N,N-Dimethylethylenediamine → 1,4-Diaminoanthraquinone-2,3-dicarboxylic acid dimethylaminoethylimide

HRID 1004499

반응식

HRID 1004499 반응식
C[O:2]S([O-])(=O)=O.[NH2:7][C:8]1[C:21]2[C:20](=O)[C:19]3[C:14](=[CH:15][CH:16]=[CH:17][CH:18]=3)[C:13](=[O:23])[C:12]=2[C:11]([NH2:24])=[C:10]2[C:25]([O:27][C:28](=[O:29])[C:9]=12)=[O:26].[CH3:30][N:31]([CH2:33][CH2:34][NH2:35])[CH3:32]>C(O)(=O)C>[CH3:30][N:31]([CH2:33][CH2:34][N:35]=[C:20]1[C:21]2[C:8]([NH2:7])=[C:9]([C:28]([OH:2])=[O:29])[C:10]([C:25]([OH:27])=[O:26])=[C:11]([NH2:24])[C:12]=2[C:13](=[O:23])[C:14]2[C:19]1=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH3:32]

참가 물질

5

반응물 3

HCID 66053N,N-DimethylethylenediamineHCID 4694097Methyl sulfate(1-)HCID 108705481,4-Diaminoanthraquinone-2,3-dicarboxylic anhydride

생성물 1

HCID 691530541,4-Diaminoanthraquinone-2,3-dicarboxylic acid dimethylaminoethylimide

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

Synthesis of a dye with formula XVI, R'=R"=CH3, n=2, A-=CH3SO4 was performed as described below. A solution of 1,4-diaminoanthraquinone-2,3-dicarboxylic anhydride (3.08 g) and dimethylaminoethylamine (1.32 g) in acetic acid (30 ml) is heated to boiling and boiled for 4 hours to form a reaction mixture. Then, the reaction mixture is cooled, and the resultant precipitate is filtered, washed with ethyl alcohol, and dried to yield 3.6 g of 1,4-diaminoanthraquinone-2,3-dicarboxylic acid dimethylaminoethylimide.

후처리

  1. customto form a reaction mixture
  2. temperatureThen, the reaction mixture is cooled
  3. filtrationthe resultant precipitate is filtered
  4. washwashed with ethyl alcohol
  5. customdried

출처 및 근거

ORD 기록
ord-4f7fc9b684de478db7d87419c617e190
출처 데이터셋
uspto-grants-2000_04
특허 번호
US06049428

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