Diphenylamine → HCID 11137635, 화합물

HRID 1031852노트

반응식

HRID 1031852 반응식
C([Li:5])CCC.[C:6]1([NH:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1>CCCCCC.CCOCC>[C:13]1([N-:12][C:6]2[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=2)[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1.[Li+:5]

참가 물질

5

반응물 2

HCID 11487Diphenylamine2회HCID 178418339Butyllithium

생성물 1

HCID 11137635HCID 11137635, 화합물

시약·촉매·용매 2

HCID 3283Diethyl Ether용매2회HCID 8058Hexane용매

반응 조건

온도
-78 °C

실험 절차

To a 500 ml Schlenk equipped with a 250 ml pressure equalizing dropping funnel is added 250 ml of diethyl ether which is chilled to -78° C. in an acetone/dry ice bath. To this is added n-butyl lithium, 0.10 mole of a 2.90 molar solution in hexane, followed by the addition of 16.923 g (0.10 mole) of diphenylamine dissolved in ether, 50 ml. The flask contents are stirred magnetically and maintained at -78° C. during the addition of diphenylamine which requires 0.5 hour. The contents are warmed to room temperature for 2 hours.

후처리

  1. customTo a 500 ml Schlenk equipped with a 250 ml pressure
  2. temperatureThe contents are warmed to room temperature for 2 hours

출처 및 근거

ORD 기록
ord-40bdc2c4a3624e5db08bf94b732d47d4
출처 데이터셋
uspto-grants-1990_09
특허 번호
US04956323

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