Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
사이클로헥센옥사이드
사이클로헥센옥사이드 · 시클로헥센옥사이드 · 1,2-에폭시사이클로헥세인 · 7-OXABICYCLO[4.1.0]HEPTANE · 1,2-EPOXYCYCLOHEXANE · EPOXYCYCLOHEXANE · 1,2-epoxy-cyclohexan · (1R,6S)-7-Oxabicyclo[4.1.0]heptane
식별자 및 물리적 특성
| CAS No. | 286-20-4 |
|---|---|
| 분자식 | C6H10O |
| 평균 분자량 | 98.14 g/mol |
| 단동위원소 질량 | 98.07316494 g/mol |
| SMILES | C1CCC2OC2C1 |
| InChIKey | ZWAJLVLEBYIOTI-UHFFFAOYSA-N |
| PubChem CID | 9246 |
| ChEMBL | CHEMBL1361659 |
| EC No. | 206-007-7 |
| DTXSID | DTXSID6024880 |
| 현지명 | 사이클로헥센옥사이드 |
화학 및 물리적 성질
| XLogP | 1.2 |
|---|---|
| 극성 표면적 | 12.5 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 1 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 7 |
| 형식 전하 | 0 |
| 복잡도 | 70 |
| 냄새 | STRONG ODOR |
| 밀도 | 0.967 @ 25 °C/4 °C0.97 g/mL at 25 °C(lit.) |
| Color/Form | COLORLESS LIQUID |
| 용해도 | SOL IN ALC, ETHER, ACETONEINSOL IN WATERVERY SOL IN BENZENESOL IN CHLOROFORM |
| 인화점 | 81 °C CC81 °F |
| 끓는 점 | 129-130 °C129-130 °C(lit.) |
| 녹는점 | GREATER THAN -10 °C-40 °C |
| 굴절률 | INDEX OF REFRACTION: 1.4503 @ 25 °C/Dn20/D 1.452(lit.) |
| Physical Description | Colorless liquid[HSDB] |
| Kovats Retention Index | 11581152 |
| 증기압 | 12 hPa (20 °C) |
| 저장 조건 | Store below +30°C. |
| 물리적 상태 | 액체 |
| 색상 | 무색~황색으로 투명함 |
| 폭발한계 | 1.2-6.5%(V) |
| 용해도 | 불용성 |
| BRN | 383568 |
| InChI | 1S/C6H10O/c1-2-4-6-5(3-1)7-6/h5-6H,1-4H2 |
| InChIKey | ZWAJLVLEBYIOTI-UHFFFAOYSA-N |
| SMILES | C1CCC2OC2C1 |
| NIST | Cyclohexene oxide(286-20-4) |
| EPA | Cyclohexene oxide (286-20-4) |
화학적 성질
clear colorless to yellow liquid
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 3.2% (5 of 158) of reports.DangerH226 (95.6%): Flammable liquid and vapor [Warning Flammable liquids]H302 (96.2%): Harmful if swallowed [Warning Acute toxicity, oral]H311 (84.8%): Toxic in contact with skin [Danger Acute toxicity, dermal]H312 (20.9%): Harmful in contact with skin [Warning Acute toxicity, dermal]H314 (77.8%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]H318 (58.9%): Causes serious eye damage [Danger Serious eye damage/eye irritation]H331 (72.2%): Toxic if inhaled [Danger Acute toxicity, inhalation]H341 (52.5%): Suspected of causing genetic defects [Warning Germ cell mutagenicity]P203, P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P318, P321, P330, P361+P364, P362+P364, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 158 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Reported as not meeting GHS hazard criteria per 5 of 158 reports by companies.There are 15 notifications provided by 153 of 158 reports by companies with hazard statement code(s).Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| 규제 정보 | Chemical: 7-Oxabicyclo[4.1.0]heptaneStatus: Active Update: 20-06-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/5629Epoxycyclohexane: Does not have an individual approval but may be used under an appropriate group standard |
| 화재 가능성 | FLAMMABLE, DANGEROUS FIRE RISK. |
| 유해성 요약 | A tumorigen and mutagen[RTECS] An irritant[MSDSonline] |
용도
용도
Cyclohexene oxide has been patented for use as an insecticidal fumigant. Cyclohexene oxide is an important intermediate in the organic industry. It is employed in the manufacture of medicines, pesticides, dyes, and perfumes. In addition, cyclohexene oxide can be used as a monomer in polymerization, chain-cutting agent, flame retardant and diluting agent among other uses. Cyclohexene oxide is useful as a monomer in polymerization with CO2 for production of cyclic carbonates and polycarbonates in the presence of different catalysts.