Iodine → 2-Iodo-9H-fluorene

HRID 1029063

반응식

HRID 1029063 반응식
[CH:1]1[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.S(=O)(=O)(O)O.II.[I:21](O)(=O)=O>CO>[I:21][C:9]1[CH:8]=[CH:7][C:6]2[C:5]3[C:13](=[CH:1][CH:2]=[CH:3][CH:4]=3)[CH2:12][C:11]=2[CH:10]=1

참가 물질

6

반응물 4

HCID 807IodineHCID 1118Sulfuric AcidHCID 6853FluoreneHCID 24345Iodic acid

생성물 1

HCID 2240942-Iodo-9H-fluorene

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

56.8 parts of fluorene, 200 parts of methanol, 37 parts of 63% sulfuric acid aqueous solution, 31 parts of iodine, and 34 parts of 34% iodic acid aqueous solution were stirred at 60° C. for 5 hours. After completion of the stirring, the resultant was filtrated, and it was then washed with 100 parts of water twice. Thereafter, the resultant was dried at 70° C. overnight. After completion of the drying, the resultant was recrystallized in methanol to obtain 60 parts of 2-iodofluorene in the form of white powders.

후처리

  1. filtrationAfter completion of the stirring, the resultant was filtrated
  2. washit was then washed with 100 parts of water twice
  3. customThereafter, the resultant was dried at 70° C. overnight
  4. customAfter completion of the drying, the resultant was recrystallized in methanol

출처 및 근거

ORD 기록
ord-1d95bd822adf49d3a6d85f49bc1132eb
출처 데이터셋
uspto-grants-2014_05
특허 번호
US08735720B2

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