Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Bromo-2-methoxynaphthalene → 2-Acetyl-6-methoxynaphthalene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Bromo-2-methoxynaphthalene | HCID 72860 | — |
| 반응물 | 1-(5-Bromo-6-methoxynaphthalen-2-yl)ethan-1-one | HCID 622178 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 용매 | P-Xylene | HCID 7809 | — |
| 생성물 | 2-Acetyl-6-methoxynaphthalene | HCID 77506 | — |
반응 단계
45.3 Ml of p-xylene and 8.2 g of anhydrous aluminum chloride are added to the solution of 2-acetyl-5-bromo-6-methoxynaphthalene obtained as in example 1a), while keeping the temperature at -10° C. The reaction mixture is kept for 16 hours under stirring at room temperature and then it is worked as in example 1 obtaining 42.8 g of product with a yield equal to 87.3% calculated on the basis of the starting material 1-bromo-2-methoxynaphthalene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05107013 |
| 출처 데이터셋 | uspto-grants-1992_04 |
| ORD ID | ord-2f93aea472d243479a535e24734e7c06 |
| 출처 메모 | uspto-grants-1992_04 |