Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Naphthalenecarboxylic acid, 1-hydroxy-, methyl ester → Methyl 1-(2-methoxy-ethoxy)-naphthalene-2-carboxylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Naphthalenecarboxylic acid, 1-hydroxy-, methyl ester | HCID 70358 | — |
| 반응물 | 2-Bromoethyl methyl ether | HCID 80972 | — |
| 생성물 | Methyl 1-(2-methoxy-ethoxy)-naphthalene-2-carboxylate | HCID 22126290 | — |
반응 단계
By alkylating methyl 1-hydroxy-naphthalene-2-carboxylate analogously to Example 1 (g) with 2-bromoethyl methyl ether there was obtained methyl 1-(2-methoxy-ethoxy)-naphthalene-2-carboxylate, which was subsequently converted analogously to Example 5 (b)-(c) firstly into [1-(2-methoxy-ethoxy)-naphthalen-2-yl]-methanol and then into 2-chloromethyl-1-(2-methoxy-ethoxy)-naphthalene, which was finally obtained as a beige solid; MS: 250 (M)+.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06051712 |
| 출처 데이터셋 | uspto-grants-2000_04 |
| ORD ID | ord-ec1ba080094845c7805ff815c90d503a |
| 출처 메모 | uspto-grants-2000_04 |