Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Bicyclo(2.2.1)heptane
camphenilane · Norbornylane · BICYCLO[2.2.1]HEPTANE · NSC 91457 · ORBORNANE · NORBORNANE · Norsantane · Norfenchane
식별자 및 물리적 특성
| CAS No. | 279-23-2 |
|---|---|
| 분자식 | C7H12 |
| 평균 분자량 | 96.17 g/mol |
| 단동위원소 질량 | 96.09390038 g/mol |
| SMILES | C1CC2CCC1C2 |
| InChIKey | UMRZSTCPUPJPOJ-UHFFFAOYSA-N |
| PubChem CID | 9233 |
| ChEBI | CHEBI:71546 |
| EC No. | 205-996-2 |
| DTXSID | DTXSID4075376 |
화학 및 물리적 성질
| XLogP | 3 |
|---|---|
| 극성 표면적 | 0 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 0 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 7 |
| 형식 전하 | 0 |
| 복잡도 | 58.1 |
| Solvents | Solvents -> Aliphatics, Saturated (<C12) |
| SpringerMaterials Properties | Schoenflies notation |
| LogP(분배 계수) | 3.78 |
| 증기압 | 33.0 [mmHg] |
| Physical Description | White solid[Acros Organics MSDS] |
| 녹는점 | 85-88 °C (lit.) |
| 끓는 점 | 106 °C |
| 밀도 | 0.914±0.06 g/cm3 (20 ºC 760 Torr) |
| 굴절률 | 1.4770 (estimate) |
| 인화점 | -0.2±11.7℃ |
| 저장 조건 | 2-8°C |
| 용해도 | 아세톤에 용해됨 |
| 물리적 상태 | powder to crystal |
| 색상 | 흰색에서 거의 흰색 |
| 비열 | Cp(crystal): 1.57 J/(g·K), at 25℃ |
| InChI | 1S/C7H12/c1-2-7-4-3-6(1)5-7/h6-7H,1-5H2/t6-,7+ |
| InChIKey | UMRZSTCPUPJPOJ-KNVOCYPGSA-N |
| SMILES | C1C[C@@H]2CC[C@H]1C2 |
| EPA | Bicyclo[2.2.1]heptane (279-23-2) |
안전 및 규제
| 규제 정보 | Bicyclo2.2.1heptane: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
|---|---|
| 유해성 요약 | Intravenous LD50 (mouse) = 56 mg/kg[RTECS] May cause irritation[Acros Organics MSDS] |
| 유해 작용 | Neurotoxin - Acute solvent syndrome |
| 수질 위해 등급(WGK) | 3 |
| RTECS 번호 | RB6945000 |
| 독성 | mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#04038, |
| 관세 코드 | 2902.19.0050 |
| 저장 분류 | 11 - Combustible Solids |
용도
개요
Norbornane (also known as bicyclo[2.2.1]heptane or norcamphane) is an organic compound and a saturated hydrocarbon with chemical formula C7H12. It is a crystalline compound with a melting point of 88 °C. The carbon skeleton is derived from cyclohexane ring with a methylene bridge in the 1,4- position, and is a bridged bicyclic compound. The compound is a prototype of a class of strained bicyclic hydrocarbons.
제조 및 합성 방법
제조 방법
Norbornane is obtained by adding ethylene to cyclopentadiene under heat and pressure and then hydrogenating.