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(2R,2'R)-2β,2'β-Bi[옥시란]

(2R,2'R)-2,2'-Bioxirane

HCID 92270
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
298-18-0
표준 SMILES
C1O[C@H]1[C@H]1CO1
InChIKey
ZFIVKAOQEXOYFY-QWWZWVQMSA-N
분자식
C4H6O2
평균 분자량
86.09 g/mol
단동위원소 질량
86.03677943

개요

D,l-1,2:3,4-diepoxybutane is a colorless to yellow liquid. (NTP, 1992)

이름 및 식별자

우선 이름
(2R,2'R)-2,2'-Bioxirane
IUPAC
(2R)-2-[(2R)-oxiran-2-yl]oxirane
현지명
(2R,2'R)-2β,2'β-Bi[옥시란]
영어명
(2R,2'R)-2β,2'β-Bi[oxirane]
분자식
C4H6O2
분자량
86.09

이름 및 동의어

l-Butadiene epoxideD-Erythritol anhydride(2R,2'R)-2,2'-bioxiraneD-Threitol, 1,2:3,4-dianhydro-2,2'-Bioxirane, (2R,2'R)-4KEO88VB9L2,2'-Bioxirane, (R-(R*,R*))-30419-67-1DTXSID801031195RefChem:934700DTXCID001516206608-478-8
이름 더 보기
(2R,2'R)-2β,2'β-Bi[옥시란]2R:3R-Diepoxybutane2,2'-Bi[(2R)-oxirane]Butane, D-1,2:3,4-diepoxy-(R-(R*,R*))-2,2'-Bioxirane(2R,2'R)-2β,2'β-Bi[oxirane]1,2:3,4-Dianhydro-D-threitol
D-Diepoxybutane(R,R)-diepoxybutane1,2,3,4-Diepoxybutane298-18-0GQK28B9ZWF(2S)-2-[(2R)-oxiran-2-yl]oxiranerel-(2R,2'R)-2,2'-BioxiraneDiepoxybutane, (R*,R*)-(+/-)-

데이터베이스 식별자

CAS
298-18-0、30419-67-1
PubChem CID
92270
DTXSID
DTXSID801031195
ChEBI
CHEBI:51048
UNII
4KEO88VB9L、GQK28B9ZWF
EC Number
206-060-6、608-478-8

물성

구조 계산 물성

XLogP
-0.5
극성 표면적
25.1 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
1
무거운 원자 수
6
형식 전하
0
복잡도
61.9

실험 및 물리화학적 성질

SpringerMaterials PropertiesOptical coefficient
Density1.1157 at 68 °F (NTP, 1992) - Denser than water; will sink
Solubilitygreater than or equal to 100 mg/mL at 67.1 °F (NTP, 1992)
Flash Point114 °F (NTP, 1992)
Boiling Point291 °F at 760 mmHg (NTP, 1992)
Melting Point39 °F (NTP, 1992)
Vapor Pressure3.9 mmHg at 68 °F (NTP, 1992)
Physical DescriptionD,l-1,2:3,4-diepoxybutane is a colorless to yellow liquid. (NTP, 1992)

물리화학적 성질

끓는 점
144 °C · 144 °C
밀도
1.383 · 1.383±0.06 g/cm3(Predicted)

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

유해성 정보

DOT LabelPoison Inhalation Hazard Flammable Liquid Corrosive
Fire HazardsThis chemical is combustible. (NTP, 1992)
Health Hazards · 1건

SYMPTOMS: Exposure to this compound in humans may cause swollen eyelids, irritation of the upper respiratory tract and painful eye irritation 6 hours past exposure. Systemic toxicity may be caused by skin contact. It causes pronounced nasal and eye irritation at 10 ppm but barely recognizable at 5 ppm after 5-minute exposure. It may also cause mucous membrane irritation. Other symptoms include severe pulmonary irritation and depression of the hematopoietic system. Other symptoms include lacrimation, clouding of the cornea, labored breathing, lung congestion, atrophy of the thymus, involution of the spleen and decreased weight gain. Causes of death are pulmonary edema and shock following extreme local irritation. It may also cause reduced or loss of spermatogenesis, leukopenia and lymphopenia.

Reactive GroupEpoxides
Reactivity AlertsHighly Flammable
Reactivity ProfileD,L-1,2:3,4-DIEPOXYBUTANE is incompatible with acids, bases and oxidizing agents. Reacts with 4-(4'-nitrobenzyl)pyridine. Also reacts with alcohols, amines, phenols. (NTP, 1992)
Air and Water ReactionsHighly flammable. Water soluble. Slowly hydrolyzes in water.

안전 및 보호

Fire FightingFires involving this compound should be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1건

화학 및 산업

공급사1 곳

济南尚博医药股份有限公司0531-61320525 15866703830 · [email protected]

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이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
Nikkaji
J59.681G

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 131 [Flammable Liquids - Toxic]:
Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.