Coumarin → Heptadecanal

반응식

O1C2C(=CC=CC=2)C=CC1=O.[C:12](O)(=[O:29])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28]>>[CH:12](=[O:29])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28]

참가 물질

반응물 2

HCID 323Coumarin

HCID 10465Heptadecanoic Acid

생성물 1

HCID 71552Heptadecanal수율 21%

실험 절차

After the reaction, the autoclave was cooled with ice, and the pressure was reduced; subsequently, the reaction mixture was analyzed by FT-NMR using coumarin as an internal standard. The results confirmed that heptadecanoic acid was obtained in a yield of 78%, and heptadecanal was obtained in a yield of 21%.

후처리

customAfter the reaction
temperaturethe autoclave was cooled with ice
customwas obtained in a yield of 78%

출처 및 근거

ORD 기록: ord-99f5706563e94938a082bb3edd44fd6d
출처 데이터셋: uspto-grants-2014_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08716501B2

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