code: 20/21-28-45-60-61
포장분류: III
위험 등급: 6.1
F 고인화성물질: 3-10-21
Hazard Classifications: Acute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1STOT RE 2
스토리지 클래스: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects

화학 및 산업

응용 분야

용도Benzeneseleninic acid anhydride was used to oxidize hydrazines to afford azo-compounds.

일반 설명Oxidation of phenols by benzeneseleninic acid anhydride yields ortho-quinones. Benzeneseleninic anhydride acts as a mild oxidant for the conversion of benzylic hydrocarbons into aldehydes or ketones.