CAS 13292-87-0 Boron, trihydro(thiobis(methane))-, (T-4)- (HCID 9833925)

이름 및 식별자

우선 이름: Boron, trihydro(thiobis(methane))-, (T-4)-
현지명: 디메틸설파이드보란
영어명: Borane-methyl sulfide complex
분자식: C2H10BS
분자량: 76.97

이름 및 동의어

13292-87-0borane dimethyl sulfideDimethyl sulphide boraneBoron, trihydro[thiobis[methane]]-, (T-4)-Boron, trihydro(thiobis(methane))-, (T-4)-Di-methylsulfide boraneDimethyl sulphide--boraneEINECS 236-313-6RefChem:570117EC 236-313-6Boron, trihydrothiobismethane-, (T-4)-Methyl sulfide, compd. with borane (1:1)

이름 더 보기

디메틸설파이드보란디메틸설파이드보란보레인/ 다이메틸설파이드 혼합물(황화 다이메틸) 트라이하이드로붕소다이메틸설페인과 보레인의 화합물(1:1)디메틸 설파이드 보란보레인과 싸이오비스[메테인] 화합물(1:1)보레인과 황화 다이메틸의 화합물보레인-다이메틸 설파이드 (1:1)보레인-다이메틸 설파이드 착물보레인-다이메틸 설파이드 착물 (1:1)트라이하이드로(싸이오비스(메테인))붕소, (T-4)-황화 다이메틸 보레인황화 메틸과 보레인 화합물(1:1)BMSDimethylsulfide borane complex(Dimethyl sulfide)trihydroboronDMSBborane-methyl sulfideBORANE-DIMETHYLSULFIDEBORANE-DIMETHYLSULFIDE COMPLEXBORANE DIMETHYL SULPHIDE COMPLEXborane dimethyl sulfide complex solution

6AVE9SRR08BORON, TRIHYDRO(THIOBIS(METHANE))-TRIHYDRO(DIMETHYL SULFIDE)BORONDimethyl sulfide boraneborane dimethylsulfideBorane-dimethyl sulfideMethyl Sulfide BoraneMFCD00013189

데이터베이스 식별자

CAS: 13292-87-0
PubChem CID: 9833925
EC Number: 236-313-6

물성

구조 계산 물성

극성 표면적: 25.3 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 4
형식 전하: 0
복잡도: 2.8

실험 및 물리화학적 성질

Density0.789 @25 °C

물리화학적 성질

녹는점: -40 · -40--37°C
끓는 점: 34 °C · ~34 °C
밀도: 1.287 g/mL · 1.287 g/mL at 25 °C
굴절률: 1.457 · 1.4570
인화점: 65 °F · 65 °F
저장 조건: 2 · 2-8°C
용해도: 에틸 에테르, 테트라히드로푸란, 디클로로메탄, 벤젠, 자일렌, 헥산, 디글라임, 디메틸 에테르, 에틸 아세테이트, 톨루엔, 염화메틸렌 및 기타 비양성자성 용매와 섞입니다.
물리적 상태: 액체
색상: 무색~담황색
Specific Gravity: 0.801 · 0.801
수용성: 물과 반응
BRN: 3663489 · 3663489
InChI: 1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3
InChIKey: RMHDLBZYPISZOI-UHFFFAOYSA-N
SMILES: B.CSC
NIST: Borane-methyl sulfide complex(13292-87-0)
EPA: Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0)

화학적 성질

clear colorless to light yellow solution

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 0.5% (1 of 186) of reports.

Danger

H225 (95.7%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P203, P210, P223, P231+P232, P233, P240, P241, P242, P243, P261, P262, P264, P264+P265, P270, P271, P273, P280, P301+P316, P302+P335+P334, P302+P352, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P318, P319, P321, P330, P332+P317, P361+P364, P362+P364, P370+P378, P402+P404, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 186 reports by companies from 20 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 2건

Status: Active Update: 21-11-2017 https://echa.europa.eu/registration-dossier/-/registered-dossier/12369

Boron, trihydrothiobismethane-, (T-4)-: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 2 (95.7%)

안전 및 보호

Protective Action Criteria (PAC) · 3건

0.093 [mg/m3]

1.0 [mg/m3]

6.2 [mg/m3]

안전 데이터

wgk: 3
tsca: TSCA listed
rtecs: PV5080000
ridadr: UN 3399 4.3/PG 1
HS 번호: 29309090
risk_code: 12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21-36/37/38-37
hazard_code: F+,Xn,F,Xi
safety_code: 36/37-62-36/39-33-26-23-16-36-24/25-7/8-43-39-36/37/39
포장분류: II
위험 등급: 4.3
기존화학 물질: 2008-1-560
F 고인화성물질: 10-13-23
Hazard Classifications: Acute Tox. 4 OralEye Dam. 1Flam. Liq. 2Repr. 1BSkin Irrit. 2Water-react 1
스토리지 클래스: 4.3 - Hazardous materials which set free flammable gases upon contact with water
함량 및 규제정보: 물질구분: 유독물질; 혼합물(제품)함량정보: 디메틸 설파이드 보란 및 이를 25% 이상 함유한 혼합물
유해화학물질 필터링: 2008-1-560

화학 및 산업

용도 및 제조

General Manufacturing InformationBoron, trihydro[thiobis[methane]]-, (T-4)-: ACTIVE

응용 분야 · 2건

용도Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.

일반 설명Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.

상·하류 제품 정보

하류 제품

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공급사101 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

爱斯特（成都）生物制药股份有限公司+86-28-85122536 85324413 · [email protected]

湖南省华中特种气体有限公司0734-8755555 15674722888 · [email protected]

宜昌众意泰贸易有限公司0717-6449896 13886658719 · [email protected]

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