참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 1,1,1-Trichloro-2,2,2-trifluoroethane | HCID 9635 | — |
| 반응물 | Propane, 2-(ethenyloxy)-2-methyl- | HCID 70220 | — |
| 촉매 | Mercury | HCID 23931 | — |
| 생성물 | HCID 54430105 | HCID 54430105 | 60% |
반응 단계
A mixture of 1,1,1-trifluoro-2,2,2-trichloroethane and tert-butylvinyl ether in a 3:1 molar ratio is introduced to a jacketed photochemical reaction vessel. The mixture is irradiated using a medium-pressure mercury UV lamp so as to maintain the temperature of the mixture at about 35-45° C. for about 2 hours. The resultant reaction mixture is concentrated to remove volatiles and distilled to produce 3-chloro-4,4,4-trifluorobut-2-enal in a 60% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06476279B2 |
|---|
| 출처 데이터셋 | uspto-grants-2002_11 |
|---|
| ORD ID | ord-6ba90947a37f4507b6f63d1f42967f69 |
|---|
| 출처 메모 | uspto-grants-2002_11 |
|---|
