Aluminium lithium hydride → HCID 22126362, 화합물

HRID 1005177노트

반응식

HRID 1005177 반응식
[CH3:1][O:2][C:3]1[C:12]2[C:7](=[C:8]([O:13][CH3:14])[CH:9]=[CH:10][CH:11]=2)[CH:6]=[C:5]([C:15](OC)=[O:16])[CH:4]=1.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH3:1][O:2][C:3]1[C:12]2[C:7](=[C:8]([O:13][CH3:14])[CH:9]=[CH:10][CH:11]=2)[CH:6]=[C:5]([CH2:15][OH:16])[CH:4]=1

참가 물질

3

반응물 2

HCID 21226445Aluminium lithium hydrideHCID 22126413HCID 22126413, 화합물

생성물 1

HCID 22126362HCID 22126362, 화합물

실험 절차

In an analogous manner to that described in Example 5 b), by reducing methyl 4,8-dimethoxy-naphthalene-2-carboxylate (J.Chem.Soc. 1959, 1024) by means of lithium aluminium hydride there was obtained (4,8-dimethoxy-naphthalen-2-yl)-methanol, MS: 218 (M)+, as a colourless solid.

출처 및 근거

ORD 기록
ord-48be9e889cc04dcb95c7b44f3cecc5b7
출처 데이터셋
uspto-grants-2000_04
특허 번호
US06051712

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