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라로민 C 260

Bis(4-amino-3-methylcyclohexyl)methane

HCID 91555
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
6864-37-5
표준 SMILES
CC1CC(CC2CCC(N)C(C)C2)CCC1N
InChIKey
IGSBHTZEJMPDSZ-UHFFFAOYSA-N
분자식
C15H30N2
평균 분자량
238.41 g/mol
단동위원소 질량
238.24089897

개요

amine curing agent for epoxy resin

이름 및 식별자

우선 이름
Bis(4-amino-3-methylcyclohexyl)methane
IUPAC
4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine
현지명
라로민 C 260
영어명
4,4'-Methylenebis(2-methylcyclohexylamine)
분자식
C15H30N2
분자량
238.41

이름 및 동의어

6864-37-5Bis(4-amino-3-methylcyclohexyl)methane4,4'-Methylenebis(2-methylcyclohexylamine)3,3'-Dimethyl-4,4'-diaminodicyclohexylmethaneCyclohexanamine, 4,4'-methylenebis[2-methyl-DTXSID60296702,2'-Dimethyl-4,4'-methylenebis(cyclohexylamine)3K4H01E55XCyclohexanamine, 4,4'-methylenebis(2-methyl-DTXCID209670RefChem:120131Cyclohexanamine, 4,4'-methylene-bis(2-methyl-)
이름 더 보기
라로민C2602,2’-다이메틸-4,4’-메틸렌비스(사이클로헥실아민)라로민C2604,4'-메틸렌 비스(2-메틸사이클로헥산아민)4,4'-메틸렌 비스(2-메틸사이클로헥실아민)4,4'-메틸렌비스(2-메틸사이클로헥산아민)4,4'-메틸렌비스(2-메틸사이클로헥실아민)사이클로헥산아민, 4,4'-메틸렌 비스(2-메틸-)사이클로헥산아민, 4,4'-메틸렌비스(2-메틸-)사이클로헥실아민, 4,4'-메틸렌 비스(2-메틸-)사이클로헥실아민, 4,4'-메틸렌비스(2-메틸-)DMDCMACM4,4'-methylenebis(2-methylcyclohexan-1-amine)3,3’-Dimethyl-4,4’-diaminodicyclohexylmethaneDMDC/MACMMACM 、DMDCDimethyldicycan

물성

구조 계산 물성

XLogP
2.8
극성 표면적
52 Ų
수소 결합 공여자 수
2
수소 결합 수용자 수
2
회전 가능 결합 수
2
무거운 원자 수
17
형식 전하
0
복잡도
217

실험 및 물리화학적 성질

LogP2.5
DensityRelative density (water = 1): 0.95
SolubilitySolubility in water, g/100ml at 20 °C: 0.4
Endocrine DisruptorsPotential endocrine disrupting compound
Boiling Point342 °C
Melting Point-7 °C
Vapor PressureVapor pressure, Pa at 20 °C: 0.08
Food Contact Substances · 2건

FCS -> FDA Cumulative Estimated Daily Intake (CEDI)

FCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

Physical Description · 2건

Liquid

COLOURLESS-TO-YELLOW LIQUID.

물리화학적 성질

녹는점
-7 °C · -7°C
끓는 점
93 · 93-100 °C(lit.)

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P262, P264, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Danger

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 4건

Chemical: Cyclohexanamine, 4,4'-methylenebis[2-methyl-

Cyclohexanamine, 4,4'-methylenebis[2-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cyclohexanamine, 4,4'-methylenebis[2-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: 2,2'-dimethyl-4,4'-methylenebis(cyclohexylamine) (EC: 229-962-1)

4,4'-Methylenebis(2-methylcyclohexylamine): Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Cyclohexanamine, 4,4'-methylenebis[2-methyl-
Fire HazardsCombustible.
EC ClassificationSymbol: T, C, N; R: 22-23/24-35-51/53; S: (1/2)-26-36/37/39-45-61
Chemical DangersThe substance is a weak base. Decomposes on burning. This produces nitrogen oxides.

화학 및 산업

용도 및 제조

U.S. Production2023: 1,000,000 - <2,500,000 lb
Consumer UsesCatalyst
Industry UsesIntermediate
General Manufacturing Information · 2건

Not Known or Reasonably Ascertainable

Cyclohexanamine, 4,4'-methylenebis[2-methyl-: ACTIVE

응용 분야

용도4,4'-Methylenebis(2-methylcyclohexylamine) can be used as epoxy curing agents.

일반 설명4,4′-Methylenebis(2-methylcyclohexylamine) is an alicyclic diamine.

상·하류 제품 정보

상류 원료

3,3`-디메틸-4,4`-디아미노디페닐메탄

공급사100 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]

관련 반응

0건
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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
229-962-14,4'-methylenebis(2-methylcyclohexanamine)Dimethyldicyane4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine4,4''-Methylenebis[2-methylcyclohexanamine]MFCD00075535EINECS 229-962-1UNII-3K4H01E55X

데이터베이스 식별자

CAS
6864-37-5
PubChem CID
91555
DTXSID
DTXSID6029670
ChEMBL
CHEMBL3189048
UNII
3K4H01E55X
EC Number
229-962-1
Nikkaji
J39.615J
밀도
0.94 g/mL · 0.94 g/mL at 25 °C(lit.)
증기압
0.08 Pa · 0.08Pa at 20℃
굴절률
20 · n20/D 1.499(lit.)
인화점
230 °F · >230 °F
저장 조건
Keep in dark place,Inert atmosphere,Room temperature
용해도
3.6 g/L · 3.6g/L
물리적 상태
투명한 액체
산도 계수 (pKa)
11.03 · 11.03±0.70(Predicted)
색상
Colorless to Light yellow to Light orange
수소이온지수(pH)
11 · 11 (3.6g/l, H2O, 20℃)
폭발한계
0.5 · 0.5-2.8%(V)
수용성
2.01 g/L · 2.01g/L at 20℃
InChI
1S/C15H30N2/c1-10-7-12(3-5-14(10)16)9-13-4-6-15(17)11(2)8-13/h10-15H,3-9,16-17H2,1-2H3
InChIKey
IGSBHTZEJMPDSZ-UHFFFAOYSA-N
SMILES
CC1CC(CCC1N)CC2CCC(N)C(C)C2
LogP
2.3 at · 2.3 at 23℃
EPA
4 · Cyclohexanamine, 4,4'-methylenebis[2-methyl- (6864-37-5)
화학적 성질 · 2건

Colorless transparent viscous liquid

4,4'-Methylenebis(2-methylcyclohexylamine) (MACM) is a colorless/yellowish liquid with a water solubility of 3.6 g/l at 20°C and a vapor pressure of 0.08 Pa at 20°C. The measured log KOW is 2.51 at 25 °C. However, due to the Lewis base character of the substance, the experimental determination of the log KOW is inaccurate. The density of the substance (ca. 0.95 g/cm3 at 20°C) is virtually the same as that of water.

Packaging and Labelling
Do not transport with food and feedstuffs.
Hazard Classes and Categories · 5건

Acute Tox. 4 (100%)

Skin corrosion - category 1A

Acute toxicity (Oral) - Category 4

Hazardous to the aquatic environment (Acute) - Category 2

Acute Tox. 3 *

안전 및 보호

Fire FightingUse water spray, powder, alcohol-resistant foam, carbon dioxide.
First Aid Measures · 4건

Fresh air, rest. Refer for medical attention. Half-upright position. Artificial respiration may be needed.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention .

Safe StorageSeparated from food and feedstuffs.
Spillage DisposalConsult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible.
Eye PreventionWear face shield or eye protection in combination with breathing protection.
Fire PreventionNO open flames.
Inhalation RiskA harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20 °C; on spraying or dispersing, however, much faster.
Skin PreventionProtective gloves. Protective clothing.
Exposure PreventionAVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!
Ingestion PreventionDo not eat, drink, or smoke during work. Wash hands before eating.
Inhalation PreventionUse ventilation, local exhaust or breathing protection.
Effects of Long Term Exposure · 1건

The substance may have effects on the skin. This may result in chronic disease (scleroderma). The substance may have effects on the blood, cardiovascular system, kidneys and liver. This may result in anaemia, cardiac disorders, kidney impairment and liver impairment.

독성 정보

Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.
Signs and Symptoms · 4건

Burning sensation. Cough. Sore throat. Laboured breathing. Shortness of breath. Symptoms may be delayed.

Serious skin burns. Pain. Redness.

Pain. Redness. Severe deep burns.

Abdominal pain. Burning sensation. Shock or collapse.

ICSC Environmental DataThe substance is toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment.

안전 데이터

wgk
3
tsca
TSCA listed
ridadr
UN 2927 6.1/PG 2
독성
LC50 ihl-rat: 420 mg/m3/4H NTIS** OTS0539620-1
HS 번호
29213000
risk_code
22-23/24-35-51/53
hazard_code
T,C,N
safety_code
26-36/37/39-45-61
포장분류
II
위험 등급
8
기존화학 물질
KE-23839
Hazard Classifications
Acute Tox. 2 InhalationAcute Tox. 3 DermalAcute Tox. 4 OralAquatic Chronic 2Skin Corr. 1A
스토리지 클래스
6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
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