m-Fluorotoluene (HCID 9606)

개요

3-fluorotoluene appears as a colorless liquid with an aromatic odor. Boiling point 239 °C. Flash point 63 °F. Density 0.991 g / cm3 --- may float or sink in water. (USCG, 1999)

이름 및 식별자

우선 이름: m-Fluorotoluene
IUPAC: 1-fluoro-3-methylbenzene
현지명: 플로로톨루엔(3-)
영어명: 3-Fluorotoluene
분자식: C7H7F
분자량: 110.13

이름 및 동의어

3-Fluorotoluene352-70-51-Fluoro-3-methylbenzeneM-FLUOROTOLUENEBenzene, 1-fluoro-3-methyl-Toluene, m-fluoro-1-Methyl-3-fluorobenzeneF72W445DQ0NSC 8860NSC-8860EINECS 206-524-8M-FLUOROTOLUENE [MI]

이름 더 보기

M-플루오로톨루엔3-플루오로톨루엔플로로톨루엔(3-)3-플루오로톨루엔(3-FLUOROTOLUENE)3-FLUOROBENZENE3-FluortoluolJACS-352-70-5Fluorotoluene2m-Fluro Toluenetoluene,3-fluoro-Toluene,m-fluoro-

DTXSID2059855EC 206-524-83fluorotoluenemTolyl fluorideToluene, mfluoro1Fluoro3methylbenzene1Methyl3fluorobenzeneM-TOLYL FLUORIDE

데이터베이스 식별자

CAS: 2599-73-7、352-70-5
PubChem CID: 9606
DTXSID: DTXSID2059855
ChEMBL: CHEMBL345698
UNII: F72W445DQ0
EC Number: 206-524-8
Nikkaji: J61.495E

물성

구조 계산 물성

XLogP: 2.7
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 8
형식 전하: 0
복잡도: 70.8

실험 및 물리화학적 성질

Chemical ClassesOther Classes -> Halogenated Monoaromatics

SpringerMaterials Properties13C nuclear magnetic resonance spectrum

Density0.9986 at 68 °F (USCG, 1999) - Less dense than water; will float

Flash Point49 °F (USCG, 1999)

Boiling Point240.8 °F at 760 mmHg (USCG, 1999)

Melting Point-125.9 °F (USCG, 1999)

물리화학적 성질

녹는점: -87 °C · -87 °C
끓는 점: 115 °C · 115 °C(lit.)
밀도: 0.991 g/mL · 0.991 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.469(lit.)
인화점: 49 °F · 49 °F
저장 조건: 30 °C · Store below +30°C.
물리적 상태: 투명한 액체
색상: 무색 내지 거의 무색
Specific Gravity: 0.991 · 0.991
수용성: 섞일 수 없음
Merck: 14 · 14,4180
BRN: 1903631 · 1903631
Dielectric constant: 5.42 · 5.4199999999999999
InChI: 1S/C7H7F/c1-6-3-2-4-7(8)5-6/h2-5H,1H3
InChIKey: BTQZKHUEUDPRST-UHFFFAOYSA-N
SMILES: Cc1cccc(F)c1
LogP: 2.75 · 2.75
NIST: 1 · Benzene, 1-fluoro-3-methyl-(352-70-5)
EPA: m-Fluorotoluene (352-70-5)

화학적 성질

clear colorless to light yellow liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 44% (37 of 84) of reports.

Danger

H225 (56%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 84 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 2건

Status: Cease Manufacture Update: 22-05-2013 https://echa.europa.eu/registration-dossier/-/registered-dossier/6237

3-Fluorotoluene: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelFlammable Liquid

Fire HazardsSpecial Hazards of Combustion Products: May contain toxic fluoride fumes.

Health HazardsInhalation causes upper respiratory irritation. Irritating to skin and eyes. May be absorbed through the skin. Prolonged exposure may result in systemic toxic effects. Harmful if swallowed. (USCG, 1999)

Hazards Summary · 1건

An irritant; May cause smarting and reddening of skin if spilled and allowed to remain on clothes; Can be absorbed through skin; Harmful by ingestion; [CHRIS] A mild skin and eye irritant; Causes respiratory tract irritation; [Alfa Aesar MSDS] See m-Chlorotoluene and 4-Chlorotoluene.

Reactive GroupAryl Halides

안전 및 보호

Fire FightingFire Extinguishing Agents: Small fires: dry chemical, CO2, water spray or foam; large fires: water spray, fog or foam. (USCG, 1999)

First AidINHALATION: Move to fresh air. If not breathing, give artificial respiration. if breathing is difficult, give oxygen.

Nonfire Spill ResponseExcerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:

Isolation and EvacuationExcerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:

Personal Protective Equipment (PPE)Wear self-contained positive pressure breathing apparatus and full protective clothing. (USCG, 1999)

안전 데이터

wgk: 2
tsca: TSCA listed
rtecs: XT2578000
ridadr: UN 2388 3/PG 2
HS 번호: 29036990
risk_code: 11-36/37/38
hazard_code: F,Xi
safety_code: 16-26-36-37/39
포장분류: II
위험 등급: 3
기존화학 물질: KE-17062
위험 참고 사항: Flammable/Irritant
Hazard Classifications: Flam. Liq. 2
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

용도 및 제조

General Manufacturing InformationBenzene, 1-fluoro-3-methyl-: ACTIVE

응용 분야

용도3-Fluorotoluene was used in gas phase selective synthesis of 3-fluorobenzaldehyde. It was used in generation of tolyl cations by chemical ionization in mass spectrometry.

일반 설명A colorless liquid with an aromatic odor. Boiling point 239°C. Flash point 63°F. Density 0.991 g / cm3---may float or sink in water.

상·하류 제품 정보

상류 원료

하류 제품

플로로(3-)벤조일클로라이드 4-플루오로-2-메틸벤조산 3-Fluorophenylacetonitrile 2-플루오로-4-메틸아닐린 4-플루오로-2-메틸아닐린 플로로톨루엔(2-)5-플루오로-2-니트로벤조산 3-플루오로벤조트리클로라이드 4-Fluoro-2-methyl-5-nitrobenzoic acid 3-Fluorophenylacetone 3-FLUORO-4-아이오도벤조익산 3-Fluorobenzyl alcohol

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

Changzhou Carman Chemical Co., Ltd.15061933924

武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]

연결된 노트

불러오는 중…

플로로톨루엔(3-)

기본 정보

개요