Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-[2-Hydroxy-4,6-bis(methoxymethoxy)phenyl]ethanone → 3,4-Bis(methoxymethoxy)benzaldehyde
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-[2-Hydroxy-4,6-bis(methoxymethoxy)phenyl]ethanone | HCID 10879697 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 3,4-Bis(methoxymethoxy)benzaldehyde | HCID 11746314 | 218.6% |
반응 단계
In 260 ml of ethanol were dissolved 33.37 g of the 2'-hydroxy-4',6'-bis(methoxymethoxy)acetophenone obtained in Production Example 11 and 32.20 g of the 3,4-bis(methoxymethoxy)benzaldehyde obtained in Production Example 24, and 300 ml of a saturated solution of potassium hydroxide in ethanol was added to the solution and the mixture was stirred for 24 hours to effect a reaction. After the reaction, the pH value of the reaction liquid was adjusted to about 6 by 6N hydrochloric acid, and the formed precipitate was recovered by filtration, washed with water and dried to obtain 53.17 g (yield=87.9%) of 2'-hydroxy-3,4,4',6'-tetrakis(methoxymethoxy)chalcone.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05106871 |
| 출처 데이터셋 | uspto-grants-1992_04 |
| ORD ID | ord-ab4fe7a5970b4393aba04cc2d4a14e60 |
| 출처 메모 | uspto-grants-1992_04 |