Hydrogen Sulfide → 3,5-Di-tert-butyl-4-hydroxyphenyl dithiocarbamate

HRID 1030225노트

반응식

HRID 1030225 반응식
[C:1]([C:5]1[CH:6]=[C:7]([S:16][C:17]#[N:18])[CH:8]=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:10]=1[OH:11])([CH3:4])([CH3:3])[CH3:2].C(N(CC)CC)C.[SH2:26]>C(OCC)C>[C:17](=[S:26])([S:16][C:7]1[CH:6]=[C:5]([C:1]([CH3:4])([CH3:2])[CH3:3])[C:10]([OH:11])=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[CH:8]=1)[NH2:18]

참가 물질

5

반응물 3

HCID 402Hydrogen SulfideHCID 8471TriethylamineHCID 6192452,6-DI-Tert-butyl-4-thiocyanato-phenol

생성물 1

HCID 198222993,5-Di-tert-butyl-4-hydroxyphenyl dithiocarbamate

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

3,5-Di-tert-butyl-4-hydroxyphenyl thiocyanate (8.7 g) and 0.3 g of triethylamine were dissolved in 80 ml of diethyl ether, and hydrogen sulfide was blown into the solution at room temperature over 4.5 hours. The reaction mixture was concentrated, and the crude product thus obtained was washed with diethyl ether to give 7.5 g of the desired compound as a colorless solid.

후처리

  1. concentrationThe reaction mixture was concentrated
  2. customthe crude product thus obtained
  3. washwas washed with diethyl ether

출처 및 근거

ORD 기록
ord-f36eeb5821fc47d0bea9d53a851b063b
출처 데이터셋
uspto-grants-1992_04
특허 번호
US05104889

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