Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethanol → 1~2~,2~2~:2~3~,3~2~-Terpyridine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethanol | HCID 702 | — |
| 반응물 | 2-Acetylpyridine | HCID 14286 | — |
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | Ammonium Hydroxide | HCID 14923 | — |
| 생성물 | 1~2~,2~2~:2~3~,3~2~-Terpyridine | HCID 14938971 | — |
반응 단계
6-(2-(4-Iodophenyl)ethynyl)pyridine-3-ter-pyridine (Compound 94, Scheme 24) was prepared by stirring a mixture of Compound 93 (500 mg, 1.5 mmol), 2-Acetylpyridine (550 mg, 4.5 mmol), KOH 85% (360 mg, 4.5 mmol, and NH4OH 29% (7.5 ml, 6 mmol) in anhydrous ethyl alcohol (25 ml) and reflux for 14 hours. Thereafter the crude solid was collected by filtration, and washed with cold EtOH to produce the ter-pyridine Compound 94 as a brownish solid (65% yield).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08715635B2 |
| 출처 데이터셋 | uspto-grants-2014_05 |
| ORD ID | ord-638d4cd671e84bc7be1e416ebb935395 |
| 출처 메모 | uspto-grants-2014_05 |