3-(Trifluoromethyl)phenol → HCID 178418715, 화합물

HRID 10155

반응식

HRID 10155 반응식
[CH:1]1([Zr:6](C)C)[CH:5]=[CH:4][CH:3]=[CH:2]1.[F:9][C:10]([F:19])([F:18])[C:11]1[CH:16]=[CH:15][CH:14]=[C:13]([OH:17])[CH:12]=1>C1(C)C=CC=CC=1>[CH:1]1([Zr:6]([O:17][C:13]2[CH:14]=[CH:15][CH:16]=[C:11]([C:10]([F:9])([F:18])[F:19])[CH:12]=2)[O:17][C:13]2[CH:14]=[CH:15][CH:16]=[C:11]([C:10]([F:18])([F:19])[F:9])[CH:12]=2)[CH:5]=[CH:4][CH:3]=[CH:2]1

참가 물질

4

반응물 2

HCID 73763-(Trifluoromethyl)phenolHCID 178418892HCID 178418892, 화합물

생성물 1

HCID 178418715HCID 178418715, 화합물

시약·촉매·용매 1

HCID 1140Toluene용매3회

실험 절차

To a 50 ml Schlenk flask containing 138.7 mg (0.5 mmole) of (1-methylboratabenzene) (cyclopentadienyl) dimethyl zirconium [intermediate product of 1st Step] in 15 ml toluene and at 0° C., 162.1 mg (1 mmole) of Trifluoro-m-Cresol in 10 ml toluene is added slowly under stirring. After warming up to room temperature and stirring one hour at room temperature, toluene of the reaction mixture is moved by vacuum. The desired product (1-methylboratabenzene) (cyclopentadienyl) bis(3-trifluoromethylphenoxy) zirconium can be obtained from the residue of vacuum distillation.

후처리

  1. stirringstirring one hour at room temperature

출처 및 근거

ORD 기록
ord-6cea0494348b410e84f555c127ac38a6
출처 데이터셋
uspto-grants-2006_08
특허 번호
US07094723B2

연결된 노트

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