기본 정보
- 표준 SMILES
N[C@H](Cc1c[nH]c2ccccc12)C(=O)O- InChIKey
QIVBCDIJIAJPQS-SECBINFHSA-N- 분자식
- C11H12N2O2
- 평균 분자량
- 204.22 g/mol
- 단동위원소 질량
- 204.08987762
개요
D(+)-tryptophan is a white solid. (NTP, 1992)
이름 및 식별자
- 우선 이름
- D-Tryptophan
- IUPAC
- (2R)-2-amino-3-(1H-indol-3-yl)propanoic acid
- 영어명
- D-Tryptophan
- 분자식
- C11H12N2O2
- 분자량
- 204.23
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
153-94-6- PubChem CID
- 9060
- DTXSID
DTXSID0046989- ChEMBL
CHEMBL292303- ChEBI
CHEBI:16296- UNII
- 7NS97N9H1G
- EC Number
- 205-819-9
- Nikkaji
- J9.185E
물성
구조 계산 물성
- XLogP
- -1.1
- 극성 표면적
- 79.1 Ų
- 수소 결합 공여자 수
- 3
- 수소 결합 수용자 수
- 3
- 회전 가능 결합 수
- 3
- 무거운 원자 수
- 15
- 형식 전하
- 0
- 복잡도
- 245
실험 및 물리화학적 성질
Melting Point
527 to 540 °F (NTP, 1992)
282-85 dec °C
282 - 85 °C
Physical Description
D(+)-tryptophan is a white solid. (NTP, 1992)
White solid; [CAMEO] White powder; [Alfa Aesar MSDS]
Solid
Collision Cross Section
151.5 Ų [M-H]- [CCS Type: DT; Buffer gas: N2; Ionization: ESI-; Dataset: TOXCAST; Source Identifier: DTXSID0046989]
142.6 Ų [M-H]-
물리화학적 성질
- 녹는점
- 282 · 282-285 °C (dec.)(lit.)
- 끓는 점
- 342.72 °C · 342.72°C (rough estimate)
- 밀도
- 1.1754 · 1.1754 (rough estimate)
- 굴절률
- 31 ° · 31 ° (C=1, H2O)
- 저장 조건
- Keep in dark place,Inert atmosphere,Room temperature
- 용해도
- 수성 염기(약간 용해됨), DMSO(약간 용해됨, 가열, 초음파 처리), 메탄올(약간 용해됨)
- 산도 계수 (pKa)
- 2.3 · 2.30±0.10(Predicted)
- 물리적 상태
- 가루
- 색상
- 흰색에서 약간 노란색
- 생물학적 소스
- synthetic (organic)
- 수용성
- 11 g/L · 11 g/L (20 ºC)
- BRN
- 86198 · 86198
- 안정성
- 안정적인. 산화제와 호환되지 않습니다.
- InChI
- 1S/C11H12N2O2/c12-9(11(14)15)5-7-6-13-10-4-2-1-3-8(7)10/h1-4,6,9,13H,5,12H2,(H,14,15)/t9-/m1/s1
- InChIKey
- QIVBCDIJIAJPQS-SECBINFHSA-N
- SMILES
- N[C@H](Cc1c[nH]c2ccccc12)C(O)=O
- LogP
- 0.704 · 0.704 (est)
- EPA
- D-Tryptophan (153-94-6)
화학적 성질
white powder
안전 및 규제
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 87.5% (7 of 8) of all reports.
Warning
H315 (12.5%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 8 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Reactivity Profile
Acidic salts, such as D(+)-TRYPTOPHAN, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
안전 및 보호
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, you should dampen the solid spill material with alcohol, then transfer the dampened material to a suitable container. Use absorbent paper dampened with alcohol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminate area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
안전 데이터
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- YN6129000
- HS 번호
- 29339990
- risk_code
- 36/37/38-41-37/38-22
- hazard_code
- Xi
- safety_code
- 24/25-36/37/39-36-26
- 위험 등급
- IRRITANT
- F 고인화성물질
- 8
- 스토리지 클래스
- 11 - Combustible Solids
화학 및 산업
용도 및 제조
응용 분야
용도An essential amino acid found in naturally produced pedtides. Unlike its stereoisomer, L-tryptophan, it is not used in structural or enzyme proteins.
일반 설명White solid.
상·하류 제품 정보
상류 원료
하류 제품
공급사50 곳
추가 설명
정의ChEBI: The D-enantiomer of tryptophan.
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