Methane → 1,1,1-Triphenyl-4-acetoxy-1-sila-2-butene

HRID 1004749

반응식

HRID 1004749 반응식
[C:1]([O:4][CH:5]=[CH:6][CH:7]=C)(=[O:3])[CH3:2].[C:9]1([SiH:15]([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.C>C1(C)C=CC=CC=1>[C:22]1([Si:15]([C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:7]=[CH:6][CH2:5][O:4][C:1](=[O:3])[CH3:2])[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1

참가 물질

5

반응물 3

HCID 297MethaneHCID 151951,3-Butadienyl acetateHCID 69922Triphenylsilane

생성물 1

HCID 538005221,1,1-Triphenyl-4-acetoxy-1-sila-2-butene

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

A solution of 1-acetoxy-1,3-butadiene (0.1 mol), triphenylsilane (0.1 mol), and Rh2Cl2 (CO)4 (194.5 mg, 0.625 mol) in 100 mL of toluene was stirred at room temperature under argon for 3 days. The reaction mixture is treated with decolorizing charcoal, and the mixture boiled briefly. After cooling, the reaction mixture is filtered through Celite. Concentration of the solution will afford the title compound.

후처리

  1. temperatureAfter cooling
  2. filtrationthe reaction mixture is filtered through Celite

출처 및 근거

ORD 기록
ord-4baec51b142348798f2b34373f01253c
출처 데이터셋
uspto-grants-2000_04
특허 번호
US06051699

연결된 노트

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