참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Cyclohexanecarboxylic acid | HCID 7413 | — |
| 반응물 | Triethoxysilane | HCID 13830 | — |
| 반응물 | p-Vinylbiphenyl | HCID 16883 | — |
| 반응물 | 1,1-Diethenyl-1,3,3,3-tetramethyldisiloxane | HCID 17760531 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | Para-phenylphenethyltriethoxysilane | HCID 18795112 | 32% |
반응 단계
361 mg Of 4-vinylbiphenyl and 394 mg of triethoxysilane were placed in a glass reaction tube and 0.0009 ml of cyclohexanoic acid was added. Then, 0.009 ml of a toluene solution of a 0-valent platinum complex of divinyltetramethyldisiloxane (platinum content: 0.0044 Wt. %) was added to this mixture. The reaction tube was sealed with Teflon tape and heated for 30 minutes in an oil bath at 50° C. When the tube contents were analyzed by GC-MS following cooling, the conversion rate of 4-vinylbiphenyl was 36% and para-phenylphenethyltriethoxysilane was produced at a yield of 32%. The yield of α-(4-biphenylyl) triethoxysilane was 3%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06048994 |
|---|
| 출처 데이터셋 | uspto-grants-2000_04 |
|---|
| ORD ID | ord-a069b6bbeca745188344d2d97fdf52de |
|---|
| 출처 메모 | uspto-grants-2000_04 |
|---|
