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헥사플루오로프로펜 산화물

Hexafluoropropylene oxide

HCID 9883
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
428-59-1
표준 SMILES
FC(F)(F)C1(F)OC1(F)F
InChIKey
PGFXOWRDDHCDTE-UHFFFAOYSA-N
분자식
C3F6O
평균 분자량
166.02 g/mol
단동위원소 질량
165.98533359

개요

Hexafluoropropylene oxide is a colorless odorless gas. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Its vapors are heavier than air. It can cause asphyxiation by the displacement of air. Exposure of the container to prolonged heat or fire may cause it to rupture violently and rocket.

이름 및 식별자

우선 이름
Hexafluoropropylene oxide
IUPAC
2,2,3-trifluoro-3-(trifluoromethyl)oxirane
현지명
헥사플루오로프로펜 산화물
영어명
Hexafluoropropylene oxide
분자식
C3F6O
분자량
166.02

이름 및 동의어

Hexafluoropropylene oxide428-59-1Hexafluoropropene oxide2,2,3-Trifluoro-3-(trifluoromethyl)oxiraneHfpoTRIFLUORO(TRIFLUOROMETHYL)OXIRANEPerfluoropropylene oxideHexafluoro-1,2-epoxypropaneHexafluoropropene epoxideHexafluoroepoxypropaneHexafluoropropylene epoxidePropylene oxide hexafluoride
이름 더 보기
헥사플루오로프로펜산화물헥사플루오로프로펜산화물(HEXAFLUOROPROPENEOXIDE)1,1,2,3,3,3-Hexafluoro-1,2-epoxypropaneC3F6ONA 1956(S) TRIMETHYLOXIRANE
Oxirane, trifluoro(trifluoromethyl)-JPY12AP87NPropane, 1,2-epoxy-1,1,2,3,3,3-hexafluoro-RefChem:146014ACETONE, HEXAFLUOROHFPO hexafluoropropylene oxide207-050-4Poly(perfluoropropyleneoxide)

데이터베이스 식별자

CAS
428-59-1
PubChem CID
9883
DTXSID
DTXSID6029177
UNII
JPY12AP87N
EC Number
207-050-4
Nikkaji
J27.198E

물성

구조 계산 물성보충 중

XLogP
2.1
극성 표면적
12.5 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
7
회전 가능 결합 수
0
무거운 원자 수
10
형식 전하
0
복잡도
161

실험 및 물리화학적 성질

PFAS · 6건

PFAS -> PFAS identified in REACH Regulation EC No. 1272/2008

PFAS -> Suspected persistent, mobile, toxic (PMT) PFAS or PFAS-like compounds

PFAS -> Other/unspecified

PFAS -> OECD Category

PFAS

PFAS -> Intentionally added food contact chemicals

PolymersPlastics & Rubber -> Other Monomers
Boiling Point-18 °F at 760 mmHg (NTP, 1992)
Decomposition · 1건

AT TEMP BETWEEN 500-800 °C, CARBONYL FLUORIDE (COF2) IS DOMINANT PYROLYSIS PRODUCT. THIS GAS IS VERY SUSCEPTIBLE TO HYDROLYSIS, READILY YIELDING HYDROFLUORIC ACID & CARBON DIOXIDE. ABOVE 800 °C, THE PYROLYSIS PRODUCTS CONSIST OF INORGANIC FLUORIDE, A LITTLE TETRAFLUOROMETHANE & CARBON DIOXIDE. /POLYFLUORINES/

Melting Point-200 °F (NTP, 1992)
Physical Description · 3건

Hexafluoropropylene oxide is a colorless odorless gas. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Its vapors are heavier than air. It can cause asphyxiation by the displacement of air. Exposure of the container to prolonged heat or fire may cause it to rupture violently and rocket.

Gas Vapor; CBI; Liquid

Colorless odorless gas; Shipped liquefied under its vapor pressure; [CAMEO]

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 24.2% (16 of 66) of reports.

Danger

H280 (74.2%): Contains gas under pressure; may explode if heated [Warning Gases under pressure]

P260, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P316, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 66 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

유해성 정보

Regulatory Information · 4건

Oxirane, 2,2,3-trifluoro-3-(trifluoromethyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2,2,3-trifluoro-3-(trifluoromethyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

S - indicates a substance that is identified in a final Significant New Use Rule.

REACH registered substance: Trifluoro(trifluoromethyl)oxirane (EC: 207-050-4)

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelNon-Flammable Gas
Fire HazardsExcerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Health HazardsExcerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Hazards Summary · 1건

May polymerize; Containers may explode from prolonged heat; Evaporating liquid can cause frostbite; In confined space spill, may displace air and act as simple asphyxiant; [CAMEO] May explode if heated under confinement; An irritant; In confined space spill, may displace air and act as simple asphyxiant; [MSDSonline]

화학 및 산업

용도 및 제조

Uses · 2건

Used as monomer for heat-resistant hexafluoropropylene oxide polymers; [HSDB]

MONOMER FOR HEXAFLUOROPROPYLENE OXIDE POLYMERS THAT ARE HEAT RESISTANT TO 410 °C

U.S. Production2023: 2,500,000 - <4,000,000 lb
Industry UsesIntermediate
Methods of ManufacturingOXIDATION OF HEXAFLUOROPROPYLENE WITH ALKALINE HYDROGEN PEROXIDE...ABOUT -30 °C.
Use ClassificationPFAS (per- and polyfluoroalkyl substances) -> OECD Category
General Manufacturing Information · 4건

All Other Basic Organic Chemical Manufacturing

Oxirane, 2,2,3-trifluoro-3-(trifluoromethyl)-: ACTIVE

"FREON E" /IS/ TRADEMARK FOR SERIES OF HYDROGEN END-CAPPED TETRAFLUOROETHYLENE EPOXIDE POLYMERS HAVING A DP /DEGREE OF POLYMERIZATION/ UP TO 10. BOILING RANGE 39-490 °C. HIGH DIELECTRIC CONSTANT. USED AS COOLANTS IN ELECTRONIC DEVICES. /FREON E/

"KRYTOX" /IS/ TRADEMARK FOR A SERIES OF HEXAFLUOROPROPYLENE EPOXIDE POLYMERS OF MEDIUM MOLECULAR WT, USED AS LUBRICATING OILS & GREASES. FOR USE IN HIGH TEMP OR CORROSIVE CONDITIONS; GOOD CHEM INERTNESS, EVEN WITH BOILING SULFURIC ACID; LOW SOLUBILITY IN MOST SOLVENTS; GOOD LUBRICITY UNDER LOAD... /KRYTOX/

응용 분야 · 2건

용도Hexafluoropropylene oxide is an important intermediate of organic fluorine material.HFPO is mainly used in the manufacture of high-quality fluorinated compounds.It is the main component of perfluor-vinyl ether(PPVE,PSVE,PFVE,PMVE) and the monomer of fluorinated surfactants and fluorinated ether oil.

일반 설명Hexafluoropropylene oxide is a colorless odorless gas. Hexafluoropropylene oxide is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Its vapors are heavier than air. Hexafluoropropylene oxide can cause asphyxiation by the displacement of air. Exposure of the container to prolonged heat or fire may cause Hexafluoropropylene oxide to rupture violently and rocket.

관련 반응

20건
반응 기록 만들기
HRID 26670 반응식
HRID 26670반응물로uspto-grants-1979_04
HRID 247232 반응식
HRID 247232반응물로uspto-grants-1987_11
HRID 247653 반응식
HRID 247653반응물로uspto-grants-1987_11
HRID 435204 반응식
HRID 435204반응물로uspto-grants-1983_08
HRID 437450 반응식
HRID 437450반응물로uspto-grants-1977_06
HRID 505971 반응식
HRID 505971반응물로uspto-grants-2010_08
HRID 673072 반응식
HRID 673072반응물로Training data from https://doi.org/10.1039/C8SC04228D (3/10)
HRID 1197684 반응식
HRID 1197684생성물로uspto-grants-1994_01
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물리화학적 성질

녹는점
-129 °C · -129°C
끓는 점
42 °C · −42 °C(lit.)
밀도
1.67 · 1.67±0.1 g/cm3(Predicted)
증기압
680.85 kPa · 680.85kPa at 25℃
수용성
16.3 μg/L · 16.3μg/L at 22.7℃
Henry's Law Constant
9.3 · 9.3×10-6 mol/(m3Pa) at 25℃, Clever et al. (2005)
InChI
InChI=1S/C3F6O/c4-1(2(5,6)7)3(8,9)10-1
InChIKey
PGFXOWRDDHCDTE-UHFFFAOYSA-N
SMILES
O1C(F)(C(F)(F)F)C1(F)F
LogP
1.72 at · 1.72 at 25℃
NIST
Oxirane, trifluoro(trifluoromethyl)-(428-59-1)
EPA
2 · Oxirane, 2,2,3-trifluoro-3-(trifluoromethyl)- (428-59-1)
Reactive GroupEpoxides
Reactivity AlertsPolymerizable
Reactivity Profile · 1건

HEXAFLUOROPROPYLENE OXIDE is a chlorinated epoxide. Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
Hazard Classes and Categories · 2건

Press. Gas (Comp.) (74.2%)

Gases under pressure - Low pressure liquefied gas

Shipping Name/ Number DOT/UN/NA/IMONA 1956; Hexafluoropropylene oxide

안전 및 보호

Fire FightingExcerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill ResponseExcerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Preventive Measures · 1건

VENTILATION CONTROL: ...WHERE...RESINS ARE LIKELY TO UNDERGO PYROLYSIS & DECOMP DURING PROCESSING, PROVISION SHOULD BE MADE FOR ADEQUATE LOCAL EXHAUST & GENERAL VENTILATION TO KEEP CONCN OF DECOMP PRODUCTS AS LOW AS POSSIBLE. /POLYFLUORINES/

Isolation and EvacuationExcerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:

독성 정보

Adverse EffectsOther Poison - Simple Asphyxiant
Human Toxicity Excerpts · 1건

A UNIQUE EFFECT FROM PYROLYSIS PRODUCTS OF PTFE /POLYTETRAFLUOROETHYLENE/ RESINS...BEEN OBSERVED IN MAN... THIS IS AN INFLUENZA-LIKE SYNDROME RESEMBLING METAL FUME FEVER & HAS BEEN TERMED "POLYMER FUME FEVER". IT IS SELF-LIMITING, LASTS...24-48 HR & REQUIRES ONLY SYMPTOMATIC TREATMENT. /POLYFLUORINES/

Non-Human Toxicity Excerpts · 1건

IN ACUTE STUDIES WITH MICE & RATS IT CAUSED CHANGES IN LIVER & KIDNEY. IN SPLEEN IT CAUSED VASCULAR PERMEABILITY & DEGENERATIVE DYSTROPHIC CHANGES & INFLAMMATION. EXTENT & NATURE OF TOXICITY DEPENDS UPON TYPE OF METABOLITES THAT ARE PRODUCED.

Probable Routes of Human Exposure · 1건

A UNIQUE EFFECT FROM PYROLYSIS PRODUCTS OF PTFE /POLYTETRAFLUOROETHYLENE/ RESINS...BEEN OBSERVED IN MAN... THIS IS AN INFLUENZA-LIKE SYNDROME RESEMBLING METAL FUME FEVER & HAS BEEN TERMED "POLYMER FUME FEVER". IT IS SELF-LIMITING, LASTS...24-48 HR & REQUIRES ONLY SYMPTOMATIC TREATMENT. /POLYFLUORINES/

안전 데이터

wgk
3
tsca
TSCA listed
ridadr
UN 1956 2.2
risk_code
36/37/38-44
hazard_code
Xi
safety_code
7-26-37/39-38
위험 등급
2.2
기존화학 물질
KE-28148
위험 참고 사항
Irritant
유해 물질 데이터
428-59-1(Hazardous Substances Data)

상·하류 제품 정보

상류 원료

과불화프로판헥사플루오로프로필렌

하류 제품

헥사플루오로아세톤메틸퍼플루오로(2-메틸-3-옥사헥사노에이트)헵타 플루오로-1-메톡시 프로판2,2-Bis(4-methylphenyl)hexafluoropropane