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지르코늄 N-프로프산화물
지르코늄N-프로프산화물 · 지르코늄N-프로프산화물(ZIRCONIUMN-PROPOXIDE) · Zirconium propoxide · ZIRCONIUM(IV) N-PROPOXIDE · N-PROPYL ZIRCONATE · ZIRCONIUM(IV) PROPOXIDE · ZirconiuM propoxide solution · Zirconium(IV) propoxide solution
식별자 및 물리적 특성
| CAS No. | 23519-77-9 |
|---|---|
| 분자식 | C12H28O4Zr |
| 평균 분자량 | 327.57 g/mol |
| 단동위원소 질량 | 326.10346378 g/mol |
| SMILES | CCC[O-].CCC[O-].CCC[O-].CCC[O-].[Zr+4] |
| InChIKey | XPGAWFIWCWKDDL-UHFFFAOYSA-N |
| PubChem CID | 90139 |
| EC No. | 245-711-9 |
| DTXSID | DTXSID6046975 |
| 현지명 | 지르코늄 N-프로프산화물 |
화학 및 물리적 성질
| 극성 표면적 | 92.2 |
|---|---|
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 4 |
| 회전 가능 결합 수 | 4 |
| 무거운 원자 수 | 17 |
| 형식 전하 | 0 |
| 복잡도 | 7.2 |
| Physical Description | Tetra-n-propyl zirconate appears as a yellow-colored liquid with an alcohol-like odor. Has about the same density as water and is insoluble in water. Vapors are heavier than air. May be irritating to skin, eyes, and mucous membranes.CBI |
| 녹는점 | -55.00°C |
| 끓는 점 | 208 °C0.1 mm Hg |
| 밀도 | 1.058 g/mL at 20 °C |
| 증기압 | 19.4hPa at 20℃ |
| 굴절률 | n20/D 1.454 |
| 인화점 | 83 °F |
| 물리적 상태 | 약간 점성이 있는 용액 |
| 비중 | 1.05 |
| 색상 | 무색~황색~연한 호박색 |
| 용해도 | 물과 섞이지 않습니다. |
| BRN | 3679533 |
| InChI | 1S/4C3H7O.Zr/c4*1-2-3-4/h4*2-3H2,1H3/q4*-1+4 |
| InChIKey | XPGAWFIWCWKDDL-UHFFFAOYSA-N |
| SMILES | CCCO[Zr](OCCC)(OCCC)OCCC |
| LogP(분배 계수) | 0.34 at 20℃ |
| EPA | 1-Propanol, zirconium(4+) salt (23519-77-9) |
화학적 성질
slightly viscous colorless to pale yellow solution
안전 및 규제
| GHS 분류 | DangerH226 (67.3%): Flammable liquid and vapor [Warning Flammable liquids]P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 260 reports by companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Chemical: 1-Propanol, zirconium(4+) salt1-Propanol, zirconium(4+) salt (4:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Propanol, zirconium(4+) salt (4:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 01-12-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/249021-Propanol, zirconium(4+) salt: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| 운송 라벨(DOT) | Flammable Liquid |
| 화재 위험 | Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: |
| 건강 유해성 | Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: |
| 반응성 그룹 | Bases, Strong |
| Reactivity Alerts | Highly Flammable |
| Reactivity Profile | TETRA-N-PROPYL ZIRCONATE is an metal alkoxide, which is a strong base. |
| Air and Water Reactions | Flammable. Insoluble in water. |
| Hazard Classes and Categories | Flam. Liq. 3 (67.3%) |
| 소화 | Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: |
| 응급 처치 | Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: |
| 비화재 누출 대응 | Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: |
| Isolation and Evacuation | Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: |
| Protective Action Criteria (PAC) | 36 [mg/m3]300 [mg/m3]1800 [mg/m3] |
| Personal Protective Equipment (PPE) | Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: |
| Immediately Dangerous to Life or Health (IDLH) | 25 mg Zr/m3 (NIOSH, 2024) |
| 수질 위해 등급(WGK) | 1 |
| TSCA 등재 상태 | TSCA listed |
| 운송 번호(UN) | UN 1993 3/PG 3 |
| 관세 코드 | 29310099 |
| 위험 문구(R) | 10-41-67 |
| 위험 표시 | Xi |
| 안전 문구(S) | 26-39 |
| 포장분류 | II |
| 위험 등급 | 3Eye Dam. 1Flam. Liq. 3STOT SE 3 |
| 기존화학 물질 | KE-35649 |
| F 고인화성물질 | 10-21 |
| 저장 분류 | 3 - Flammable liquids |
용도
용도
Zirconium(IV) n-propoxide is used as a precursor in the production of zirconia. It is also used to study the thermophysical properties like thermal conductivity and thermal effusivity of hybrid films and thereby adjusting optic properties of the films.
일반 설명
A yellow-colored liquid with an alcohol-like odor. Has about the same density as water and is insoluble in water. Flash point below 141°F. Vapors are heavier than air. May be irritating to skin, eyes, and mucous membranes.