16920-45-9O=C([O-])[O-].[Ag+].[Ag+]KQTXIZHBFFWWFW-UHFFFAOYSA-L16920-45-9、534-16-7DTXSID90423846.1 at 68 °F (USCG, 1999) - Denser than water; will sink
6.077 @25 °C
Silver carbonate is an odorless yellow to brown solid. Sinks in water. (USCG, 1999)
Light yellow solid; Darkens on drying and light exposure; [Merck Index] Yellow odorless powder; Insoluble in water (0.032 g/L); [Alfa Aesar MSDS]
This chemical does not meet GHS hazard criteria for 0.6% (1 of 166) of reports.
Danger
H315 (25.3%): Causes skin irritation [Warning Skin corrosion/irritation];H318 (74.7%): Causes serious eye damage [Danger Serious eye damage/eye irritation];H319 (24.7%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H335 (25.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation];H400 (69.9%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H410 (71.7%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]
P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 166 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 1 of 166 reports by companies.;There are 13 notifications provided by 165 of 166 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
Chemical: Carbonic acid, disilver(1+) salt
Status: Active Update: 16-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5603
Silver carbonate: Does not have an individual approval but may be used under an appropriate group standard
Silver and its compounds can be absorbed via inhalation, while silver compounds can also be absorbed orally and dermally. It distributes throughout the body in the blood, particularily to the liver. Insoluble silver salts are transformed into soluble silver sulfide albuminates, bind to amino or carboxyl groups in RNA, DNA, and proteins, or are reduced to metallic silver by ascorbic acid or catecholamines. Metallic silver is oxidized and may deposit in the tissues, causing arygria. Silver is eliminated primarily in the faeces. (L808)
Used as an oxidizing agent (to convert alcohols to aldehydes and ketones) and as a biological stain; [Merck Index]
Silver carbonate is used as a reagent in organic synthesis such as the Koenigs-Knorr reaction. It is also employed to convert alkyl bromides into alcohols. (L815)
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11 [mg/m3]
120 [mg/m3]
740 [mg/m3]
Silver itself is not toxic to humans, but most silver salts are. In large doses, silver and compounds containing it can be absorbed into the circulatory system and become deposited in various body tissues, leading to argyria, which results in a blue-grayish pigmentation of the skin, eyes, and mucous membranes. Argyria is rare, and although, so far as known, this condition does not otherwise harm a person's health, it is disfiguring and usually permanent. Mild forms of argyria are sometimes mistaken for cyanosis. (L809)
Metallic silver is oxidized and may deposit in the tissues, causing arygria. The silver ion is known to inhibit glutathione peroxidase and NA+,K+-ATPase activity, disrupting selenium-catalyzed sulfhydryl oxidation-reduction reactions and intracellular ion concentrations, respectively. Silver nanoparticles are believed to disrupt the mitochondrial respiratory chain, causing oxidative stress, reduced ATP synthesis, and DNA damage. (L808, A243, A244, A245, A246)
Exposure to high levels of silver for a long period of time may result in a condition called arygria, a blue-gray discoloration of the skin and other body tissues. Argyria is a permanent effect but does not appear to be harmful to health. Exposure to high levels of silver in the air has resulted in breathing problems, lung and throat irritation, and stomach pains. Skin contact with silver can cause mild allergic reactions such as rash, swelling, and inflammation in some people. (L808)
Chemical: Carbonic acid, disilver(1+) salt
Status: Active Update: 16-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5603
Silver carbonate: Does not have an individual approval but may be used under an appropriate group standard