Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
디노르말헥실아민
다이헥실아민 · 디노르말헥실아민 · DI-N-헥실아민 · DIHEXYLAMINE · NSC 7498 · Dihexylamin · Di-n-hexylamin · DihexylaMine 1
식별자 및 물리적 특성
| CAS No. | 143-16-8 |
|---|---|
| 분자식 | C12H27N |
| 평균 분자량 | 185.35 g/mol |
| 단동위원소 질량 | 185.21434986 g/mol |
| SMILES | CCCCCCNCCCCCC |
| InChIKey | PXSXRABJBXYMFT-UHFFFAOYSA-N |
| PubChem CID | 8920 |
| ChEMBL | CHEMBL3188279 |
| EC No. | 205-588-4 |
| DTXSID | DTXSID1022009 |
| 현지명 | 디노르말헥실아민 |
화학 및 물리적 성질
| XLogP | 4.5 |
|---|---|
| 극성 표면적 | 12 |
| 수소 결합 공여자 수 | 1 |
| 수소 결합 수용자 수 | 1 |
| 회전 가능 결합 수 | 10 |
| 무거운 원자 수 | 13 |
| 형식 전하 | 0 |
| 복잡도 | 71.2 |
| 물질 분류 | Nitrogen Compounds -> Amines, AliphaticFlammable agents - 3rd degree |
| SpringerMaterials Properties | Boiling point |
| 밀도 | 0.79 at 68 °F (NTP, 1992) - Less dense than waterwill float0.795 g/mL at 25 °C(lit.) |
| 용해도 | less than 1 mg/mL at 79 °F (NTP, 1992)0.3g/L |
| 인화점 | 203 °F (NTP, 1992) |
| 끓는 점 | 451 to 469 °F at 760 mmHg (NTP, 1992)192-195 °C(lit.) |
| 증기 밀도 | 6.38 (NTP, 1992) - Heavier than airwill sink (Relative to Air)6.4 (vs air) |
| 증기압 | less than 0.1 mmHg at 68 °F (NTP, 1992)0.05 hPa (20 °C) |
| Physical Description | Dihexylamine is a clear colorless liquid. (NTP, 1992)[CAMEO] Clear light yellow liquid[Sigma-Aldrich MSDS] |
| Collision Cross Section | 158.0 Ų [M+H]+ [CCS Type: DTBuffer gas: N2Ionization: ESI+Dataset: TOXCASTSource Identifier: DTXSID1022009] |
| 녹는점 | 3 °C |
| 굴절률 | n20/D 1.432(lit.) |
| 저장 조건 | Store below +30°C. |
| pKa(산도 계수) | pK1:11.0(+1) (25°C) |
| 물리적 상태 | 액체 |
| 색상 | 무색의 |
| pH | 9.9 (0.3g/l, H2O, 25℃) |
| 폭발한계 | 0.7-5.9%(V) |
| 용해도 | 물과 섞일 수 있습니다. |
| Merck | 14,7650 |
| BRN | 1738519 |
| 헨리 상수 | 1.3×10-1 mol/(m3Pa) at 25℃, Yaws (2003) |
| 안정성 | 안정적인. 타기 쉬운. 강한 산화제와 호환되지 않습니다. |
| InChI | 1S/C12H27N/c1-3-5-7-9-11-13-12-10-8-6-4-2/h13H,3-12H2,1-2H3 |
| InChIKey | PXSXRABJBXYMFT-UHFFFAOYSA-N |
| SMILES | CCCCCCNCCCCCC |
| EPA | Dihexylamine (143-16-8) |
화학적 성질
colourless liquid
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 0.7% (1 of 151) of reports.DangerH300 (72.2%): Fatal if swallowed [Danger Acute toxicity, oral]P260, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P320, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 151 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Chemical: 1-Hexanamine, N-hexyl-Dihexylamine: HSNO Approval: HSR004442 Approved with controlsThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 운송 라벨(DOT) | Poison |
| 화재 위험 | This compound is combustible. (NTP, 1992) |
| 건강 유해성 | ACUTE/CHRONIC HAZARDS: This compound is readily absorbed through the skin. (NTP, 1992) |
| 유해성 요약 | A severe eye and mild skin irritant[RTECS] Readily absorbed through skin[NTP] Causes burnsInhalation may cause corrosive injuries to upper respiratory tract and lungsToxic by ingestionHighly toxic by skin absorption[Sigma-Aldrich MSDS] See 2-Ethylhexylamine. |
| 반응성 그룹 | Amines, Phosphines, and Pyridines |
| Reactivity Profile | DIHEXYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. |
| Air and Water Reactions | This compound may be sensitive to prolonged exposure to air. Insoluble in water. |
| Hazard Classes and Categories | Acute Tox. 2 (72.2%)Flammable agents - 3rd degree |
| 소화 | Fires involving this compound can be controlled with carbon dioxide, dry chemical or Halon extinguishers. (NTP, 1992) |
| 응급 처치 | EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. |
| 비화재 누출 대응 | SMALL SPILLS AND LEAKAGE: If you spill this chemical, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. |
| Isolation and Evacuation | Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: |
| Personal Protective Equipment (PPE) | MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves. |
| 유해 작용 | Dermatotoxin - Skin burns. |
| 수질 위해 등급(WGK) | 2 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | IH6600000 |
| 운송 번호(UN) | UN 2922 8/PG 2 |
| 독성 | LD50 orally in Rabbit: 42 mg/kg LD50 dermal Rabbit < 160 mg/kg |
| 관세 코드 | 29211990 |
| 위험 문구(R) | 22-24-34 |
| 위험 표시 | T |
| 안전 문구(S) | 26-36/37/39-45 |
| 포장분류 | I |
| 위험 등급 | 6.1Acute Tox. 1 DermalAcute Tox. 2 InhalationAcute Tox. 2 OralAquatic Acute 1Aquatic Chronic 1Eye Dam. 1Skin Corr. 1A |
| 기존화학 물질 | KE-10587 |
| 자연 발화 온도 | 250 °C |
| 저장 분류 | 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials |
용도
용도
Di-n-hexylamine is used in organic synthesis and involved in the preparation of succinic acid.
일반 설명
Clear colorless liquid.