테트라하이드로푸르푸릴 아크릴레이트
테트라하이드로푸르푸릴아크릴레이트 · 테트라히드로푸르푸릴아크릴산 · 테트라히드로푸르푸릴아크릴산(TETRAHYDROFURFURYLACRYLATE) · 테트라하이드로퍼퓨릴 아크릴레이트 · 테트라히드로푸르푸릴아크릴레이트 · Tetrahydrofuran acrylate · sr285 · Oxolan-2-ylmethyl prop-2-enoate
식별자 및 물리적 특성
| CAS No. | 2399-48-6 |
|---|---|
| 분자식 | C8H12O3 |
| 평균 분자량 | 156.18 g/mol |
| 단동위원소 질량 | 156.07864424 g/mol |
| SMILES | C=CC(=O)OCC1CCCO1 |
| InChIKey | YNXCGLKMOXLBOD-UHFFFAOYSA-N |
| PubChem CID | 94232 |
| ChEMBL | CHEMBL3187472 |
| EC No. | 219-268-7 |
| DTXSID | DTXSID8044884 |
| 현지명 | 테트라하이드로푸르푸릴 아크릴레이트 |
화학 및 물리적 성질
| XLogP | 1.1 |
|---|---|
| 극성 표면적 | 35.5 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 3 |
| 회전 가능 결합 수 | 4 |
| 무거운 원자 수 | 11 |
| 형식 전하 | 0 |
| 복잡도 | 153 |
| 끓는 점 | 188.6 °F87 °C/9 mmHg (lit.) |
| Physical Description | LiquidOther SolidClear liquid with a musty odor. |
| 밀도 | 1.064 g/mL at 25 °C (lit.) |
| 증기압 | 1.19hPa at 25℃ |
| 굴절률 | n20/D 1.46(lit.) |
| 인화점 | >230 °F |
| 저장 조건 | Sealed in dry,Room Temperature |
| 용해도 | 물에 용해됨 |
| 물리적 상태 | 투명한 액체 |
| 색상 | 무색 내지 거의 무색 |
| 용해도 | 79.1g/L at 20.9℃ |
| BRN | 113115 |
| 화장품 원료 기능 | 점도 조절 |
| InChI | 1S/C8H12O3/c1-2-8(9)11-6-7-4-3-5-10-7/h2,7H,1,3-6H2 |
| InChIKey | YNXCGLKMOXLBOD-UHFFFAOYSA-N |
| SMILES | C=CC(=O)OCC1CCCO1 |
| LogP(분배 계수) | 0.81 at 21.7℃ |
| EPA | Tetrahydrofurfuryl acrylate (2399-48-6) |
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 3.7% (16 of 434) of reports.DangerH302 (47.9%): Harmful if swallowed [Warning Acute toxicity, oral]P203, P260, P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P318, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P363, P391, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 434 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Chemical: 2-Propenoic acid, (tetrahydro-2-furanyl)methyl ester2-Propenoic acid, (tetrahydro-2-furanyl)methyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, (tetrahydro-2-furanyl)methyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 01-07-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/201492-Propenoic acid, (tetrahydro-2-furanyl)methyl ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| 기타 안전 정보 | Evaluation - Tetrahydrofurfuryl acrylate and tetrahydrofurfuryl methacrylate |
| Hazard Classes and Categories | Acute Tox. 4 (47.9%)Acute toxicity (Oral) - Category 4 |
| 수질 위해 등급(WGK) | 3 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | UD3670893 |
| 운송 번호(UN) | 3334 |
| 관세 코드 | 29321900 |
| 위험 문구(R) | 36/38 |
| 위험 표시 | Xi |
| 안전 문구(S) | 26 |
용도
용도
Tetrahydrofurfuryl acrylate may be used as an acrylic matrix for silver nanoparticles/polymer nanocomposites . It can form copolymers with butadiene. Prior to transfer printing, cellulosic and proteinic fibers are grafted with THFA.
용도
Tetrahydrofurfuryl acrylate (THFA) can be used to prepare bio-based photopolymers. A series of thermostable shape memory photopolymers were synthesised from a mixture of two bio-based monomers, THFA and tridecyl methacrylate, with the addition of a small amount of 1,3-benzodithiol. Ethyl phenylphosphonate (2,4,6 trimethylbenzoyl) was used as a photoinitiator. The biorenewable carbon content of these photopolymers ranged from (63.7-74.9) %. The increase in THFA content in the photocured resins increased the light curing rate, increased the stiffness, and improved the mechanical and thermal properties of the obtained polymers. The developed bio-based photopolymers could replace petroleum-derived thermostable shape memory polymer analogues in a wide range of applications[1].