Methyl 4-[(acetylsulfanyl)methyl]oxane-4-carboxylate → 1-Acetylsulfanylmethylcyclohexanecarboxylic acid methyl ester

HRID 1005885노트

반응식

HRID 1005885 반응식
[CH3:1][O:2][C:3]([C:5]1([CH2:11][S:12][C:13](=[O:15])[CH3:14])[CH2:10][CH2:9]O[CH2:7][CH2:6]1)=[O:4].[CH3:16]OC(C1(CI)CCCCC1)=O>>[CH3:1][O:2][C:3]([C:5]1([CH2:11][S:12][C:13](=[O:15])[CH3:14])[CH2:10][CH2:9][CH2:16][CH2:7][CH2:6]1)=[O:4]

참가 물질

3

반응물 2

HCID 23448262Methyl 4-[(acetylsulfanyl)methyl]oxane-4-carboxylateHCID 58947958Methyl 1-(iodomethyl)cyclohexanecarboxylate

생성물 1

HCID 589479501-Acetylsulfanylmethylcyclohexanecarboxylic acid methyl ester수율 92%

실험 절차

Prepared according to the method for the preparation of 4-acetylsulfanylmethyltetrahydropyran-4-carboxylic acid methyl ester, from 1-iodomethylcyclohexanecarboxylic acid methyl ester (20 g), to yield the title compound as a brown gum (15 g, 92%).

후처리

  1. customPrepared

출처 및 근거

ORD 기록
ord-5768a0c849eb41108867a175c460d01f
출처 데이터셋
uspto-grants-2004_09
특허 번호
US06787536B2

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